Investigation of Single Crystal and Polycrystalline Forms of Copper(II) and Vanadium(II) Doped Beta Potassium Sulfate Complex by Electron Spin Resonance Technique

Murat Kurt; Fahri Çelik

doi:10.29132/ijpas.316870

Research Article

Investigation of Single Crystal and Polycrystalline Forms of Copper(II) and Vanadium(II) Doped Beta Potassium Sulfate Complex by Electron Spin Resonance Technique

Year 2017, Volume: 3 Issue: 2, 33 - 39, 28.12.2017

Murat Kurt Fahri Çelik

https://doi.org/10.29132/ijpas.316870

Cited By: 1

Abstract

In this study, single crystal and powder of Cu²⁺ and V²⁺
transition metal ions doped potassium sulphate complex were evaluated by electron
spin resonance (ESR) technique. For Cu²⁺doped complex were determined four paramagnetic centers and g and A values
were found for each of the paramagnetic centers. g and A values obtained for
the single crystal were found to be in agreement with the g and A values
obtained for the powder form of this complex. The angles between the
experimental axis set and the actual axes were determined. Molecular binding
coefficients for each paramagnetic centers and powder form calculated. The
values obtained from the spectras, in the regions where the Cu²⁺ions are located, it is concluded that the neighbors of
the paramagnetic centers are the rhombic symmetry (low symmetry). Similar
measurements were made for the powder form of the V²⁺ transition
metal ion doped potassium sulphate complex. According to the datas obtained
from the powder spectrum,itis concluded that the neighbors in the region where
the ion is placed are compatible with the axial symmetry. Also g and A values were
obtained for this structure.

Keywords

ESR analysis, single crystal, Cu2+ and V2+ doping, single crystal

References

Andriyevsky, B., Romanyuk, M., Stadnyk, V., 2009. Simulation of elasto optical properties of K2SO4 crystals. Journal of Physics and Chemistyr of Solids, 70:1109-1112.
Anooz, S.B., Bertram, R., Klimm, D., 2006. The solid state phase transformation of potassium sulphate. Solid State Communications, 1:1-11.
Dhair, T.A., Saadi, T.M., 2015. Effect of thermal neutron irradiation on the growth and structure of K2SO4 crystal. Advances in Physics Theories and Applications, 39:48-54.
Freeman, T.E., Pilbrow, J.R., 1974. The low-symmetry EPR spectrum of divalent copper ions in potassium and rubidium sulphate. IOP Science, Journal of Physics C: Solid State Physics, 7:2933-2939.
Goeder, F.P., 1927. The space group of potassium, rubidium and caesium sulphates. Proceedings of the National Academy of Sciences of the United States of America, 13:793-797.
Liu, D., Lu, M., Ullman, F.G., Hardy, J.R., 1991. First- principles study of the lattice dynamics of K2SO4. APS Physics Physical Review B, 43(7):6202-6203.
Onodera, A., Sawada, T., Kawamura, Y., Takama, T., Fujita, M., Yamashita, H., 1998. X-ray and thermal study of β-K2SO4-type K2BeF4. Journal of Korean Physical Society, 32:73-76.
Robinson, M. T., 1958. The crystal structure of β-K2SO4 and of K2PO3F. Solid State Division, 62:925-928.
Weckhuysen, B.M., Heidler, R., Schoonheydt, R.A. 2004. Electron spin resonance spectroscopy. Molecular Sieves, Part of the Molecular Sieves – Science and Technology book series (SIEVES), 4:295-335.
Wertz, J.E., Bolton, J.R., 1972. Electron spin resonance elementary theory and practical application. Mcgraw-Hill, Newyork.
Yıldırım, P., 2013. Pridin-2,6 dikarboksilik asit, orotik asit, metabüsilfit, sakkarin, imidazol ve metil imidazol geçiş metal komplekslerinin X ışını, EPR ve optik soğurma teknikleri ile incelenmesi. Doktora Tezi, Ondokuz Mayıs Üniversitesi Fen Bilimleri Enstitüsü, Samsun.
Yerli, Y., 2002. Bazı inorganik yapılarda katkılanma ve ışınlama ile oluşturulan bozuklukların EPR ile incelenmesi. Doktora Tezi, Ondokuz Mayıs Üniversitesi Fen Bilimleri Enstitüsü, Samsun.

Bakır(II) ve Vanadyum(II) Katkılı Beta Potasyum Sülfat Kompleksinin Tek Kristal ve Polikristal Formlarının Elektron Spin Rezonans Tekniği ile İncelenmesi

Year 2017, Volume: 3 Issue: 2, 33 - 39, 28.12.2017

Murat Kurt Fahri Çelik

https://doi.org/10.29132/ijpas.316870

Cited By: 1

Abstract

Bu çalışmada Cu²⁺ ve V²⁺ katkılı beta potasyum
sülfat kompleksinin tek kristal ve toz formlarının elektron spin rezonans (ESR)
tekniği ile analizi yapıldı. Cu²⁺katkılı kompleks için dört ayrı paramanyetik merkezin varlığı tespit edildi.
Her bir paramanyetik merkez için, g ve A değerleri bulundu. Toz için yapılan
incelemede bulunan g ve A değerlerinin, tek kristal ölçümleri ile elde edilen sonuçlar
ile uyum içinde olduğu görüldü. Seçilen deneysel eksen takımları ile gerçek eksenler
arasındaki açılar tespit edildi. Her bir paramanyetik merkez ve toz form için moleküler
bağ kat sayıları hesaplandı. Sonuç olarak bakır iyonunun yerleştiği bölgede ligandlar
ile komşuluğunun (düşük simetrili) rombik simetriye uyduğu sonucuna varıldı.
Benzer ölçümler V²⁺ katkılı beta-potasyum
sülfat kompleksinin toz formu içinde yapıldı. Toz spektrumdan elde edilen verilere
göre iyonun yerleştiği bölgede komşuları ile eksensel simetriye uyumlu bir şekilde
konumlandığı tespite dildi. Bu yapı için g ve A değerleri tespit edildi.

Keywords

ESR analizi, tek kristal, Cu2+ ve V2+ katkılama, tek kristal

References

Andriyevsky, B., Romanyuk, M., Stadnyk, V., 2009. Simulation of elasto optical properties of K2SO4 crystals. Journal of Physics and Chemistyr of Solids, 70:1109-1112.
Anooz, S.B., Bertram, R., Klimm, D., 2006. The solid state phase transformation of potassium sulphate. Solid State Communications, 1:1-11.
Dhair, T.A., Saadi, T.M., 2015. Effect of thermal neutron irradiation on the growth and structure of K2SO4 crystal. Advances in Physics Theories and Applications, 39:48-54.
Freeman, T.E., Pilbrow, J.R., 1974. The low-symmetry EPR spectrum of divalent copper ions in potassium and rubidium sulphate. IOP Science, Journal of Physics C: Solid State Physics, 7:2933-2939.
Goeder, F.P., 1927. The space group of potassium, rubidium and caesium sulphates. Proceedings of the National Academy of Sciences of the United States of America, 13:793-797.
Liu, D., Lu, M., Ullman, F.G., Hardy, J.R., 1991. First- principles study of the lattice dynamics of K2SO4. APS Physics Physical Review B, 43(7):6202-6203.
Onodera, A., Sawada, T., Kawamura, Y., Takama, T., Fujita, M., Yamashita, H., 1998. X-ray and thermal study of β-K2SO4-type K2BeF4. Journal of Korean Physical Society, 32:73-76.
Robinson, M. T., 1958. The crystal structure of β-K2SO4 and of K2PO3F. Solid State Division, 62:925-928.
Weckhuysen, B.M., Heidler, R., Schoonheydt, R.A. 2004. Electron spin resonance spectroscopy. Molecular Sieves, Part of the Molecular Sieves – Science and Technology book series (SIEVES), 4:295-335.
Wertz, J.E., Bolton, J.R., 1972. Electron spin resonance elementary theory and practical application. Mcgraw-Hill, Newyork.
Yıldırım, P., 2013. Pridin-2,6 dikarboksilik asit, orotik asit, metabüsilfit, sakkarin, imidazol ve metil imidazol geçiş metal komplekslerinin X ışını, EPR ve optik soğurma teknikleri ile incelenmesi. Doktora Tezi, Ondokuz Mayıs Üniversitesi Fen Bilimleri Enstitüsü, Samsun.
Yerli, Y., 2002. Bazı inorganik yapılarda katkılanma ve ışınlama ile oluşturulan bozuklukların EPR ile incelenmesi. Doktora Tezi, Ondokuz Mayıs Üniversitesi Fen Bilimleri Enstitüsü, Samsun.

There are 12 citations in total.

Details

Subjects	Engineering
Journal Section	Articles
Authors	Murat Kurt Fahri Çelik This is me
Publication Date	December 28, 2017
Submission Date	May 29, 2017
Acceptance Date	November 10, 2017
Published in Issue	Year 2017 Volume: 3 Issue: 2

Cite

APA	Kurt, M., & Çelik, F. (2017). Investigation of Single Crystal and Polycrystalline Forms of Copper(II) and Vanadium(II) Doped Beta Potassium Sulfate Complex by Electron Spin Resonance Technique. International Journal of Pure and Applied Sciences, 3(2), 33-39. https://doi.org/10.29132/ijpas.316870
AMA	Kurt M, Çelik F. Investigation of Single Crystal and Polycrystalline Forms of Copper(II) and Vanadium(II) Doped Beta Potassium Sulfate Complex by Electron Spin Resonance Technique. International Journal of Pure and Applied Sciences. December 2017;3(2):33-39. doi:10.29132/ijpas.316870
Chicago	Kurt, Murat, and Fahri Çelik. “Investigation of Single Crystal and Polycrystalline Forms of Copper(II) and Vanadium(II) Doped Beta Potassium Sulfate Complex by Electron Spin Resonance Technique”. International Journal of Pure and Applied Sciences 3, no. 2 (December 2017): 33-39. https://doi.org/10.29132/ijpas.316870.
EndNote	Kurt M, Çelik F (December 1, 2017) Investigation of Single Crystal and Polycrystalline Forms of Copper(II) and Vanadium(II) Doped Beta Potassium Sulfate Complex by Electron Spin Resonance Technique. International Journal of Pure and Applied Sciences 3 2 33–39.
IEEE	M. Kurt and F. Çelik, “Investigation of Single Crystal and Polycrystalline Forms of Copper(II) and Vanadium(II) Doped Beta Potassium Sulfate Complex by Electron Spin Resonance Technique”, International Journal of Pure and Applied Sciences, vol. 3, no. 2, pp. 33–39, 2017, doi: 10.29132/ijpas.316870.
ISNAD	Kurt, Murat - Çelik, Fahri. “Investigation of Single Crystal and Polycrystalline Forms of Copper(II) and Vanadium(II) Doped Beta Potassium Sulfate Complex by Electron Spin Resonance Technique”. International Journal of Pure and Applied Sciences 3/2 (December 2017), 33-39. https://doi.org/10.29132/ijpas.316870.
JAMA	Kurt M, Çelik F. Investigation of Single Crystal and Polycrystalline Forms of Copper(II) and Vanadium(II) Doped Beta Potassium Sulfate Complex by Electron Spin Resonance Technique. International Journal of Pure and Applied Sciences. 2017;3:33–39.
MLA	Kurt, Murat and Fahri Çelik. “Investigation of Single Crystal and Polycrystalline Forms of Copper(II) and Vanadium(II) Doped Beta Potassium Sulfate Complex by Electron Spin Resonance Technique”. International Journal of Pure and Applied Sciences, vol. 3, no. 2, 2017, pp. 33-39, doi:10.29132/ijpas.316870.
Vancouver	Kurt M, Çelik F. Investigation of Single Crystal and Polycrystalline Forms of Copper(II) and Vanadium(II) Doped Beta Potassium Sulfate Complex by Electron Spin Resonance Technique. International Journal of Pure and Applied Sciences. 2017;3(2):33-9.