Atık Su Örneklerinde Bazı Ağır Metallerin İndüktif Eşleşmiş Plazma Kütle Spektrometresi ile (ICP-MS) Tayini

Yıl 2020, Cilt: 5 Sayı: 1, 56 - 60, 31.03.2020

Zekeriyya Bahadır

https://doi.org/10.35229/jaes.667255

Öz

Bu çalışmada Giresun ilinde farklı oto yıkama merkezlerinin atik su içeriğindeki kadmiyum (Cd), arsenik (As), kurşun (Pb), nikel (Ni) ve krom (Cr) metalleri indüktif eşleşmiş plazma kütle spektrometresi (ICP-MS) ile tayin edilmiştir. Bu amaçla, belirlenen istasyonlardan toplanan su numuneleri, 0,45 µm membran filtreden süzülmüş ve tayin öncesinde asitlendirilerek metal içerikleri analiz edilmiştir. Elde edilen veriler Dünya Sağlık Örgütü (WHO), Amerika Birleşik Devletleri Çevre Koruma Ajansı (EPA) ve Türk Standartları Enstitüsü’nün içme ve kullanım sularında metal içerikleri için belirlenen sınır değerler kullanılarak tartışılmıştır. Analiz edilen atık su numuneleri için metal konsantrasyonları; As (15,2±0,3 µg L-1), Pb (26,9±0,4 µg L-1), Ni (31,5±1,1 µg L-1) ve Cr (9,8±0,4 µg L-1) olarak tespit edilmiştir. Ölçümlerin doğruluğu, numune matriksine ekleme/geri kazanım yöntemi kullanılarak belirlenmiştir. Elde edilen geri kazanım değerleri %88-108 arasında bulunmuştur.

Anahtar Kelimeler

Ağır metal, atık su, ICP-MS

Proje Numarası

300318-90

Kaynakça

• Akieh, M.N., Lahtinen, M., Väisänen, A. & Sillanpää, M. (2008). Preparation and characterization of sodium iron titanate ion exchanger and its application in heavy metal removal from waste waters, Journal of Hazardous Materials, 152, 640-647.
• Al Rmalli, S.W., Harrington, C.F., Ayub, M. & Haris, P.I. (2005). A biomaterial based approach for arsenic removal from water, Journal of Environmental Monitoring, 7, 279-282.
• Ali, M. (2007). Preconcentration and Determination of Trace Amounts of Heavy Metals in Water Samples Using Membrane Disk and Flame Atomic Absorption Spectrometry, Chinese Journal of Chemistry, 25, 640-644.
• Almeida, J.C., Cardoso, C.E.D., Tavares, D.S., Freitas, R., Trindade, T., Vale, C. & Pereira, E. (2019). Chromium removal from contaminated waters using nanomaterials e A review, Trends in Analytical Chemistry, 118, 277-291.
• Álvarez-Ayuso, E., Garcı́a-Sánchez, A. & Qquerol, X. (2003). Purification of metal electroplating waste waters using zeolites, Water Research, 37, 4855-4862.
• Assis, R.C., Faria, B.A.A., Caldeira, C.L., Mageste, A.B., Lemos, L.R.de. & Rodriguesa, G.D. (2019). Extraction of arsenic (III) in aqueous two-phase systems: A new methodology for determination and speciation analysis of inorganic arsenic, Microchemical Journal, 147, 429-436.
• Dressler, V.L., Pozebon, D., Matusch, A. & Becker J.S. (2007). Micronebulization for trace analysis of lanthanides in small biological specimens by ICP-MS, International Journal of Mass Spectrometry, 266, 25-33.
• Duffus, J.H. (2002). “Heavy Metals”-A meaningless term? Pure and Applied Chemistry, 74, 93-807.
• EPA (US Environmental Protection Agency). (2018). Edition of the Drinking Water Standards and Health Advisories EPA, 822-F-18-001, Washington, DC.
• Grant R.L. & Grant E. (1987). Grant and Hackh’s Chemical Dictionary, 5th ed., McGraw-Hill, New York, 657p.
• Gürkan, R., Kır, U. & Altunay, N. (2015). Development of a simple, sensitive and inexpensive ion-pairing cloud point extraction approach for the determination of trace inorganic arsenic species in spring water, beverage and rice samples by UV–Vis spectrophotometry, Food Chemistry, 180, 32-41.
• Jahromi, E.Z., Bidari, A., Assadi, Y., Hosseini, M.R.M. & Jamali, M.R. (2007). Dispersive liquid–liquid microextraction combined with graphite furnace atomic absorption spectrometry Ultra trace determination of cadmium in water samples, Analytica Chimica Acta, 585, 305-311.
• Karve, M. & Rajgor, R.V. (2009). Octadecyl bonded silica membrane disk modified with Cyanex302 for separation and flame atomic absorption spectrometric determination of nickel from tap water and industrial effluent, Journal of Hazardous Materials, 166, 576-580.
• Khajeh, M., Sarafraz-Yazdi, A. & Moghadam, A.F. (2017). Modeling of solid-phase tea waste extraction for the removal of manganese and cobalt from water samples by using PSO-artificial neural network and response surface methodology, Arabian Journal of Chemistry, 10, 1663-1673.
• Liang, P. & Sang H. (2008). Speciation of chromium in water samples with cloud point extraction separation and preconcentration and determination by graphite furnace atomic absorption spectrometry, Journal of Hazardous Materials, 154, 1115-1119.
• Lingling, Z., Shuxian, Z., Keming, F., Zhaosheng, Q. & Jianrong, C. (2012). Determination of cadmium (II), cobalt (II), nickel (II), lead (II), zinc (II), and copper (II) in water samples using dual cloud point extraction and inductively coupled plasma emission spectrometry, Journal of Hazardous Materials, 239, 206-212.
• Mansel, C., Fross, S., Rose, J., Dema, E., Mann, A., Hart, H., Klawinski, P. & Vohra, B.P.S. (2019). Lead exposure reduces survival, neuronal determination, and differentiation of P19 stem cells, Neurotoxicology and Teratology, 72, 8-70.
• Maxwell III, S.L. & Jones, V.D. (2009). Rapid determination of actinides in urine by inductively coupled plasma mass spectrometry and alpha spectrometry: A hybrid approach, Talanta, 80, 143-150.
• Mikuła, B. & Puzio, B. (2007). Determination of trace metals by ICP-OES in plant materials after preconcentration of 1,10-phenanthroline complexes on activated carbon, Talanta, 71, 136-140.
• Montaser, A (1998). Inductively Coupled Plasma Mass Spectrometry, 1rd ed., Wiley-VCH, USA, 1004p.
• Nazari, S. (2009). Liquid phase microextraction and ultratrace determination of cadmium by modified graphite furnace atomic absorption spectrometry, Journal of Hazardous Materials, 165, 200-205.
• TSE (Türk Standartları Enstitüsü). (2005). Türk Standardı, Sular-İnsani Tüketim Amaçlı Sular, Ankara.
• Urdaneta, C., Parra, L.M.M., Matute, S., Garaboto, M.A., Barros, H. & Vázquezde, C. (2008). Evaluation of vermicompost as bioadsorbent substrate of Pb, Ni, V and Cr for waste waters remediation using Total Reflection X-ray Fluorescence, Spectrochimica Acta Part B: Atomic Spectroscopy, 63, 1455-1460.
• Vinodh, R., Padmavathi, R. & Sangeetha, D. (2011). Separation of heavy metals from water samples using anion exchange polymers by adsorption process, Desalination, 267, 267-276.
• WHO (World Health Organization). (2011). Guidelines for Drinking-water Quality, fourth edition, Geneva.