Research Article
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Year 2022, Volume: 25 Issue: 4, 56 - 65, 01.12.2022
https://doi.org/10.5541/ijot.1136615

Abstract

References

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Thermodynamic Modeling of Liquid-Liquid Equilibrium in Ternary Systems with Biodiesel and Isolated Ester (Methyl Palmitate)

Year 2022, Volume: 25 Issue: 4, 56 - 65, 01.12.2022
https://doi.org/10.5541/ijot.1136615

Abstract

Liquid-liquid equilibrium data were measured and analyzed for two ternary systems (biodiesel + methanol + glycerol and methyl palmitate + methanol + glycerol). Biodiesel, produced by the conventional chemical route at 60 °C for 60 min, using methanol and soybean oil at a molar rate of 10:1 and potassium hydroxide concentration (KOH) of 1 wt% exhibited thermal decomposition at temperatures between 100 and 250 ºC, reaching mass loss of approximately 98.8%, confirming soybean oil conversion into biodiesel by gas chromatography and thermogravimetry. Tie line composition quality was verified using Othmer-Tobias and Hand correlation equations. The distribution and selectivity coefficients were calculated for the immiscibility regions. The experimental tie line data exhibited good correlation in the UNIQUAC and NRTL thermodynamic models. The biodiesel system displayed deviations of 0.66 and 0.53% for the UNIQUAC and NRTL models, respectively. In addition, the methyl palmitate system showed a 1.23 and 0.48% deviation for the UNIQUAC and NRTL model, respectively. The individual behavior of the main biodiesel esters , based on the UNIQUAC model parameters, demonstrated that the type of fatty acid does not interfere in model correlation, likely due to the similarity between their composition and properties.

References

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  • T. Wannachod, M. Hronec, T. Soták, K. Fulajtárová, U. Pancharoen, A. Arpornwichanop, "Effects of salt on the LLE and tie-line data for furfuryl alcohol - N-butanol-water at T = 298.15 K," J. Mol. Liq., 218, 50–58, 2016, https://doi.org/10.1016/j.molliq.2016.02.027.
  • M. Maghami, J. Yousefi Seyf, S.M. Sadrameli, A. Haghtalab, "Liquid-liquid phase equilibrium in ternary mixture of waste fish oil biodiesel-methanol-glycerol: Experimental data and thermodynamic modeling," Fluid Phase Equilib., 409, 124–130, 2016, https://doi.org/10.1016/j.fluid.2015.09.046.
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  • B. Bazooyar, F. Shaahmadi, M.A. Anbaz, A. Jomekian, "Intelligent modelling and analysis of biodiesel/alcohol/glycerol liquid-liquid equilibria," J. Mol. Liq., 322, 114972, 2021, https://doi.org/10.1016/j.molliq.2020.114972.
  • M.A. Noriega, P.C. Narváez, "UNIFAC correlated parameters for liquid-liquid equilibrium prediction of ternary systems related to biodiesel production process," Fuel., 249, 365–378, 2019, https://doi.org/10.1016/j.fuel.2019.03.124.
  • L.A. Follegatti-Romero, M.B. Oliveira, F.R.M. Batista, E.A.C. Batista, J.A.P. Coutinho, A.J.A. Meirelles, "Liquid-liquid equilibria for ternary systems containing ethyl esters, ethanol and glycerol at 323.15 and 353.15 K," Fuel., 94, 386–394, 2012, https://doi.org/10.1016/j.fuel.2011.09.020.
  • M. Toikka, P. Kuzmenko, A. Samarov, M. Trofimova, "Phase behavior of the oleic acid – methanol – methyl oleate – water mixture as a promising model system for biodiesel production: Brief data review and new results at 303.15 K and atmospheric pressure," Fuel., 319, 2022, https://doi.org/10.1016/j.fuel.2022.123730.
  • R.N. Cavalcanti, M.B. Oliveira, A.J.A. Meirelles, "Liquid-liquid equilibria for systems containing fatty acid ethyl esters, ethanol and glycerol at 333.15 and 343.15 K: Experimental data, thermodynamic and artificial neural network modeling," Brazilian J. Chem. Eng., 35, 819–834, 2018, https://doi.org/10.1590/0104-6632.20180352s20160267.
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There are 52 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Research Articles
Authors

Jessyca Bezerra

Maria Rosiane De Alemeida Andrade

Edyjancleide Rodrigues Silva

Lindemberg De Jesus Nogueira Duarte

Gilson Gomes Medeiros

Eduardo Lins De Barros Neto

Publication Date December 1, 2022
Published in Issue Year 2022 Volume: 25 Issue: 4

Cite

APA Bezerra, J., Andrade, M. R. D. A., Silva, E. R., Duarte, L. D. J. N., et al. (2022). Thermodynamic Modeling of Liquid-Liquid Equilibrium in Ternary Systems with Biodiesel and Isolated Ester (Methyl Palmitate). International Journal of Thermodynamics, 25(4), 56-65. https://doi.org/10.5541/ijot.1136615
AMA Bezerra J, Andrade MRDA, Silva ER, Duarte LDJN, Medeiros GG, Barros Neto ELD. Thermodynamic Modeling of Liquid-Liquid Equilibrium in Ternary Systems with Biodiesel and Isolated Ester (Methyl Palmitate). International Journal of Thermodynamics. December 2022;25(4):56-65. doi:10.5541/ijot.1136615
Chicago Bezerra, Jessyca, Maria Rosiane De Alemeida Andrade, Edyjancleide Rodrigues Silva, Lindemberg De Jesus Nogueira Duarte, Gilson Gomes Medeiros, and Eduardo Lins De Barros Neto. “Thermodynamic Modeling of Liquid-Liquid Equilibrium in Ternary Systems With Biodiesel and Isolated Ester (Methyl Palmitate)”. International Journal of Thermodynamics 25, no. 4 (December 2022): 56-65. https://doi.org/10.5541/ijot.1136615.
EndNote Bezerra J, Andrade MRDA, Silva ER, Duarte LDJN, Medeiros GG, Barros Neto ELD (December 1, 2022) Thermodynamic Modeling of Liquid-Liquid Equilibrium in Ternary Systems with Biodiesel and Isolated Ester (Methyl Palmitate). International Journal of Thermodynamics 25 4 56–65.
IEEE J. Bezerra, M. R. D. A. Andrade, E. R. Silva, L. D. J. N. Duarte, G. G. Medeiros, and E. L. D. Barros Neto, “Thermodynamic Modeling of Liquid-Liquid Equilibrium in Ternary Systems with Biodiesel and Isolated Ester (Methyl Palmitate)”, International Journal of Thermodynamics, vol. 25, no. 4, pp. 56–65, 2022, doi: 10.5541/ijot.1136615.
ISNAD Bezerra, Jessyca et al. “Thermodynamic Modeling of Liquid-Liquid Equilibrium in Ternary Systems With Biodiesel and Isolated Ester (Methyl Palmitate)”. International Journal of Thermodynamics 25/4 (December 2022), 56-65. https://doi.org/10.5541/ijot.1136615.
JAMA Bezerra J, Andrade MRDA, Silva ER, Duarte LDJN, Medeiros GG, Barros Neto ELD. Thermodynamic Modeling of Liquid-Liquid Equilibrium in Ternary Systems with Biodiesel and Isolated Ester (Methyl Palmitate). International Journal of Thermodynamics. 2022;25:56–65.
MLA Bezerra, Jessyca et al. “Thermodynamic Modeling of Liquid-Liquid Equilibrium in Ternary Systems With Biodiesel and Isolated Ester (Methyl Palmitate)”. International Journal of Thermodynamics, vol. 25, no. 4, 2022, pp. 56-65, doi:10.5541/ijot.1136615.
Vancouver Bezerra J, Andrade MRDA, Silva ER, Duarte LDJN, Medeiros GG, Barros Neto ELD. Thermodynamic Modeling of Liquid-Liquid Equilibrium in Ternary Systems with Biodiesel and Isolated Ester (Methyl Palmitate). International Journal of Thermodynamics. 2022;25(4):56-65.