Alizarin Red Boyar Maddesinin Dietilaminodekstran/Epiklorohidrin (DEAE-D/ECH) Kriyojeli ile Sulu Çözeltiden Gideriminin Araştırılması
Year 2021,
Volume: 7 Issue: 3, 383 - 390, 31.12.2021
Celile Demirbilek Bucak
,
Cemile Özdemir Dinç
Abstract
Bu çalışmada, polimerik adsorban dietilamino etil dekstran/epiklorohidrinin (DEAE-D/ECH) kriyojelinin sudan boyar madde adsorplama yeteneği araştırılmıştır. Dietilamino etil dekstran/epiklorohidrinin kriyojeli ile suda çözünen Alizarin Red boyar maddesinin etkileşim mekanizması açıklanmıştır. Adsorpsiyondan önce ve sonra yapılan FTIR analizleri ve yüzey morfolojik analizler ile adsorpsiyonun mekanizması belirlenmiştir. Dietilamino etil dekstran/epiklorohidrinin kriyojelinin saf suda (% 2630) ve Alizarin Red boyası çözeltisinde (%1678) yüksek şişme oranına sahip olduğu görülmüştür. Adsorpsiyona başlangıç boya derişiminin etkisi ve Langmuir ve Freundlich izotermlerine uygunluğu araştırılmıştır. Sonuç olarak Alizarin Red boyasının dietilamino etil dekstran/epiklorohidrinin kriyojeline adsorpsiyonunun Langmuir izotermine göre uygun olduğu belirlenmiştir.
Supporting Institution
HMKÜBAP
References
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Investigation of the removal of Alizarin Red dye from aqueous solution with Diethylaminodextran / Epichlorohydrin (DEAE-D / ECH) cryogel
Year 2021,
Volume: 7 Issue: 3, 383 - 390, 31.12.2021
Celile Demirbilek Bucak
,
Cemile Özdemir Dinç
Abstract
This study describes the dyestuff removal ability of diethylaminoethyl-dextran–epichlorohydrin cryogel polymeric adsorbents. The interaction between diethylaminoethyl-dextran–epichlorohydrin cryogel and a water-soluble dyestuff, Alizarin Red, was investigated. The mechanism of adsorption is explained with fourier transform infrared analyzes and surface morphological analyzes performed before and after adsorption. Diethylaminoethyl-dextran–epichlorohydrin cryogel was found to have a high swelling rate in pure water (2630%) and Alizarin Red dye solution (1678%). The effect of initial dye concentration on adsorption and its suitability to the Langmuir and Freundlich isotherms were investigated. As a result, it was determined that the adsorption of Alizarin Red dye to diethylaminoethyl-dextran–epichlorohydrin cryogel was appropriate according to the Langmuir isotherm.
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- Fayazi, M., Ghanei-Motlagh, M., & Taher, M. A. (2015). The adsorption of basic dye (Alizarin red S) from aqueous solution onto activated carbon/γ-Fe2O3 nano-composite: kinetic and equilibrium studies. Materials Science in Semiconductor Processing, 40, 35-43.
- García-González, A., Zavala-Arce, R. E., Avila-Pérez, P., Rangel-Vazquez, N. A., Salazar-Rábago, J. J., García-Rivas, J. L., & García-Gaitán, B. (2021). Experimental and theoretical study of dyes adsorption process on chitosan-based cryogel. International Journal of Biological Macromolecules, 169, 75-84.
- Hu, X., Yan, L., Wang, Y., & Xu, M. (2020). Freeze-thaw as a route to build manageable polysaccharide cryogel for deep cleaning of crystal violet. Chemical Engineering Journal, 396, 125354.
- Hu, Y., Yue, M., Yuan, F., Yang, L., Chen, C., & Sun, D. (2021). Bio-inspired fabrication of highly permeable and anti-fouling ultrafiltration membranes based on bacterial cellulose for efficient removal of soluble dyes and insoluble oils. Journal of Membrane Science, 621, 118982.
- Hussain, S., Kamran, M., Khan, S. A., Shaheen, K., Shah, Z., Suo, H., ... & Ghani, U. (2021). Adsorption, kinetics and thermodynamics studies of methyl orange dye sequestration through chitosan composites films. International Journal of Biological Macromolecules, 168, 383-394.
- Jabeen, U., Shah, S. M., & Khan, S. U. (2017). Photo catalytic degradation of Alizarin red S using ZnS and cadmium doped ZnS nanoparticles under unfiltered sunlight. Surfaces and Interfaces, 6, 40-49.
- Jian, W. A. N. G., Qin-Mei, W. A. N. G., Li-Li, T. I. A. N., Chen, Y. A. N. G., Su-Hua, Y. U., & Chun, Y. A. N. G. (2015). Research progress of the molecularly imprinted cryogel. Chinese Journal of Analytical Chemistry, 43(11), 1777-1784.
- Legan, L., Retko, K., & Ropret, P. (2016). Vibrational spectroscopic study on degradation of alizarin carmine. Microchemical Journal, 127, 36-45.
- Lin, J., Su, T., Chen, J., Xue, T., Yang, S., Guo, P., ... & Li, J. (2021). Efficient adsorption removal of anionic dyes by an imidazolium-based mesoporous poly (ionic liquid) including the continuous column adsorption-desorption process. Chemosphere, 129640.
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- Mittal, H., Al Alili, A., Morajkar, P. P., & Alhassan, S. M. (2021). Graphene oxide crosslinked hydrogel nanocomposites of xanthan gum for the adsorption of crystal violet dye. Journal of Molecular Liquids, 323, 115034.
- Onder, A., Ilgin, P., Ozay, H., & Ozay, O. (2020). Removal of dye from aqueous medium with pH-sensitive poly [(2-(acryloyloxy) ethyl] trimethylammonium chloride-co-1-vinyl-2-pyrrolidone] cationic hydrogel. Journal of Environmental Chemical Engineering, 8(5), 104436.
- Qian, W., Huang, H., Diao, Z., Li, H., Liu, H., Ye, M., ... & Xu, Z. (2021). Advanced treatment of dye wastewater using a novel integrative Fenton-like/MnO2-filled upward flow biological filter bed system equipped with modified ceramsite. Environmental Research, 194, 110641.
- Salem, S., Teimouri, Z., & Salem, A. (2020). Fabrication of magnetic activated carbon by carbothermal functionalization of agriculture waste via microwave-assisted technique for cationic dye adsorption. Advanced Powder Technology, 31(10), 4301-4309.
- Sarkar, S., Banerjee, A., Halder, U., Biswas, R., & Bandopadhyay, R. (2017). Degradation of synthetic azo dyes of textile industry: a sustainable approach using microbial enzymes. Water Conservation Science and Engineering, 2(4), 121-131.
- Svedman, C., Engfeldt, M., & Malinauskiene, L. (2019). Textile contact dermatitis: How fabrics can induce dermatitis. Current Treatment Options in Allergy, 6(1), 103-111.
- Tanaydın, Z. B., Tanaydın, M. K., Demirkıran, N., & Muharrem, İ. N. C. E. (2020). Bakır ve Kadmiyumun Perlit İle Adsorpsiyonu ve Adsorpsiyon Özelliklerinin Karşılaştırılması. International Journal of Pure and Applied Sciences, 6(2), 208-218.
- Vo, T. K., Trinh, T. P., Nguyen, V. C., & Kim, J. (2021). Facile synthesis of graphite oxide/MIL-101 (Cr) hybrid composites for enhanced adsorption performance towards industrial toxic dyes. Journal of Industrial and Engineering Chemistry, 95, 224-234.
- Wang, H., Li, Z., Yahyaoui, S., Hanafy, H., Seliem, M. K., Bonilla-Petriciolet, A., ... & Li, Q. (2020). Effective adsorption of dyes on an activated carbon prepared from carboxymethyl cellulose: Experiments, characterization and advanced modelling. Chemical Engineering Journal, 128116.
- Zhu, C., Jiang, C., Chen, S., Mei, R., Wang, X., Cao, J., ... & Zhou, K. (2018). Ultrasound enhanced electrochemical oxidation of Alizarin Red S on boron doped diamond (BDD) anode: Effect of degradation process parameters. Chemosphere, 209, 685-695.