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Investigation of Gamma Radiation Shielding in NiMnGa-Doped Multifunctional Smart Polymer Composites Using Geant4 and WinXCOM

Year 2024, Volume: 10 Issue: 4, 861 - 874, 31.12.2024
https://doi.org/10.28979/jarnas.1554352

Abstract

This study assesses the gamma radiation shielding efficiency of polymer composites doped with varying amounts of alloy, using software to demonstrate the potential application of innovative materials in radiation protection. Specifically, Poly Lactic Acid (PLA) and Poly Ethylene Glycol (PEG) composites doped with NiMnGa at concentrations of 2, 6, 10, and 15% were analyzed across an energy range of 0.0595 to 1.41 MeV using Geant4 and WinXCOM software. The radiation protection ability of the composites and the pure alloy were assessed by calculating key parameters, including the mass attenuation coefficient (μm), linear attenuation coefficient (μ), half value layer (HVL), tenth value layer (TVL), and mean free path (MFP). The analyses indicated strong agreement between the results obtained from Geant4 and WinXCOM, demonstrating the performance of the software in investigating the radiation shielding characteristics of polymer-based materials. It was investigated that increasing the amount of NiMnGa in the composite structure significantly enhanced its radiation shielding capabilities. Notably, composites with 15% NiMnGa exhibited superior performance, comparable to traditional heavy metals, while maintaining the lightweight and flexible nature of polymer-based materials. The strong agreement between Geant4 and WinXCOM results further validates the computational approach. These findings highlight the potential of NiMnGa-doped polymer composites as eco-friendly, cost-effective alternatives to lead-based shields for medical and industrial applications, offering enhanced protection with reduced toxicity and environmental impact.

Project Number

FF.24.23

Thanks

This work was supported by the Management Unit of the Scientific Research Projects of Fırat University (FUBAP), Grant number: FF.24.23.

References

  • M. E. Mahmoud, A. M. El-Khatib, M. S. Badawi, A. R. Rashad, R. M. El-Sharkawy, A. A. Thabet, Fabrication, characterization and gamma rays shielding properties of nano and micro lead oxide-dispersed-high density polyethylene composites, Radiation Physics and Chemistry 145 (2018) 160–173.
  • R. K. Chaurasia, B. K. Sapra, D. K. Aswal, Interplay of immune modulation, adaptive response and hormesis: Suggestive of threshold for clinical manifestation of effects of ionizing radiation at low doses?, Science of the Total Environment 917 (2024) 170178 18 pages.
  • A. H. Taqi, A. M. Ghalib, H. N. Mohammed, Shielding properties of Cu-Sn-Pb alloy by Geant4, XCOM and experimental data, Materials Today Communications 26 (2021) 101996 12 pages.
  • T. A. A. Junior, M.S. Nogueira, V. Vivolo, M. P. A. Potiens, L.L. Campos, Mass attenuation coefficients of X-rays in different barite concrete used in radiation protection as shielding against ionizing radiation, Radiation Physics and Chemistry, 140 (2017) 349–354.
  • H. O. Tekin, T. T. Erguzel, M. I. Sayyed, V. P. Singh, T. Manici, E. E. A. Guclu, O. Agar, An investigation on shielding properties of different granite samples using MCNPX code. Digest Journal of Nanomaterials and Biostructures, 13 (2) (2018) 381–389.
  • O. Agar, Z. Y. Khattari, M. I. Sayyed, H. O. Tekin, S. Al-Omari, M. Maghrabi, M. H. M. Zaid, I.V. Kityk, Evaluation of the shielding parameters of alkaline earth based phosphate glasses using MCNPX code, Results in Physics, 12 (2019) 101–106.
  • M. E. Pekdemir, M. Kaya, M. Coşkun, Y. Aydoğdu, M. Kök, S. Yalcin Kuzu, Physicochemical properties of magnetically enhanced shape memory polymer composites doped with NiMnGa, Journal of Polymer Research, 30 (8) (2023) 293 10 pages.
  • T. Defize, R. Riva, J. M. Raquez, P. Dubois, C. Jérôme, M. Alexandre, Thermoreversibly Crosslinked Poly(ε-caprolactone) as Recyclable Shape-Memory Polymer Network, Macromolecular Rapid Communications, 32(16) (2011) 1264–1269.
  • H. Akhdar, M. Alshehri, Geant4 Simulation of Photon- and Neutron-Shielding Capabilities of Biopolymer Blends of Poly(lactic acid) and Poly(hydroxybutyrate), Polymers, 15(21) (2023) 4257 16 pages.
  • M. Kök, Y. Aydoğdu, Electron Concentration Dependence of Phase Transition and Magnetic Properties in NiMnGa Alloys, Journal of Superconductivity and Novel Magnetism, 26 (2013) 1691–1696.
  • M. Yilmaz, M. E. Pekdemir, E. Ö. Öner, Evaluation of Pb doped Poly(lactic acid) (PLA) / Poly(ethylene glycol) (PEG) blend composites regarding physicochemical and radiation shielding properties, Radiation Physics and Chemistry, 202 (2023) 110509 9 pages.
  • H. Alavian, H. T. Anbaran, Comparative study of mass attenuation coefficients for LDPE/metal oxide composites by Monte Carlo simulations, The European Physical Journal Plus, 135(82) (2020) 9 pages.
  • K. Dilsiz, H. Ogul, F. Akman, O. Agar, M. R. Kacal, H. Polat, İ. Dursun, Evaluation of CdS doped polyester composites regarding gamma and neutron shielding properties, Progress in Nuclear Energy, 139 (2021) 103865 11 pages.
  • F. Kazemi, S. Malekie, M. A. Hosseini, A Monte Carlo Study on the Shielding Properties of a Novel Polyvinyl Alcohol (PVA)/WO3 Composite, Against Gamma Rays, Using the MCNPX Code, Journal of Biomedical Physics and Engineering 9 (4) (2019) 465–472.
  • Z. M. Cinan, B. Erol, T. Baskan, S. Mutlu, S. S. Yilmaz, A. H. Yılmaz, Gamma irradiation and the radiation shielding characteristics: For the lead oxide doped the crosslinked polystyrene-b-polyethyleneglycol block copolymers and the polystyrene-b-polyethyleneglycol-boron nitride nanocomposites, Polymers 13 (19) (2021) 3246 30 pages.
  • S. Nambiar, J. T. W. Yeow, Polymer-composite materials for radiation protection, ACS Applied Materials and Interfaces 4 (11) (2012) 5717–5726.
  • H. Shin, S. Thanakkasaranee, K. Sadeghi, Preparation and characterization of ductile PLA/PEG blend films for eco-friendly flexible packaging application, Food Packaging and Shelf Life 34 (2022) 100966 10 pages.
  • K. I. Matumba, M. P. Motloung, V. Ojijo, S. S. Ray, E. R. Sadiku, Investigation of the effects of chain extender on material properties of PLA/PCL and PLA/PEG blends: Comparative study between polycaprolactone and polyethylene glycol, Polymers 15 (9) (2023) 2230 16 pages.
  • S. Agostinelli, J. Allison, K. Amako, J. Apostolakis, H. Araujo, P. Arce, M. Asai, D. Axen, S. Banerjee, G. Barrand, F. Behner, L. Bellagamba, J. Boudreau, L. Broglia, A. Brunengo, H. Burkhardt, S. Chauvie, J. Chuma, R. Chytracek, G. Cooperman, G. Cosmo, P. Degtyarenko, A. Dell'Acqua, G. Depaola, D. Dietrich, R. Enami, A. Feliciello, C. Ferguson, H. Fesefeldt, G. Folger, F. Foppiano, A. Forti, S. Garelli, S. Giani, R. Giannitrapani, D. Gibin, J. J. Gómez Cadenas, I. González, G. Gracia Abril, G. Greeniaus, W. Greiner, V. Grichine, A. Grossheim, S. Guatelli, P. Gumplinger, R. Hamatsu, K. Hashimoto, H. Hasui, A. Heikkinen, A. Howard, ..., D. Zschiesche, GEANT4 a simulation toolkit, Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment 506 (3) (2003) 250–303.
  • L. Gerward, N. Guilbert, K. B. Jensen, H. Levring, WinXCom a program for calculating X-ray attenuation coefficients, Radiation Physics and Chemistry 71 (3-4) (2004) 653–654.
  • S. Niksarlıoğlu, F. Akman, M. E. Pekdemir, S. Yalcin Kuzu, M. R. Kaçal, M. Yılmaz, An extensive investigation on gamma shielding properties of PLA/Gd2O3 nanocomposites, Radiation Physics and Chemistry 140 (2023) 110936 9 pages.
  • F. Rouihem, M. M. Albarqi, R. A. Alsulami, F.Hosni, Lead-free Gamma-ray shielding: Comparative analysis of elastomeric and fluoro-rubber materials using FLUKA and EGSnrc simulations, Journal of Radiation Research and Applied Sciences 17 (1) (2024) 100834 10 pages.
  • C. M. Davisson, Gamma-ray attenuation coefficients, in: K. Siegbahn (Ed.), Alpha-, Beta-, and Gamma- Ray Spectroscopy, Vol. 1, Elsevier, New York, 1965, App. 1, pp.827–843.
  • K. I. Hussein, M. S. Alqahtani, H. Algarni, H. Zahran, I. S. Yaha, I. Grelowska, M. Reben, E. S. Yousef, MIKE: A new computational tool for investigating radiation, optical and physical properties of prototyped shielding materials, Journal of Instrumentation 16 (07) (2021) T07004 23 pages.
  • A. Sharma, B. Singh, B. S. Sandhu, Investigation of photon interaction parameters of polymeric materials using Monte Carlo simulation, Chinese Journal of Physics 60 (2019) 709–719.
  • M. M. El-Toony, G. Eid, H. M. Algarni, T. F. Alhuwaymel, E. E. Abel-hady, Synthesis and characterisation of smart poly vinyl ester / Pb2O3 nanocomposite for gamma radiation shielding, Radiation Physics and Chemistry 168 (2020) 108536 8 pages.
  • R. Gutzler, M. Garg, A. R. Christian, K. Kuhnke, K. Kern, Light-matter interaction at atomic scales, Nature Reviews Physics 3 (6) (2021) 441–453.
  • Q. Chang, S.Guo, X. Zhang, Radiation shielding polymer composites: Ray-interaction mechanism, structural design, manufacture and biomedical applications, Materials and Design 233 (2023) 112253 21 pages.
  • S. Sharifi, R. Bagheri, S. P. Shirmardi, Comparison of shielding properties for ordinary, barite, serpentine and steel–magnetite concretes using MCNP-4C code and available experimental results, Annals of Nuclear Energy 53 (2019) 529–534.
Year 2024, Volume: 10 Issue: 4, 861 - 874, 31.12.2024
https://doi.org/10.28979/jarnas.1554352

Abstract

Project Number

FF.24.23

References

  • M. E. Mahmoud, A. M. El-Khatib, M. S. Badawi, A. R. Rashad, R. M. El-Sharkawy, A. A. Thabet, Fabrication, characterization and gamma rays shielding properties of nano and micro lead oxide-dispersed-high density polyethylene composites, Radiation Physics and Chemistry 145 (2018) 160–173.
  • R. K. Chaurasia, B. K. Sapra, D. K. Aswal, Interplay of immune modulation, adaptive response and hormesis: Suggestive of threshold for clinical manifestation of effects of ionizing radiation at low doses?, Science of the Total Environment 917 (2024) 170178 18 pages.
  • A. H. Taqi, A. M. Ghalib, H. N. Mohammed, Shielding properties of Cu-Sn-Pb alloy by Geant4, XCOM and experimental data, Materials Today Communications 26 (2021) 101996 12 pages.
  • T. A. A. Junior, M.S. Nogueira, V. Vivolo, M. P. A. Potiens, L.L. Campos, Mass attenuation coefficients of X-rays in different barite concrete used in radiation protection as shielding against ionizing radiation, Radiation Physics and Chemistry, 140 (2017) 349–354.
  • H. O. Tekin, T. T. Erguzel, M. I. Sayyed, V. P. Singh, T. Manici, E. E. A. Guclu, O. Agar, An investigation on shielding properties of different granite samples using MCNPX code. Digest Journal of Nanomaterials and Biostructures, 13 (2) (2018) 381–389.
  • O. Agar, Z. Y. Khattari, M. I. Sayyed, H. O. Tekin, S. Al-Omari, M. Maghrabi, M. H. M. Zaid, I.V. Kityk, Evaluation of the shielding parameters of alkaline earth based phosphate glasses using MCNPX code, Results in Physics, 12 (2019) 101–106.
  • M. E. Pekdemir, M. Kaya, M. Coşkun, Y. Aydoğdu, M. Kök, S. Yalcin Kuzu, Physicochemical properties of magnetically enhanced shape memory polymer composites doped with NiMnGa, Journal of Polymer Research, 30 (8) (2023) 293 10 pages.
  • T. Defize, R. Riva, J. M. Raquez, P. Dubois, C. Jérôme, M. Alexandre, Thermoreversibly Crosslinked Poly(ε-caprolactone) as Recyclable Shape-Memory Polymer Network, Macromolecular Rapid Communications, 32(16) (2011) 1264–1269.
  • H. Akhdar, M. Alshehri, Geant4 Simulation of Photon- and Neutron-Shielding Capabilities of Biopolymer Blends of Poly(lactic acid) and Poly(hydroxybutyrate), Polymers, 15(21) (2023) 4257 16 pages.
  • M. Kök, Y. Aydoğdu, Electron Concentration Dependence of Phase Transition and Magnetic Properties in NiMnGa Alloys, Journal of Superconductivity and Novel Magnetism, 26 (2013) 1691–1696.
  • M. Yilmaz, M. E. Pekdemir, E. Ö. Öner, Evaluation of Pb doped Poly(lactic acid) (PLA) / Poly(ethylene glycol) (PEG) blend composites regarding physicochemical and radiation shielding properties, Radiation Physics and Chemistry, 202 (2023) 110509 9 pages.
  • H. Alavian, H. T. Anbaran, Comparative study of mass attenuation coefficients for LDPE/metal oxide composites by Monte Carlo simulations, The European Physical Journal Plus, 135(82) (2020) 9 pages.
  • K. Dilsiz, H. Ogul, F. Akman, O. Agar, M. R. Kacal, H. Polat, İ. Dursun, Evaluation of CdS doped polyester composites regarding gamma and neutron shielding properties, Progress in Nuclear Energy, 139 (2021) 103865 11 pages.
  • F. Kazemi, S. Malekie, M. A. Hosseini, A Monte Carlo Study on the Shielding Properties of a Novel Polyvinyl Alcohol (PVA)/WO3 Composite, Against Gamma Rays, Using the MCNPX Code, Journal of Biomedical Physics and Engineering 9 (4) (2019) 465–472.
  • Z. M. Cinan, B. Erol, T. Baskan, S. Mutlu, S. S. Yilmaz, A. H. Yılmaz, Gamma irradiation and the radiation shielding characteristics: For the lead oxide doped the crosslinked polystyrene-b-polyethyleneglycol block copolymers and the polystyrene-b-polyethyleneglycol-boron nitride nanocomposites, Polymers 13 (19) (2021) 3246 30 pages.
  • S. Nambiar, J. T. W. Yeow, Polymer-composite materials for radiation protection, ACS Applied Materials and Interfaces 4 (11) (2012) 5717–5726.
  • H. Shin, S. Thanakkasaranee, K. Sadeghi, Preparation and characterization of ductile PLA/PEG blend films for eco-friendly flexible packaging application, Food Packaging and Shelf Life 34 (2022) 100966 10 pages.
  • K. I. Matumba, M. P. Motloung, V. Ojijo, S. S. Ray, E. R. Sadiku, Investigation of the effects of chain extender on material properties of PLA/PCL and PLA/PEG blends: Comparative study between polycaprolactone and polyethylene glycol, Polymers 15 (9) (2023) 2230 16 pages.
  • S. Agostinelli, J. Allison, K. Amako, J. Apostolakis, H. Araujo, P. Arce, M. Asai, D. Axen, S. Banerjee, G. Barrand, F. Behner, L. Bellagamba, J. Boudreau, L. Broglia, A. Brunengo, H. Burkhardt, S. Chauvie, J. Chuma, R. Chytracek, G. Cooperman, G. Cosmo, P. Degtyarenko, A. Dell'Acqua, G. Depaola, D. Dietrich, R. Enami, A. Feliciello, C. Ferguson, H. Fesefeldt, G. Folger, F. Foppiano, A. Forti, S. Garelli, S. Giani, R. Giannitrapani, D. Gibin, J. J. Gómez Cadenas, I. González, G. Gracia Abril, G. Greeniaus, W. Greiner, V. Grichine, A. Grossheim, S. Guatelli, P. Gumplinger, R. Hamatsu, K. Hashimoto, H. Hasui, A. Heikkinen, A. Howard, ..., D. Zschiesche, GEANT4 a simulation toolkit, Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment 506 (3) (2003) 250–303.
  • L. Gerward, N. Guilbert, K. B. Jensen, H. Levring, WinXCom a program for calculating X-ray attenuation coefficients, Radiation Physics and Chemistry 71 (3-4) (2004) 653–654.
  • S. Niksarlıoğlu, F. Akman, M. E. Pekdemir, S. Yalcin Kuzu, M. R. Kaçal, M. Yılmaz, An extensive investigation on gamma shielding properties of PLA/Gd2O3 nanocomposites, Radiation Physics and Chemistry 140 (2023) 110936 9 pages.
  • F. Rouihem, M. M. Albarqi, R. A. Alsulami, F.Hosni, Lead-free Gamma-ray shielding: Comparative analysis of elastomeric and fluoro-rubber materials using FLUKA and EGSnrc simulations, Journal of Radiation Research and Applied Sciences 17 (1) (2024) 100834 10 pages.
  • C. M. Davisson, Gamma-ray attenuation coefficients, in: K. Siegbahn (Ed.), Alpha-, Beta-, and Gamma- Ray Spectroscopy, Vol. 1, Elsevier, New York, 1965, App. 1, pp.827–843.
  • K. I. Hussein, M. S. Alqahtani, H. Algarni, H. Zahran, I. S. Yaha, I. Grelowska, M. Reben, E. S. Yousef, MIKE: A new computational tool for investigating radiation, optical and physical properties of prototyped shielding materials, Journal of Instrumentation 16 (07) (2021) T07004 23 pages.
  • A. Sharma, B. Singh, B. S. Sandhu, Investigation of photon interaction parameters of polymeric materials using Monte Carlo simulation, Chinese Journal of Physics 60 (2019) 709–719.
  • M. M. El-Toony, G. Eid, H. M. Algarni, T. F. Alhuwaymel, E. E. Abel-hady, Synthesis and characterisation of smart poly vinyl ester / Pb2O3 nanocomposite for gamma radiation shielding, Radiation Physics and Chemistry 168 (2020) 108536 8 pages.
  • R. Gutzler, M. Garg, A. R. Christian, K. Kuhnke, K. Kern, Light-matter interaction at atomic scales, Nature Reviews Physics 3 (6) (2021) 441–453.
  • Q. Chang, S.Guo, X. Zhang, Radiation shielding polymer composites: Ray-interaction mechanism, structural design, manufacture and biomedical applications, Materials and Design 233 (2023) 112253 21 pages.
  • S. Sharifi, R. Bagheri, S. P. Shirmardi, Comparison of shielding properties for ordinary, barite, serpentine and steel–magnetite concretes using MCNP-4C code and available experimental results, Annals of Nuclear Energy 53 (2019) 529–534.
There are 29 citations in total.

Details

Primary Language English
Subjects Materials Science and Technologies, Polymer Science and Technologies, Radiation Technology
Journal Section Research Article
Authors

Mustafa Kaya 0009-0004-2581-1747

Serpil Yalçın Kuzu 0000-0001-8905-8089

Seçil Niksarlıoğlu 0000-0002-2904-6307

Mustafa Ersin Pekdemir 0000-0002-4979-1777

Mediha Kök 0000-0001-7404-4311

Project Number FF.24.23
Publication Date December 31, 2024
Submission Date September 23, 2024
Acceptance Date December 18, 2024
Published in Issue Year 2024 Volume: 10 Issue: 4

Cite

APA Kaya, M., Yalçın Kuzu, S., Niksarlıoğlu, S., Pekdemir, M. E., et al. (2024). Investigation of Gamma Radiation Shielding in NiMnGa-Doped Multifunctional Smart Polymer Composites Using Geant4 and WinXCOM. Journal of Advanced Research in Natural and Applied Sciences, 10(4), 861-874. https://doi.org/10.28979/jarnas.1554352
AMA Kaya M, Yalçın Kuzu S, Niksarlıoğlu S, Pekdemir ME, Kök M. Investigation of Gamma Radiation Shielding in NiMnGa-Doped Multifunctional Smart Polymer Composites Using Geant4 and WinXCOM. JARNAS. December 2024;10(4):861-874. doi:10.28979/jarnas.1554352
Chicago Kaya, Mustafa, Serpil Yalçın Kuzu, Seçil Niksarlıoğlu, Mustafa Ersin Pekdemir, and Mediha Kök. “Investigation of Gamma Radiation Shielding in NiMnGa-Doped Multifunctional Smart Polymer Composites Using Geant4 and WinXCOM”. Journal of Advanced Research in Natural and Applied Sciences 10, no. 4 (December 2024): 861-74. https://doi.org/10.28979/jarnas.1554352.
EndNote Kaya M, Yalçın Kuzu S, Niksarlıoğlu S, Pekdemir ME, Kök M (December 1, 2024) Investigation of Gamma Radiation Shielding in NiMnGa-Doped Multifunctional Smart Polymer Composites Using Geant4 and WinXCOM. Journal of Advanced Research in Natural and Applied Sciences 10 4 861–874.
IEEE M. Kaya, S. Yalçın Kuzu, S. Niksarlıoğlu, M. E. Pekdemir, and M. Kök, “Investigation of Gamma Radiation Shielding in NiMnGa-Doped Multifunctional Smart Polymer Composites Using Geant4 and WinXCOM”, JARNAS, vol. 10, no. 4, pp. 861–874, 2024, doi: 10.28979/jarnas.1554352.
ISNAD Kaya, Mustafa et al. “Investigation of Gamma Radiation Shielding in NiMnGa-Doped Multifunctional Smart Polymer Composites Using Geant4 and WinXCOM”. Journal of Advanced Research in Natural and Applied Sciences 10/4 (December 2024), 861-874. https://doi.org/10.28979/jarnas.1554352.
JAMA Kaya M, Yalçın Kuzu S, Niksarlıoğlu S, Pekdemir ME, Kök M. Investigation of Gamma Radiation Shielding in NiMnGa-Doped Multifunctional Smart Polymer Composites Using Geant4 and WinXCOM. JARNAS. 2024;10:861–874.
MLA Kaya, Mustafa et al. “Investigation of Gamma Radiation Shielding in NiMnGa-Doped Multifunctional Smart Polymer Composites Using Geant4 and WinXCOM”. Journal of Advanced Research in Natural and Applied Sciences, vol. 10, no. 4, 2024, pp. 861-74, doi:10.28979/jarnas.1554352.
Vancouver Kaya M, Yalçın Kuzu S, Niksarlıoğlu S, Pekdemir ME, Kök M. Investigation of Gamma Radiation Shielding in NiMnGa-Doped Multifunctional Smart Polymer Composites Using Geant4 and WinXCOM. JARNAS. 2024;10(4):861-74.


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