Year 2025,
Volume: 11 Issue: 2, 107 - 116, 30.06.2025
Kagan Kayacı
,
Şengül Can Genç
,
Mehmet Uğur Taşkıran
,
Hasan Poçan
,
Yıldız Yıldırım
,
Mehmet Mert Doğu
,
Semih Yüksel
References
- K. Sarıiz, İ. Nuhoğlu. Endüstriyel hammadde yatakları ve madenciliği, Anadolu University Publications, 1992.
- E. Sabah, M. S. Çelik. Removal of pollutants from wastewater using sepiolite, Journal of Clay Science and Technology 1 (1) (2006) 55–72.
- S. Sherlock, S. Kelley, S. Inger, N. Harris, A. I. Okay. 40 Ar-39 Ar and Rb-Sr geochronology of high-pressure metamorphism and exhumation history of the Tavsanlı Zone, NW Turkey. Contributions to Mineralogy and Petrology, 137 (1999) 46-58.
- P. B. Davis, D. L. Whitney, Petrogenesis of lawsonite and epidote eclogite and blueschist, Sivrihisar Massif, Turkey. Journal of Metamorphic Geology 24 (9) (2006) 823-849.
- A. I. Okay, Tavşanlı zone: The northern subducted margin of the Anatolide-Tauride block. Bulletin of the Mineral Research and Exploration 142 (2011) 191-221.
- A. Plunder, P. Agard, C. Chopin, A. Pourteau, A. I. Okay. Accretion, underplating and exhumation along a subduction interface: From subduction initiation to continental subduction (Tavşanlı zone, W. Turkey) Lithos 226 (2015) 233-254.
- S. Kadir, H. Erkoyun, M. Eren, J. Huggett, N. Önalgil. Mineralogy, geochemistry, and genesis of sepiolite and palygorskite in Neogene lacustrine sediments, Eskişehir Province, west-central Anatolia, Turkey. Clays and Clay Minerals 64 (2) (2016) 145-166.
- S. Kadir, M. Eren, T. İrkeç, H. Erkoyun, T. Külah, N. Önalgil, J. Huggett. An approach to genesis of sepiolite and palygorskite in lacustrine sediments of the Lower Pliocene Sakarya and Porsuk Formations in the Sivrihisar and Yunusemre-Biçer regions (Eskişehir), Turkey. Clays and Clay Minerals 65(5) (2017) 310-328.
- K. Sarıiz. The geology, mineralogy, and occurrence of bedded sepiolite deposits in the Akçayır-Yürükakçayır (Eskişehir) lacustrine basin, central Turkey. Exploration and Mining Geology 9 (2000) 265-275.
- Z. Karakaş, Ö. Karakaş, B. Varol, Mineralogical investigation of claystone in the Neogene (Miocene Pliocene) lacustrine basin of the Sazak Biçer area (NE of Sivrihisar), Geological Bulletin of Turkey 50 2 (2007) 57-69.
- Ü. Özbaş, Origin and diagenetic evolution of sepiolite-palygorskite formations in Turkey, Doctoral Dissertation Dokuz Eylül University (2008) İzmir.
- K. Kayacı, Effect of fluxing raw materials on moisture expansion of monoporosa wall tile bodies, Journal of Thermal Analysis and Calorimetry 146 (1) (2020) 1603–1611.
- G. Sümer, İstanbul Bölgesi döküm kilinin özellikleri ve seramik döküm çamurunda kullanılma imkanlarının araştırılması, in: M. Ç. Karakaya, N. Karakaya, (Eds.), 10. Ulusal Kil Sempozyumu, Konya, (2001) pp. 532.
- K. Kayacı, S. C. Genç¸ Sintering behaviour of albite and microgranite containing porcelain stoneware bodies, Industrial Ceramic 29 (2009) 91–99.
- C. E. Işık, M. Beyarslan, Mineralogy and charectarizations of nodular sepiolite (meerschaum) of Türkmentokat-Karatepe district (Eskişehir), Science and Engineering Journal of Fırat University 28 (2) (2016) 73-82.
- D. L. Whitney, C. Teyssier, E. Toraman, N. C. Seaton, A. K. Fayon, Metamorphic and tectonic evolution of a structurally continuous blueschist-to-barrovian terrane, Sivrihisar Massif, Turkey Journal of Metamorphic Geology 29 (2010) 193–212.
- A. I. Okay, O. Monod, P. Monié, Triassic blueschists and Eclogites from Northwest Turkey: Vestiges of the Paleo-Tethyan subduction, Lithos 64 (2002) 155–178.
- K. Kayacı, Ş. C. Genç, Y. Yıldırım. Mineralogical and technological properties of the Eskişehir sepiolite (Turkey), and its usage possibilities as enstatite-based wall tile production, Qualicer 22 (2022) 1-2.
- E. S. Sabah, M.S. Çelik Sepiyolit Oluşumu, Özellikleri, Kullanım Alanları. (1998), 172.
- R. L. Frost, Z. Ding, Controlled rate thermal analysis and differential scanning calorimetry of sepiolites and palygorskites, Thermochimica Acta 397 (2003) 119-128.
- H. Nagata, S. Shimoda, T. Sudo, On dehydration of bound water of sepiolite, Clays and Clay Minerals, 22 (1974) 285-293.
Investigation of Mineralogy and Ceramic Technology Properties of Sivrihisar Kurtşeyh Sepiolites (Türkiye)
Year 2025,
Volume: 11 Issue: 2, 107 - 116, 30.06.2025
Kagan Kayacı
,
Şengül Can Genç
,
Mehmet Uğur Taşkıran
,
Hasan Poçan
,
Yıldız Yıldırım
,
Mehmet Mert Doğu
,
Semih Yüksel
Abstract
In this study, the geology, mineralogy, and potential uses of the Sivrihisar sepiolite and dolomitic sepiolites of the Eskişehir region (Türkiye) for ceramic wall tiles were investigated. A geological map of the open pits in the village of Kurtşeyh and generalized stratigraphic sections are presented. Samples taken from the pit sequences were characterized in terms of their mineralogy by XRD (X-ray diffraction). Chemical and Thermal analysis of the raw materials was determined by XRF (X-ray fluorescence), Thermal analysis (TA), and Differential Thermal analysis (DTA). Besides these studies, the thermal properties and shrinkage (%), water absorption (%), and color (L, a, b) of the fired wall tile bodies were investigated to determine their technological properties. In light of all the analysis results, alternative body formulations were created, and these recipes were fired under wall tile conditions. The fired phases were then mineralogically characterized, and the physical and technological properties of the different bodies were studied. As a sum, 10% dolomitic sepiolite usage instead of İstanbul clays is suitable for manufacturing wall tiles.
Ethical Statement
The author declares no conflict of interest
Supporting Institution
This research has been done in Kaleseramik Research and Development Center that is supported by Republic of Turkey, Ministry of Science, Industry and Technology
References
- K. Sarıiz, İ. Nuhoğlu. Endüstriyel hammadde yatakları ve madenciliği, Anadolu University Publications, 1992.
- E. Sabah, M. S. Çelik. Removal of pollutants from wastewater using sepiolite, Journal of Clay Science and Technology 1 (1) (2006) 55–72.
- S. Sherlock, S. Kelley, S. Inger, N. Harris, A. I. Okay. 40 Ar-39 Ar and Rb-Sr geochronology of high-pressure metamorphism and exhumation history of the Tavsanlı Zone, NW Turkey. Contributions to Mineralogy and Petrology, 137 (1999) 46-58.
- P. B. Davis, D. L. Whitney, Petrogenesis of lawsonite and epidote eclogite and blueschist, Sivrihisar Massif, Turkey. Journal of Metamorphic Geology 24 (9) (2006) 823-849.
- A. I. Okay, Tavşanlı zone: The northern subducted margin of the Anatolide-Tauride block. Bulletin of the Mineral Research and Exploration 142 (2011) 191-221.
- A. Plunder, P. Agard, C. Chopin, A. Pourteau, A. I. Okay. Accretion, underplating and exhumation along a subduction interface: From subduction initiation to continental subduction (Tavşanlı zone, W. Turkey) Lithos 226 (2015) 233-254.
- S. Kadir, H. Erkoyun, M. Eren, J. Huggett, N. Önalgil. Mineralogy, geochemistry, and genesis of sepiolite and palygorskite in Neogene lacustrine sediments, Eskişehir Province, west-central Anatolia, Turkey. Clays and Clay Minerals 64 (2) (2016) 145-166.
- S. Kadir, M. Eren, T. İrkeç, H. Erkoyun, T. Külah, N. Önalgil, J. Huggett. An approach to genesis of sepiolite and palygorskite in lacustrine sediments of the Lower Pliocene Sakarya and Porsuk Formations in the Sivrihisar and Yunusemre-Biçer regions (Eskişehir), Turkey. Clays and Clay Minerals 65(5) (2017) 310-328.
- K. Sarıiz. The geology, mineralogy, and occurrence of bedded sepiolite deposits in the Akçayır-Yürükakçayır (Eskişehir) lacustrine basin, central Turkey. Exploration and Mining Geology 9 (2000) 265-275.
- Z. Karakaş, Ö. Karakaş, B. Varol, Mineralogical investigation of claystone in the Neogene (Miocene Pliocene) lacustrine basin of the Sazak Biçer area (NE of Sivrihisar), Geological Bulletin of Turkey 50 2 (2007) 57-69.
- Ü. Özbaş, Origin and diagenetic evolution of sepiolite-palygorskite formations in Turkey, Doctoral Dissertation Dokuz Eylül University (2008) İzmir.
- K. Kayacı, Effect of fluxing raw materials on moisture expansion of monoporosa wall tile bodies, Journal of Thermal Analysis and Calorimetry 146 (1) (2020) 1603–1611.
- G. Sümer, İstanbul Bölgesi döküm kilinin özellikleri ve seramik döküm çamurunda kullanılma imkanlarının araştırılması, in: M. Ç. Karakaya, N. Karakaya, (Eds.), 10. Ulusal Kil Sempozyumu, Konya, (2001) pp. 532.
- K. Kayacı, S. C. Genç¸ Sintering behaviour of albite and microgranite containing porcelain stoneware bodies, Industrial Ceramic 29 (2009) 91–99.
- C. E. Işık, M. Beyarslan, Mineralogy and charectarizations of nodular sepiolite (meerschaum) of Türkmentokat-Karatepe district (Eskişehir), Science and Engineering Journal of Fırat University 28 (2) (2016) 73-82.
- D. L. Whitney, C. Teyssier, E. Toraman, N. C. Seaton, A. K. Fayon, Metamorphic and tectonic evolution of a structurally continuous blueschist-to-barrovian terrane, Sivrihisar Massif, Turkey Journal of Metamorphic Geology 29 (2010) 193–212.
- A. I. Okay, O. Monod, P. Monié, Triassic blueschists and Eclogites from Northwest Turkey: Vestiges of the Paleo-Tethyan subduction, Lithos 64 (2002) 155–178.
- K. Kayacı, Ş. C. Genç, Y. Yıldırım. Mineralogical and technological properties of the Eskişehir sepiolite (Turkey), and its usage possibilities as enstatite-based wall tile production, Qualicer 22 (2022) 1-2.
- E. S. Sabah, M.S. Çelik Sepiyolit Oluşumu, Özellikleri, Kullanım Alanları. (1998), 172.
- R. L. Frost, Z. Ding, Controlled rate thermal analysis and differential scanning calorimetry of sepiolites and palygorskites, Thermochimica Acta 397 (2003) 119-128.
- H. Nagata, S. Shimoda, T. Sudo, On dehydration of bound water of sepiolite, Clays and Clay Minerals, 22 (1974) 285-293.