Synthesis and Characterization of Polyglycidol Based Hyperbranched Urethane Methacrylate/ POSS/ Silver Nanoparticle Nanocomposites

Abstract

Keywords

• silver nanoparticles
• hybrid nanocomposites
• photopolymerization

Poliglisidol Esaslı Çok Dallanmış Üretan Metakrilat/POSS/Gümüş Nanopartikül İçeren Nanokompozitlerin Hazırlanması ve Karakterizasyonu

Abstract

Bu çalışmada çok dallanmış poliglisidol oligomeri (PG) ve poliglisidol esaslı çok dallanmış üretan metakrilat (PGUM) oligomeri glisidol ve 2-izosiyanatoetil metakrilat (IEM) kullanılarak sentezlenmiştir. Oligomerlerin yapıları FT-IR ile aydınlatılmıştır. Daha sonra PGUM, Metakril-POSS, fotobaşlatıcı (Irg-184), çapraz bağlayıcı olarak trimetilolpropan triakrilat (TMPA) ve AgNO3 karıştırılarak hibrit nanokompozit film hazırlanmıştır. Hibrit nanokompozit filmlerin mekanik ve termal özelliklerinin yanısıra kaplama performansları incelenmiştir. Metakrilik grupların çapraz bağlanması, gümüş iyonlarının kararlı nanopartiküllere (AgNP) indirgenmesi ve AgNP'lerin nanokompozitlere dahil edilmesi için UV ışığı kullanılmıştır. AgNP'lerin oluşumu TEM analizi ile doğrulanmıştır. Hibrit nanokompozit filmlerin Gram-pozitif ve Gram-negatif bakterilere karşı antibakteriyel aktiviteside ayrıca gözlenmiştir.

Keywords

• Gümüş nanopartikül
• Nanokompozitler
• Fotopolimerizasyon

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