Research Article
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Static Dielectric Constants, Densities, Refractive Indices and Related Properties of Binary Mixtures at Various Temperatures Under Atmospheric Pressure

Year 2022, Volume: 25 Issue: 3, 1 - 10, 01.09.2022
https://doi.org/10.5541/ijot.1017174

Abstract

Experimental dielectric constants at (293.15, 298.15, 303.15) K, densities and refractive indices at 293.15 K are reported for water- ethanol and water- n-butanol binary mixture systems over the entire volume fraction range and atmospheric pressure. From the experimental dielectric data, the excess dielectric constant, effective Kirkwood correlation factor, Bruggeman factor and from density and refractive index data various parameters and their excess properties like excess density, excess refractive index, excess molar polarization, and excess molar volume were estimated and reported in the study. The static dielectric constant of the studied binary mixtures decreases with increase in temperature and volume fraction of the solutes. The density values are decreasing and refractive indices are increasing with increasing volume fraction of ethanol and n-butanol in water. Excess molar volumes values of ethanol and n-butanol are negative over the entire volume fraction range shows the presence of intermolecular interaction and hydrogen bonding in both the binary mixtures.

References

  • R. Day and A. Underwood, “Quantitative Analysis, New Jersey: Prentice-Hall 1991.
  • H. Yilmaz and S. Guler, “Excess properties of methanol-water binary system at various temperatures,” II Nuovo Cimento, 20D, 1853-1851, 1998.
  • A. Jouyban, S. Shahla and H. Chan, “A simple relationship between dielectric constant of mixed solvents with solvent composition and temperature,”International Journal of Pharmaceutics, 269, 353- 360, 2004. doi: 10.1016/j.ijpharm.2003.09.010.
  • M. Mohsen- Nia, H. Amiri, B. Jazi, “Dielectric constant of water, methanol, ethanol, butanol, and acetone: measurement and computational study,” J. Solu. Chem., 39, 701-708, 2010. DOI 10.1007/s10953-010-9538-5.
  • Hülya Yilmaz, “Excess properties of alcohol- water systems at 298.15K,” Turk, J. Phys., 26, 243-246, 2002.
  • A.P. Maharolkar, A. Murugkar, P.W. Khirade, S.C. Mehrotra, “Study of Dielectric and Acoustic Properties of Binary Liquid Mixtures of Cyclohexane with n-Butanol at 308 K,” Russian Journal of Physical Chemistry A, 95, S56-S61, 2021. DOI:10.1134/S0036024421140120.
  • V. V. Navarkhele, “Dielectric and Excess properties of glycol with formamide at different temperatures,” Russian Journal of Physical Chemistry A, 92, 1417-1422, 2018. DOI: 10.1134/S0036024418070191.
  • R. J. Sengwa, S. Sankhla and S. Shinyashiki,. “Dielectric Parameters and Hydrogen Bond Interaction Study of Binary Alcohol Mixtures,” J. Sol. Chem., 37, 137-153, 2008. DOI 10.1007/s10953-007-9230-6.
  • J. G. Kirkwood, “The dielectric polarization of polar liquids”, J. Chem. Phys., 7, 911-919, 1939. A.C. Kumbharkhane, S.M. Puranik, S.C. Mehrotra, “Dielectric relaxation of tert- butyl alcohol–water mixtures using a time-domain technique”, J. Chem. Soc. Faraday Trans., 87, 1569-1573, 1991. https://doi.org/10.1039/FT9918701569.
  • A.C. Kumbharkhane, S.M. Puranik, S.C. Mehrotra, “Dielectric relaxation studies of aqueous N, N dimethylformamide using a picoseconds time domain technique”, J. Sol. Chem., 22, 219-229, 1993. https://doi.org/10.1007/BF00649245
  • D. A. G. Bruggeman, Ann. Phys (Leipz.), 24, 636-646, 1935.
  • Farid I.EI-Dossoki, “Refractive index and density measurements of selected binary protic-protic, aprotic-aprotic, and aprotic and protic syatems at temperatures from 298.15K to 308.15 K”, J. Chinese Chem. Society, 54, 1129-1137, 2007.
  • C. M. Trivediand V. A. Rana, “Static permittivity,refractive index, density,and related properties of binary mixtures of pyridine and 1-propanol at diffenent temperatures”, Indian journal of pure & applied Physics, 52, 183-191, 2014.
  • E.R. Mongnaschi and L.M. Laboranti, “Association of pure polar liquids: Dielectric properties of docosanoic acid”, J. Chem..Soc. Faraday Trans., 92(18), 3367-3369, 1996.
  • S. K. Rays, J. Rath and C. Dwivedi, “ Excess Molar polarization in binary mixtures of polar liquids,” Physics and Chemistry of Liuids., 39, 227-237 2001. https://doi.org/10.1080/00319100108030341
  • J. I. Kim, “A Critical Study of the Ph4AsPh4B Assumption for Single Ion Thermodynamics in Amphiprotic and Dipolar-Aprotic Solvents; Evaluation of Physical Parameters Relevant to Theoretical Consideration,” Z. Phys, Chem. Neue Folge, 113, S.129- 150, 1978.https://doi.org/10.1524/zpch.1978.113.2.129
  • S. Oswal, “Studies on density, viscosity, dielectric constant, and refractive indices of binary mixtures of ester in benezen and carbon tetrachloride”, Can. J. Chem., 66, 111-116, 1988.
  • Fisnik Aliaj, Naim Syla, Ardita Kurtishaj, Njomza Elezaj, Tahir arbneshi, Arber Zeqiraj, “Densities, refractive indices, and derived properties of binary mixtures of ethanol with benzene and pyridine at various temperatures under atmospheric pressure”, International journal of Thermophysics,41, 49-55, 2020. doi.org/10.1007/s10765-020-02632-9
  • E. J. Gonzalez, P.F. Requejo, F. M. Maia, A. Dominguez and E. A. Macedo, “Solubility, density and excess molar volume of binary mixtures of aromatic compounds and common ionic liquids at T = 283.15 K and atmospheric pressure”, Physics and Chemistry of liquids, 53, 419-428, 2015. doi.org/10.1080/00319104.2013.782546
  • N.E. Hill, W.E. Vaughan, A.R. Price and M. Davies, Dielectric properties and Molecular behavior, Van Nostrand Reinhold: London -1969.
  • A.C. Kumbharkhane, S. M. Puranik, S.C. Mehrotra, “Structural study of amide-water mixtures using dielectric relaxation technique”, J. of Mole. Liqs, 51, 261-277, 1992. doi.org/10.1016/0167 7322(92)80088-Y
  • V. V. Navarkhele, M. K. Bhanarkar, “Microwave dielectric response of binary mixture of N, N dimethylformamide with propylene glycol using TDR method,” Molecular Physics, 107, 1823-1830, 2009. http://dx.doi.org/10.1080/00268970903084912
  • B. G. Lone, P.B. Undre, S. S. Patil, P.W. Khirade and S.C. Mehrotra, “Dielectric study of methanol- ethanol mixtures using TDR method. Journal of Molecular Liquid”, J. of Mole. Liqs, 141, 47-53, 2008. doi:10.1016/j.molliq.2008.03.001.
  • V. V. Navarkhele and M.K. Bhanarkar, “High-frequency dielectric response of the binary mixture formamide–butylene glycol,” Physics and Chemistry of Liquids, 48, 89-98, 2010. http://dx.doi.org/10.1080/00319100802688360
  • A. Nasim, K. Movagharnejad, P. Mohsenand K. Mahnam, “Densities, Viscosities, and Refractive Indices of Poly(ethylene glycol) 300 + 1,2-Ethanediol, 1,2- Propanediol, 1,3-Propanediol, 1,3-Butanediol, or 1,4-Butanediol Binary Liquid Mixtures,”. Journal of Chemical Engineering Data, 65, 3448-3462, 2020. https://dx.doi.org/10.1021/acs.jced.9b01189
  • V. V. Navarkhele and M.K. Bhanarkar, “Dielectric relaxation study of formamide–propylene glycol using time domain reflectometry”, Physics and Chemistry of Liquids, 49, 550-559, 2011. DOI: 10.1080/00319104.2010.508041.
  • M.T. Hosamani, R.H. Fattepur, D.K. Deshpande and S. C.Mehrotra, “Temperature-and Frequency –Dependent Dielectric studies of PFluorophenylactetonitrile –Methanol mixtures using the Time domain reflectrometry”, J. Chem. Soc. Faraday Trans., 91, 623-626, 1995. https://doi.org/10.1039/FT9959100623
  • A. Ali, M. Tariq, F. Nabi and Shahajahn, “Density, Viscosity, Refractive Index, and Speed of Sound in Binary Mixtures of Pyridine and 1-Alkanols (C6, C7, C8, C10) at 303.15 K”, Chinese Journal of Chemistry, 26, 2009-2015, 2008. https://www.researchgate.net/publication/315750205.
Year 2022, Volume: 25 Issue: 3, 1 - 10, 01.09.2022
https://doi.org/10.5541/ijot.1017174

Abstract

References

  • R. Day and A. Underwood, “Quantitative Analysis, New Jersey: Prentice-Hall 1991.
  • H. Yilmaz and S. Guler, “Excess properties of methanol-water binary system at various temperatures,” II Nuovo Cimento, 20D, 1853-1851, 1998.
  • A. Jouyban, S. Shahla and H. Chan, “A simple relationship between dielectric constant of mixed solvents with solvent composition and temperature,”International Journal of Pharmaceutics, 269, 353- 360, 2004. doi: 10.1016/j.ijpharm.2003.09.010.
  • M. Mohsen- Nia, H. Amiri, B. Jazi, “Dielectric constant of water, methanol, ethanol, butanol, and acetone: measurement and computational study,” J. Solu. Chem., 39, 701-708, 2010. DOI 10.1007/s10953-010-9538-5.
  • Hülya Yilmaz, “Excess properties of alcohol- water systems at 298.15K,” Turk, J. Phys., 26, 243-246, 2002.
  • A.P. Maharolkar, A. Murugkar, P.W. Khirade, S.C. Mehrotra, “Study of Dielectric and Acoustic Properties of Binary Liquid Mixtures of Cyclohexane with n-Butanol at 308 K,” Russian Journal of Physical Chemistry A, 95, S56-S61, 2021. DOI:10.1134/S0036024421140120.
  • V. V. Navarkhele, “Dielectric and Excess properties of glycol with formamide at different temperatures,” Russian Journal of Physical Chemistry A, 92, 1417-1422, 2018. DOI: 10.1134/S0036024418070191.
  • R. J. Sengwa, S. Sankhla and S. Shinyashiki,. “Dielectric Parameters and Hydrogen Bond Interaction Study of Binary Alcohol Mixtures,” J. Sol. Chem., 37, 137-153, 2008. DOI 10.1007/s10953-007-9230-6.
  • J. G. Kirkwood, “The dielectric polarization of polar liquids”, J. Chem. Phys., 7, 911-919, 1939. A.C. Kumbharkhane, S.M. Puranik, S.C. Mehrotra, “Dielectric relaxation of tert- butyl alcohol–water mixtures using a time-domain technique”, J. Chem. Soc. Faraday Trans., 87, 1569-1573, 1991. https://doi.org/10.1039/FT9918701569.
  • A.C. Kumbharkhane, S.M. Puranik, S.C. Mehrotra, “Dielectric relaxation studies of aqueous N, N dimethylformamide using a picoseconds time domain technique”, J. Sol. Chem., 22, 219-229, 1993. https://doi.org/10.1007/BF00649245
  • D. A. G. Bruggeman, Ann. Phys (Leipz.), 24, 636-646, 1935.
  • Farid I.EI-Dossoki, “Refractive index and density measurements of selected binary protic-protic, aprotic-aprotic, and aprotic and protic syatems at temperatures from 298.15K to 308.15 K”, J. Chinese Chem. Society, 54, 1129-1137, 2007.
  • C. M. Trivediand V. A. Rana, “Static permittivity,refractive index, density,and related properties of binary mixtures of pyridine and 1-propanol at diffenent temperatures”, Indian journal of pure & applied Physics, 52, 183-191, 2014.
  • E.R. Mongnaschi and L.M. Laboranti, “Association of pure polar liquids: Dielectric properties of docosanoic acid”, J. Chem..Soc. Faraday Trans., 92(18), 3367-3369, 1996.
  • S. K. Rays, J. Rath and C. Dwivedi, “ Excess Molar polarization in binary mixtures of polar liquids,” Physics and Chemistry of Liuids., 39, 227-237 2001. https://doi.org/10.1080/00319100108030341
  • J. I. Kim, “A Critical Study of the Ph4AsPh4B Assumption for Single Ion Thermodynamics in Amphiprotic and Dipolar-Aprotic Solvents; Evaluation of Physical Parameters Relevant to Theoretical Consideration,” Z. Phys, Chem. Neue Folge, 113, S.129- 150, 1978.https://doi.org/10.1524/zpch.1978.113.2.129
  • S. Oswal, “Studies on density, viscosity, dielectric constant, and refractive indices of binary mixtures of ester in benezen and carbon tetrachloride”, Can. J. Chem., 66, 111-116, 1988.
  • Fisnik Aliaj, Naim Syla, Ardita Kurtishaj, Njomza Elezaj, Tahir arbneshi, Arber Zeqiraj, “Densities, refractive indices, and derived properties of binary mixtures of ethanol with benzene and pyridine at various temperatures under atmospheric pressure”, International journal of Thermophysics,41, 49-55, 2020. doi.org/10.1007/s10765-020-02632-9
  • E. J. Gonzalez, P.F. Requejo, F. M. Maia, A. Dominguez and E. A. Macedo, “Solubility, density and excess molar volume of binary mixtures of aromatic compounds and common ionic liquids at T = 283.15 K and atmospheric pressure”, Physics and Chemistry of liquids, 53, 419-428, 2015. doi.org/10.1080/00319104.2013.782546
  • N.E. Hill, W.E. Vaughan, A.R. Price and M. Davies, Dielectric properties and Molecular behavior, Van Nostrand Reinhold: London -1969.
  • A.C. Kumbharkhane, S. M. Puranik, S.C. Mehrotra, “Structural study of amide-water mixtures using dielectric relaxation technique”, J. of Mole. Liqs, 51, 261-277, 1992. doi.org/10.1016/0167 7322(92)80088-Y
  • V. V. Navarkhele, M. K. Bhanarkar, “Microwave dielectric response of binary mixture of N, N dimethylformamide with propylene glycol using TDR method,” Molecular Physics, 107, 1823-1830, 2009. http://dx.doi.org/10.1080/00268970903084912
  • B. G. Lone, P.B. Undre, S. S. Patil, P.W. Khirade and S.C. Mehrotra, “Dielectric study of methanol- ethanol mixtures using TDR method. Journal of Molecular Liquid”, J. of Mole. Liqs, 141, 47-53, 2008. doi:10.1016/j.molliq.2008.03.001.
  • V. V. Navarkhele and M.K. Bhanarkar, “High-frequency dielectric response of the binary mixture formamide–butylene glycol,” Physics and Chemistry of Liquids, 48, 89-98, 2010. http://dx.doi.org/10.1080/00319100802688360
  • A. Nasim, K. Movagharnejad, P. Mohsenand K. Mahnam, “Densities, Viscosities, and Refractive Indices of Poly(ethylene glycol) 300 + 1,2-Ethanediol, 1,2- Propanediol, 1,3-Propanediol, 1,3-Butanediol, or 1,4-Butanediol Binary Liquid Mixtures,”. Journal of Chemical Engineering Data, 65, 3448-3462, 2020. https://dx.doi.org/10.1021/acs.jced.9b01189
  • V. V. Navarkhele and M.K. Bhanarkar, “Dielectric relaxation study of formamide–propylene glycol using time domain reflectometry”, Physics and Chemistry of Liquids, 49, 550-559, 2011. DOI: 10.1080/00319104.2010.508041.
  • M.T. Hosamani, R.H. Fattepur, D.K. Deshpande and S. C.Mehrotra, “Temperature-and Frequency –Dependent Dielectric studies of PFluorophenylactetonitrile –Methanol mixtures using the Time domain reflectrometry”, J. Chem. Soc. Faraday Trans., 91, 623-626, 1995. https://doi.org/10.1039/FT9959100623
  • A. Ali, M. Tariq, F. Nabi and Shahajahn, “Density, Viscosity, Refractive Index, and Speed of Sound in Binary Mixtures of Pyridine and 1-Alkanols (C6, C7, C8, C10) at 303.15 K”, Chinese Journal of Chemistry, 26, 2009-2015, 2008. https://www.researchgate.net/publication/315750205.
There are 28 citations in total.

Details

Primary Language English
Subjects Organic Chemistry
Journal Section Research Articles
Authors

Vaijanath Navarkhele

Aishwarya Navarkhele

Publication Date September 1, 2022
Published in Issue Year 2022 Volume: 25 Issue: 3

Cite

APA Navarkhele, V., & Navarkhele, A. (2022). Static Dielectric Constants, Densities, Refractive Indices and Related Properties of Binary Mixtures at Various Temperatures Under Atmospheric Pressure. International Journal of Thermodynamics, 25(3), 1-10. https://doi.org/10.5541/ijot.1017174
AMA Navarkhele V, Navarkhele A. Static Dielectric Constants, Densities, Refractive Indices and Related Properties of Binary Mixtures at Various Temperatures Under Atmospheric Pressure. International Journal of Thermodynamics. September 2022;25(3):1-10. doi:10.5541/ijot.1017174
Chicago Navarkhele, Vaijanath, and Aishwarya Navarkhele. “Static Dielectric Constants, Densities, Refractive Indices and Related Properties of Binary Mixtures at Various Temperatures Under Atmospheric Pressure”. International Journal of Thermodynamics 25, no. 3 (September 2022): 1-10. https://doi.org/10.5541/ijot.1017174.
EndNote Navarkhele V, Navarkhele A (September 1, 2022) Static Dielectric Constants, Densities, Refractive Indices and Related Properties of Binary Mixtures at Various Temperatures Under Atmospheric Pressure. International Journal of Thermodynamics 25 3 1–10.
IEEE V. Navarkhele and A. Navarkhele, “Static Dielectric Constants, Densities, Refractive Indices and Related Properties of Binary Mixtures at Various Temperatures Under Atmospheric Pressure”, International Journal of Thermodynamics, vol. 25, no. 3, pp. 1–10, 2022, doi: 10.5541/ijot.1017174.
ISNAD Navarkhele, Vaijanath - Navarkhele, Aishwarya. “Static Dielectric Constants, Densities, Refractive Indices and Related Properties of Binary Mixtures at Various Temperatures Under Atmospheric Pressure”. International Journal of Thermodynamics 25/3 (September 2022), 1-10. https://doi.org/10.5541/ijot.1017174.
JAMA Navarkhele V, Navarkhele A. Static Dielectric Constants, Densities, Refractive Indices and Related Properties of Binary Mixtures at Various Temperatures Under Atmospheric Pressure. International Journal of Thermodynamics. 2022;25:1–10.
MLA Navarkhele, Vaijanath and Aishwarya Navarkhele. “Static Dielectric Constants, Densities, Refractive Indices and Related Properties of Binary Mixtures at Various Temperatures Under Atmospheric Pressure”. International Journal of Thermodynamics, vol. 25, no. 3, 2022, pp. 1-10, doi:10.5541/ijot.1017174.
Vancouver Navarkhele V, Navarkhele A. Static Dielectric Constants, Densities, Refractive Indices and Related Properties of Binary Mixtures at Various Temperatures Under Atmospheric Pressure. International Journal of Thermodynamics. 2022;25(3):1-10.