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MECHANICAL PROPERTIES OF BORON-DOPED-ZINC OXIDE THIN FILMS USING SPRAY PYROLYSIS TECHNIQUE

Year 2024, Volume: 12 Issue: 2, 265 - 276, 30.06.2024
https://doi.org/10.21923/jesd.1304303

Abstract

This study aims to establish the mechanical properties of boron-doped Zinc Oxide (ZnO) thin film. Mechanical properties are important for engineering applications and are a focus of engineering materials. Using the spray pyrolysis process, a thin coating of boron-doped (ZnO) is created on a soda lime glass substrate at a variable percentage. An iron-constantan thermocouple was used to monitor the substrate's temperature while the film was being deposited at different temperatures. Metallurgical microscopy was used to determine the mechanical characteristics of the doped and undoped samples, including hardness, impact, and tensile strength. The results indicated that when zinc oxide is doped, variations in impact and hardness values are detected, and maximum stress increases with dopant concentration. However, when zinc oxide is undoped, stress and hardness increase with temperature.

References

  • Animasahun, L. O. 2019. Spray Pyrolysis Deposition And Characterisation Of Dielectric Sno2 Thin Films. Fountain Journal Of Natural And Applied Sciences, 8.
  • Asif, M. H., Razaq, A., Bhand, S., Willander, M. & Danielsson, B. 2018. Biosensors For Intracellular And Less Invasive Measurements Based On Nanostructured Metal Oxides. Nanotechnology And Biosensors.
  • Badreddine, K., Srour, A., Awad, R. & Abou-Aly, A. I. 2020. The Investigation Of Mechanical And Dielectric Properties Of Samarium Doped Zno Nanoparticles. Materials Research Express, 7.
  • Berestok, T. O., Kurbatov, D. I., Opanasiuk, N. M., Manzhos, O. P. & Danilchenko, S. 2012. Structural Properties Of Zno Thin Films Obtained By Chemical Bath Deposition Technique. Sumy State University.
  • Berginski, M., Hüpkes, J., Schulte, M., Schöpe, G., Stiebig, H., Rech, B. & Wuttig, M. 2007. The Effect Of Front Zno:Al Surface Texture And Optical Transparency On Efficient Light Trapping In Silicon Thin-Film Solar Cells. Journal Of Applied Physics, 101.
  • Catania, F., De Souza Oliveira, H., Lugoda, P., Cantarella, G. & Münzenrieder, N. 2022. Thin-Film Electronics On Active Substrates: Review Of Materials, Technologies And Applications. Journal Of Physics D: Applied Physics, 55.
  • Chiba, H., Mori, T., Okuda, S. & Washio, K. 2014. Thermal Stability Of Conductive And Transparent V-Doped Zno Thin Films. Thin Solid Films, 557, 203-206.
  • Choi, J. H., Tabata, H. & Kawai, T. 2001. Initial Preferred Growth In Zinc Oxide Thin Films On Si And Amorphous Substrates By A Pulsed Laser Deposition. Journal Of Crystal Growth, 226, 493-500.
  • Cordill, M. J., Kreiml, P. & Mitterer, C. 2022. Materials Engineering For Flexible Metallic Thin Film Applications. Materials, 15.
  • Dash, U. R., Khan, M. K. R., Rahman, M. M. & Kamruzzaman, M. 2018. Effect Of Low To Heavily Boron Doped Pyrolized Zinc Oxide (Zno:B) Thin Films. Journal Of Physics: Conference Series, 1086.
  • Desai, A. V. & Haque, M. A. 2007. Mechanical Properties Of Zno Nanowires. Sensors And Actuators A: Physical, 134, 169-176.
  • Dwivedi, V. K., Srivastava, P. & Prakash, G. V. 2013. Photoconductivity And Surface Chemical Analysis Of Zno Thin Films Deposited By Solution-Processing Techniques For Nano And Microstructure Fabrication. Journal Of Semiconductors, 34.
  • Hong, X., Gan, Y. & Wang, Y. 2011. Facile Measurement Of Polymer Film Thickness Ranging From Nanometer To Micrometer Scale Using Atomic Force Microscopy. Surface And Interface Analysis, 43, 1299-1303.
  • Huzni, S., Ali, N., Rizal, S. & Adlie, T. A. 2021. The Effect Of Additional Zinc Oxide (Zno) In Polymeric Foam Composites On Impact Strength. Proceedings Of The 2nd International Conference On Science, Technology, And Modern Society (Icstms 2020).
  • Jana, S., Vuk, A. S., Mallick, A., Orel, B. & Biswas, P. K. 2011. Effect Of Boron Doping On Optical Properties Of Sol–Gel Based Nanostructured Zinc Oxide Films On Glass. Materials Research Bulletin, 46, 2392-2397.
  • Jilani, A., Abdel-Wahab, M. S. & Hammad, A. H. 2017. Advance Deposition Techniques For Thin Film And Coating. Modern Technologies For Creating The Thin-Film Systems And Coatings.
  • Khan, I., Khan, S., Nongjai, R., Ahmed, H. & Khan, W. 2013. Structural And Optical Properties Of Gel-Combustion Synthesized Zr Doped Zno Nanoparticles. Optical Materials, 35, 1189-1193.
  • Khun, J., Machková, A., Kašparová, P., Klenivskyi, M., Vaňková, E., Galář, P., Julák, J. & Scholtz, V. 2021. Non-Thermal Plasma Sources Based On Cometary And Point-To-Ring Discharges. Molecules, 27.
  • Kim, I.-D., Hong, J.-M., Lee, B. H., Kim, D. Y., Jeon, E.-K., Choi, D.-K. & Yang, D.-J. 2007. Dye-Sensitized Solar Cells Using Network Structure Of Electrospun Zno Nanofiber Mats. Applied Physics Letters, 91.
  • Mohammed Nahhas, A. 2018. Review Of Gan/Zno Hybrid Structures Based Materials And Devices. American Journal Of Nano Research And Applications, 6. Naqvi, S., Kumar, V. & Gopinath, P. 2018. Nanomaterial Toxicity: A Challenge To End Users. Applications Of Nanomaterials.
  • Özgür, Ü., Gu, X., Chevtchenko, S., Spradlin, J., Cho, S. J., Morkoç, H., Pollak, F. H., Everitt, H. O., Nemeth, B. & Nause, J. E. 2006. Thermal Conductivity Of Bulk Zno After Different Thermal Treatments. Journal Of Electronic Materials, 35, 550-555.
  • Paulthangam, K. M., Som, A., Ahuja, T., Srikrishnarka, P., Nair, A. S. & Pradeep, T. 2022. Role Of Zinc Oxide In The Compounding Formulation On The Growth Of Nonstoichiometric Copper Sulfide Nanostructures At The Brass–Rubber Interface. Acs Omega, 7, 9573-9581.
  • Pearton, S. J. & Ren, F. 2014. Advances In Zno-Based Materials For Light Emitting Diodes. Current Opinion In Chemical Engineering, 3, 51-55.
  • Phillips, J. M. 2013. Substrate Selection For Thin-Film Growth. Mrs Bulletin, 20, 35-39.
  • Saadeldin, M. M., Desouky, O. A., Ibrahim, M., Khalil, G. E. & Helali, M. Y. 2019. Investigation Of Structural And Electrical Properties Of Zno Varistor Samples Doped With Different Additives. Nriag Journal Of Astronomy And Geophysics, 7, 201-207.
  • Senol, S. D., Terzioglu, R. & Ozturk, O. 2019. The Influence Of Boron Doping On The Structural And Mechanical Characterization Of Zno. Journal Of Alloys And Compounds, 797, 717-726.
  • Sharma, D. K., Shukla, S., Sharma, K. K. & Kumar, V. 2022. A Review On Zno: Fundamental Properties And Applications. Materials Today: Proceedings, 49, 3028-3035.
  • Skorenko, K., Bernier, R. T., Liu, J., Galusha, B., Goroleski, F., Hughes, B. P., Bernier, W. E. & Jones, W. E. 2016. Thermal Stability Of Zno Nanoparticle Bound Organic Chromophores. Dyes And Pigments, 131, 69-75.
  • Ștefanov, T., Maraka, H. V. R., Meagher, P., Rice, J., Sillekens, W. & Browne, D. J. 2020. Thin Film Metallic Glass Broad-Spectrum Mirror Coatings For Space Telescope Applications. Journal Of Non-Crystalline Solids: X, 7.
  • Tahir, M. B., Rafique, M., Rafique, M. S., Nawaz, T., Rizwan, M. & Tanveer, M. 2020. Photocatalytic Nanomaterials For Degradation Of Organic Pollutants And Heavy Metals. Nanotechnology And Photocatalysis For Environmental Applications.
  • Temiz, M., Yildirim, R., Bedir, M. & Öztaş, M. 2020. Effect Of Boric Acid Concentrations On The Characterization Of The In 2 O 3 Thin Films Growth By Spraying Pyrolysis Method. Digest Journal Of Nanomaterials & Biostructures (Djnb), 15.
  • Tumbul, A., Aslan, F., Demirozu, S., Goktas, A., Kilic, A., Durgun, M. & Zarbali, M. Z. 2018. Solution Processed Boron Doped Zno Thin Films: Influence Of Different Boron Complexes. Materials Research Express, 6.
  • Willander, M., Nur, O., Zhao, Q. X., Yang, L. L., Lorenz, M., Cao, B. Q., Zúñiga Pérez, J., Czekalla, C., Zimmermann, G., Grundmann, M., Bakin, A., Behrends, A., Al-Suleiman, M., El-Shaer, A., Che Mofor, A., Postels, B., Waag, A., Boukos, N., Travlos, A., Kwack, H. S., Guinard, J. & Le Si Dang, D. 2009. Zinc Oxide Nanorod Based Photonic Devices: Recent Progress In Growth, Light Emitting Diodes And Lasers. Nanotechnology, 20.
  • Xiao, P. & Dorey, R. 2008. Nanostructured Thin Films And Coatings. Journal Of Nanomaterials, 2008, 1-2.
  • Yilbas, B. S. 2014. Introduction To Nano- And Microscale Processing – Modeling. Comprehensive Materials Processing.
  • Znaidi, L. 2010. Sol–Gel-Deposited Zno Thin Films: A Review. Materials Science And Engineering: B, 174, 18-30.

MECHANICAL PROPERTIES OF BORON-DOPED-ZINC OXIDE THIN FILMS USING SPRAY PYROLYSIS TECHNIQUE

Year 2024, Volume: 12 Issue: 2, 265 - 276, 30.06.2024
https://doi.org/10.21923/jesd.1304303

Abstract

This study aims to establish the mechanical properties of boron-doped Zinc Oxide (ZnO) thin film. Mechanical properties are important for engineering applications and are a focus of engineering materials. Using the spray pyrolysis process, a thin coating of boron-doped (ZnO) is created on a soda lime glass substrate at a variable percentage. An iron-constantan thermocouple was used to monitor the substrate's temperature while the film was being deposited at different temperatures. Metallurgical microscopy was used to determine the mechanical characteristics of the doped and undoped samples, including hardness, impact, and tensile strength. The results indicated that when zinc oxide is doped, variations in impact and hardness values are detected, and maximum stress increases with dopant concentration. However, when zinc oxide is undoped, stress and hardness increase with temperature.

References

  • Animasahun, L. O. 2019. Spray Pyrolysis Deposition And Characterisation Of Dielectric Sno2 Thin Films. Fountain Journal Of Natural And Applied Sciences, 8.
  • Asif, M. H., Razaq, A., Bhand, S., Willander, M. & Danielsson, B. 2018. Biosensors For Intracellular And Less Invasive Measurements Based On Nanostructured Metal Oxides. Nanotechnology And Biosensors.
  • Badreddine, K., Srour, A., Awad, R. & Abou-Aly, A. I. 2020. The Investigation Of Mechanical And Dielectric Properties Of Samarium Doped Zno Nanoparticles. Materials Research Express, 7.
  • Berestok, T. O., Kurbatov, D. I., Opanasiuk, N. M., Manzhos, O. P. & Danilchenko, S. 2012. Structural Properties Of Zno Thin Films Obtained By Chemical Bath Deposition Technique. Sumy State University.
  • Berginski, M., Hüpkes, J., Schulte, M., Schöpe, G., Stiebig, H., Rech, B. & Wuttig, M. 2007. The Effect Of Front Zno:Al Surface Texture And Optical Transparency On Efficient Light Trapping In Silicon Thin-Film Solar Cells. Journal Of Applied Physics, 101.
  • Catania, F., De Souza Oliveira, H., Lugoda, P., Cantarella, G. & Münzenrieder, N. 2022. Thin-Film Electronics On Active Substrates: Review Of Materials, Technologies And Applications. Journal Of Physics D: Applied Physics, 55.
  • Chiba, H., Mori, T., Okuda, S. & Washio, K. 2014. Thermal Stability Of Conductive And Transparent V-Doped Zno Thin Films. Thin Solid Films, 557, 203-206.
  • Choi, J. H., Tabata, H. & Kawai, T. 2001. Initial Preferred Growth In Zinc Oxide Thin Films On Si And Amorphous Substrates By A Pulsed Laser Deposition. Journal Of Crystal Growth, 226, 493-500.
  • Cordill, M. J., Kreiml, P. & Mitterer, C. 2022. Materials Engineering For Flexible Metallic Thin Film Applications. Materials, 15.
  • Dash, U. R., Khan, M. K. R., Rahman, M. M. & Kamruzzaman, M. 2018. Effect Of Low To Heavily Boron Doped Pyrolized Zinc Oxide (Zno:B) Thin Films. Journal Of Physics: Conference Series, 1086.
  • Desai, A. V. & Haque, M. A. 2007. Mechanical Properties Of Zno Nanowires. Sensors And Actuators A: Physical, 134, 169-176.
  • Dwivedi, V. K., Srivastava, P. & Prakash, G. V. 2013. Photoconductivity And Surface Chemical Analysis Of Zno Thin Films Deposited By Solution-Processing Techniques For Nano And Microstructure Fabrication. Journal Of Semiconductors, 34.
  • Hong, X., Gan, Y. & Wang, Y. 2011. Facile Measurement Of Polymer Film Thickness Ranging From Nanometer To Micrometer Scale Using Atomic Force Microscopy. Surface And Interface Analysis, 43, 1299-1303.
  • Huzni, S., Ali, N., Rizal, S. & Adlie, T. A. 2021. The Effect Of Additional Zinc Oxide (Zno) In Polymeric Foam Composites On Impact Strength. Proceedings Of The 2nd International Conference On Science, Technology, And Modern Society (Icstms 2020).
  • Jana, S., Vuk, A. S., Mallick, A., Orel, B. & Biswas, P. K. 2011. Effect Of Boron Doping On Optical Properties Of Sol–Gel Based Nanostructured Zinc Oxide Films On Glass. Materials Research Bulletin, 46, 2392-2397.
  • Jilani, A., Abdel-Wahab, M. S. & Hammad, A. H. 2017. Advance Deposition Techniques For Thin Film And Coating. Modern Technologies For Creating The Thin-Film Systems And Coatings.
  • Khan, I., Khan, S., Nongjai, R., Ahmed, H. & Khan, W. 2013. Structural And Optical Properties Of Gel-Combustion Synthesized Zr Doped Zno Nanoparticles. Optical Materials, 35, 1189-1193.
  • Khun, J., Machková, A., Kašparová, P., Klenivskyi, M., Vaňková, E., Galář, P., Julák, J. & Scholtz, V. 2021. Non-Thermal Plasma Sources Based On Cometary And Point-To-Ring Discharges. Molecules, 27.
  • Kim, I.-D., Hong, J.-M., Lee, B. H., Kim, D. Y., Jeon, E.-K., Choi, D.-K. & Yang, D.-J. 2007. Dye-Sensitized Solar Cells Using Network Structure Of Electrospun Zno Nanofiber Mats. Applied Physics Letters, 91.
  • Mohammed Nahhas, A. 2018. Review Of Gan/Zno Hybrid Structures Based Materials And Devices. American Journal Of Nano Research And Applications, 6. Naqvi, S., Kumar, V. & Gopinath, P. 2018. Nanomaterial Toxicity: A Challenge To End Users. Applications Of Nanomaterials.
  • Özgür, Ü., Gu, X., Chevtchenko, S., Spradlin, J., Cho, S. J., Morkoç, H., Pollak, F. H., Everitt, H. O., Nemeth, B. & Nause, J. E. 2006. Thermal Conductivity Of Bulk Zno After Different Thermal Treatments. Journal Of Electronic Materials, 35, 550-555.
  • Paulthangam, K. M., Som, A., Ahuja, T., Srikrishnarka, P., Nair, A. S. & Pradeep, T. 2022. Role Of Zinc Oxide In The Compounding Formulation On The Growth Of Nonstoichiometric Copper Sulfide Nanostructures At The Brass–Rubber Interface. Acs Omega, 7, 9573-9581.
  • Pearton, S. J. & Ren, F. 2014. Advances In Zno-Based Materials For Light Emitting Diodes. Current Opinion In Chemical Engineering, 3, 51-55.
  • Phillips, J. M. 2013. Substrate Selection For Thin-Film Growth. Mrs Bulletin, 20, 35-39.
  • Saadeldin, M. M., Desouky, O. A., Ibrahim, M., Khalil, G. E. & Helali, M. Y. 2019. Investigation Of Structural And Electrical Properties Of Zno Varistor Samples Doped With Different Additives. Nriag Journal Of Astronomy And Geophysics, 7, 201-207.
  • Senol, S. D., Terzioglu, R. & Ozturk, O. 2019. The Influence Of Boron Doping On The Structural And Mechanical Characterization Of Zno. Journal Of Alloys And Compounds, 797, 717-726.
  • Sharma, D. K., Shukla, S., Sharma, K. K. & Kumar, V. 2022. A Review On Zno: Fundamental Properties And Applications. Materials Today: Proceedings, 49, 3028-3035.
  • Skorenko, K., Bernier, R. T., Liu, J., Galusha, B., Goroleski, F., Hughes, B. P., Bernier, W. E. & Jones, W. E. 2016. Thermal Stability Of Zno Nanoparticle Bound Organic Chromophores. Dyes And Pigments, 131, 69-75.
  • Ștefanov, T., Maraka, H. V. R., Meagher, P., Rice, J., Sillekens, W. & Browne, D. J. 2020. Thin Film Metallic Glass Broad-Spectrum Mirror Coatings For Space Telescope Applications. Journal Of Non-Crystalline Solids: X, 7.
  • Tahir, M. B., Rafique, M., Rafique, M. S., Nawaz, T., Rizwan, M. & Tanveer, M. 2020. Photocatalytic Nanomaterials For Degradation Of Organic Pollutants And Heavy Metals. Nanotechnology And Photocatalysis For Environmental Applications.
  • Temiz, M., Yildirim, R., Bedir, M. & Öztaş, M. 2020. Effect Of Boric Acid Concentrations On The Characterization Of The In 2 O 3 Thin Films Growth By Spraying Pyrolysis Method. Digest Journal Of Nanomaterials & Biostructures (Djnb), 15.
  • Tumbul, A., Aslan, F., Demirozu, S., Goktas, A., Kilic, A., Durgun, M. & Zarbali, M. Z. 2018. Solution Processed Boron Doped Zno Thin Films: Influence Of Different Boron Complexes. Materials Research Express, 6.
  • Willander, M., Nur, O., Zhao, Q. X., Yang, L. L., Lorenz, M., Cao, B. Q., Zúñiga Pérez, J., Czekalla, C., Zimmermann, G., Grundmann, M., Bakin, A., Behrends, A., Al-Suleiman, M., El-Shaer, A., Che Mofor, A., Postels, B., Waag, A., Boukos, N., Travlos, A., Kwack, H. S., Guinard, J. & Le Si Dang, D. 2009. Zinc Oxide Nanorod Based Photonic Devices: Recent Progress In Growth, Light Emitting Diodes And Lasers. Nanotechnology, 20.
  • Xiao, P. & Dorey, R. 2008. Nanostructured Thin Films And Coatings. Journal Of Nanomaterials, 2008, 1-2.
  • Yilbas, B. S. 2014. Introduction To Nano- And Microscale Processing – Modeling. Comprehensive Materials Processing.
  • Znaidi, L. 2010. Sol–Gel-Deposited Zno Thin Films: A Review. Materials Science And Engineering: B, 174, 18-30.
There are 36 citations in total.

Details

Primary Language English
Subjects Wearable Materials
Journal Section Research Articles
Authors

Kehinde M. Adeleke This is me

Taiwo G. Fadara This is me

Abiodun Ojetoye 0000-0001-7552-494X

Anthony Yinka Oyerinde

Ayowumi R. Soji–adekunle This is me

Publication Date June 30, 2024
Submission Date May 27, 2023
Acceptance Date December 29, 2023
Published in Issue Year 2024 Volume: 12 Issue: 2

Cite

APA Adeleke, K. M., Fadara, T. G., Ojetoye, A., Oyerinde, A. Y., et al. (2024). MECHANICAL PROPERTIES OF BORON-DOPED-ZINC OXIDE THIN FILMS USING SPRAY PYROLYSIS TECHNIQUE. Mühendislik Bilimleri Ve Tasarım Dergisi, 12(2), 265-276. https://doi.org/10.21923/jesd.1304303