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Year 2018, Volume: 13 Issue: 3, 158 - 166, 30.09.2018

Abstract

References

  • Akzu Z. (2002). Determination of the equilibrium, kinetics and Thermodynamic parameters of the batch biosorption of nickel (ll) ions onto Chorella vulgaris. J Process Biochem.Engin., 7: 89-99.
  • Alade AO., Amuda, OS, Afolabi, TJ Okoya, AA, (2012) Adsorption of Naphthalene onto activated carbon derived from milk bush kernel shell and flamboyant pod. J. Environ. Chem. & Ecotox., 4(7): 124-132.
  • Alam MZ, Muyibi, SA, Toramae J, (2007). Statistical Optimization of Adsorption processes for 2,4-dichlorophenol by activated carbon derived from oil palm empty fruit bunches. Journal of Environmental Sciences, 19: 674-677.
  • Amuda OS, Ibrahim, AO, (2006). Industrial wastewater treatment using natural materials as adsorbent. Af. J. Biotech, 5(16): 1483-1487.
  • Anirudhan, T. S. and Ramachandran, M. (2014). Removal of 2,4,6-trichlorophenol from water and petroleum refinery industry effluents by surfactant-modified bentonite. Journal of water process engineering, 1: 46-53.
  • Aremu MO., Alade, AO., Araromi, DO., Bello A. (2017). Optimization of Process Parameters for the Carbonization of Flamboyant Pod Bark (Delonix regia). European Sci. J. 13 (24): 165 -175.
  • Bansode, R. R., Lossos, J. N., Marshal, W. E., Rao, R. M, Parties, R. J. (2004). Percan shell-based granular activated carbon for treatment of Chemical Oxygen Demand (COD) in municipal water. Journal of Bioresource Technology, 94, 129-135.
  • Baseri J.R, Palanisamy PN, Sivakumar P, (2012) Preparation and characterization of activated carbon from Thevetia peruviana for the removal of dyes from textile wastewater. J. Ad. Appl Sci Res, 3(1): 377-383.
  • Dada AO, Olalekan AP., Olatunji AM, Dada, O, (2012) Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm studies of equilibrium sorption of Zinc ion unto phosphoric acid modified rice husk. Journal of applied chemistry, 3: 41-42.
  • Girish, C.R, Swaroop, M.S. (2014). Removal of phenol from wastewater using chemically treated coconut stalk (Cocos nucifera). Int. Res. J. Environ. Sci., 3(6): 48-65.
  • Goyal, M., Singh, S. and Bansal, R. (2004). Equilibrium and dynamic adsorption of methylene blue from aqueous solutions by surface modified activated carbon. J. Carbon Sci., 5: 170-179.
  • Hameed BH., Tan AW, Ahmad AL, (2009) Preparation of oil palm empty fruit bunch-based activated carbon for removal of 2,4,6-trichlorophenol: Optimization using response surface methodology. J. Hazard.s Mat. 164, 1316-1324.
  • Harvey N, Chantawong V, (2001) Adsorption of Heavy metal by ball clay: their competition and selectivity. Journal of Tokyo University of Information science, 4(1): 78-86.
  • Ho Y. (2006). Review of second-order models for adsorption systems. J. Hazard. Mat., 4: 136-681.
  • Igwe JC., Ogunewe DN, Abia AA, (2003) Removal of Mercury, Lead and Nickel ions from waste water using modified granular activated carbon (GAC); Adsorption and kinetic studies. J. Environ. Manag., 18(2): 132-139.

Kinetics and Thermodynamics of 2,4,6–Trichlorophenol Adsorption onto Activated Carbon Derived from Flamboyant Pod Bark

Year 2018, Volume: 13 Issue: 3, 158 - 166, 30.09.2018

Abstract

This work was designed to evaluate the
suitability of activated carbon produced from flamboyant pod bark (FPBAC) for
the removal of trichloro-phenol from polluted water. Various concentrations of trichloro-phenol polluted water was
prepared and the
adsorption experiments were performed at some selected adsorption factor
ranges: agitation, 150 – 250 rpm; contact time, 60 – 120 min; adsorbent dose,
0.15 – 0.25 g; and initial trichloro-phenol concentrations, 100 – 200 mg/L.
Results of the study showed that the selected adsorption factors has a
significant effect on the adsorption capacity of FPBAC which was found to
increase with increase agitation, contact time, adsorbent dosage and initial
trichloro-phenol concentrations. The results of thermodynamic studies showed
that the process is exothermic and Langmuir isotherm model with correlation
coefficient (R2) of 0.919 best described the process. The kinetics
of the process was best described by pseudo-second order model with correlation
coefficient (R2) value of 0.999.

References

  • Akzu Z. (2002). Determination of the equilibrium, kinetics and Thermodynamic parameters of the batch biosorption of nickel (ll) ions onto Chorella vulgaris. J Process Biochem.Engin., 7: 89-99.
  • Alade AO., Amuda, OS, Afolabi, TJ Okoya, AA, (2012) Adsorption of Naphthalene onto activated carbon derived from milk bush kernel shell and flamboyant pod. J. Environ. Chem. & Ecotox., 4(7): 124-132.
  • Alam MZ, Muyibi, SA, Toramae J, (2007). Statistical Optimization of Adsorption processes for 2,4-dichlorophenol by activated carbon derived from oil palm empty fruit bunches. Journal of Environmental Sciences, 19: 674-677.
  • Amuda OS, Ibrahim, AO, (2006). Industrial wastewater treatment using natural materials as adsorbent. Af. J. Biotech, 5(16): 1483-1487.
  • Anirudhan, T. S. and Ramachandran, M. (2014). Removal of 2,4,6-trichlorophenol from water and petroleum refinery industry effluents by surfactant-modified bentonite. Journal of water process engineering, 1: 46-53.
  • Aremu MO., Alade, AO., Araromi, DO., Bello A. (2017). Optimization of Process Parameters for the Carbonization of Flamboyant Pod Bark (Delonix regia). European Sci. J. 13 (24): 165 -175.
  • Bansode, R. R., Lossos, J. N., Marshal, W. E., Rao, R. M, Parties, R. J. (2004). Percan shell-based granular activated carbon for treatment of Chemical Oxygen Demand (COD) in municipal water. Journal of Bioresource Technology, 94, 129-135.
  • Baseri J.R, Palanisamy PN, Sivakumar P, (2012) Preparation and characterization of activated carbon from Thevetia peruviana for the removal of dyes from textile wastewater. J. Ad. Appl Sci Res, 3(1): 377-383.
  • Dada AO, Olalekan AP., Olatunji AM, Dada, O, (2012) Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm studies of equilibrium sorption of Zinc ion unto phosphoric acid modified rice husk. Journal of applied chemistry, 3: 41-42.
  • Girish, C.R, Swaroop, M.S. (2014). Removal of phenol from wastewater using chemically treated coconut stalk (Cocos nucifera). Int. Res. J. Environ. Sci., 3(6): 48-65.
  • Goyal, M., Singh, S. and Bansal, R. (2004). Equilibrium and dynamic adsorption of methylene blue from aqueous solutions by surface modified activated carbon. J. Carbon Sci., 5: 170-179.
  • Hameed BH., Tan AW, Ahmad AL, (2009) Preparation of oil palm empty fruit bunch-based activated carbon for removal of 2,4,6-trichlorophenol: Optimization using response surface methodology. J. Hazard.s Mat. 164, 1316-1324.
  • Harvey N, Chantawong V, (2001) Adsorption of Heavy metal by ball clay: their competition and selectivity. Journal of Tokyo University of Information science, 4(1): 78-86.
  • Ho Y. (2006). Review of second-order models for adsorption systems. J. Hazard. Mat., 4: 136-681.
  • Igwe JC., Ogunewe DN, Abia AA, (2003) Removal of Mercury, Lead and Nickel ions from waste water using modified granular activated carbon (GAC); Adsorption and kinetic studies. J. Environ. Manag., 18(2): 132-139.
There are 15 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

Mujidat Omolara Aremu This is me

A. O. Alade This is me

A. A. Bello This is me

K. K. Salam This is me

Publication Date September 30, 2018
Acceptance Date October 12, 2018
Published in Issue Year 2018 Volume: 13 Issue: 3

Cite

APA Aremu, M. O., Alade, A. O., Bello, A. A., Salam, K. K. (2018). Kinetics and Thermodynamics of 2,4,6–Trichlorophenol Adsorption onto Activated Carbon Derived from Flamboyant Pod Bark. Journal of International Environmental Application and Science, 13(3), 158-166.
AMA Aremu MO, Alade AO, Bello AA, Salam KK. Kinetics and Thermodynamics of 2,4,6–Trichlorophenol Adsorption onto Activated Carbon Derived from Flamboyant Pod Bark. J. Int. Environmental Application & Science. September 2018;13(3):158-166.
Chicago Aremu, Mujidat Omolara, A. O. Alade, A. A. Bello, and K. K. Salam. “Kinetics and Thermodynamics of 2,4,6–Trichlorophenol Adsorption onto Activated Carbon Derived from Flamboyant Pod Bark”. Journal of International Environmental Application and Science 13, no. 3 (September 2018): 158-66.
EndNote Aremu MO, Alade AO, Bello AA, Salam KK (September 1, 2018) Kinetics and Thermodynamics of 2,4,6–Trichlorophenol Adsorption onto Activated Carbon Derived from Flamboyant Pod Bark. Journal of International Environmental Application and Science 13 3 158–166.
IEEE M. O. Aremu, A. O. Alade, A. A. Bello, and K. K. Salam, “Kinetics and Thermodynamics of 2,4,6–Trichlorophenol Adsorption onto Activated Carbon Derived from Flamboyant Pod Bark”, J. Int. Environmental Application & Science, vol. 13, no. 3, pp. 158–166, 2018.
ISNAD Aremu, Mujidat Omolara et al. “Kinetics and Thermodynamics of 2,4,6–Trichlorophenol Adsorption onto Activated Carbon Derived from Flamboyant Pod Bark”. Journal of International Environmental Application and Science 13/3 (September 2018), 158-166.
JAMA Aremu MO, Alade AO, Bello AA, Salam KK. Kinetics and Thermodynamics of 2,4,6–Trichlorophenol Adsorption onto Activated Carbon Derived from Flamboyant Pod Bark. J. Int. Environmental Application & Science. 2018;13:158–166.
MLA Aremu, Mujidat Omolara et al. “Kinetics and Thermodynamics of 2,4,6–Trichlorophenol Adsorption onto Activated Carbon Derived from Flamboyant Pod Bark”. Journal of International Environmental Application and Science, vol. 13, no. 3, 2018, pp. 158-66.
Vancouver Aremu MO, Alade AO, Bello AA, Salam KK. Kinetics and Thermodynamics of 2,4,6–Trichlorophenol Adsorption onto Activated Carbon Derived from Flamboyant Pod Bark. J. Int. Environmental Application & Science. 2018;13(3):158-66.

“Journal of International Environmental Application and Science”