Synthesis, Crystal Structure and Hydrogen Bond Properties of {[HNC5H4B(OH)(OCH3)- 4]2PdCl2} New Compound

Year 2022, , 1489 - 1495, 01.09.2022

Elif Güngör , Hülya Kara Subasat

https://doi.org/10.21597/jist.1075695

Abstract

In this study, the new compound {[HNC5H4B(OH)(OCH3)-4]2PdCl2} was synthesized
and its crystal structure was determined. Compound crystallized in the space group P21/n in the
monoclinic crystal system at a=3.8749 (8) Å, b=10.177 (2) Å, c=20.403 (4) Å, α= γ = 90°, β =91.78°
and Z=2 units cell parameters The Pd ion in the compound is at the inversion center and has a quaternary
coordination. Because the N–Pd–N* and Cl–Pd–Cl* angles are 180°, the Pd ion has a square plane
geometry. The CH···O, CH···Cl and π···π interactions in the compound form a 3-dimensional
structure in the bc plane and along a axis.

Keywords

Single crystal structure, Pd compound, hydrogen bond interactions

{[HNC5H4B(OH)(OCH3)-4]2PdCl2} Yeni Bileşiğin Sentezi, Kristal Yapısı ve Hidrojen Bağ Özellikleri

Abstract

Bu çalışmada, yeni bileşik {[HNC5H4B(OH)(OCH3)-4]2PdCl2} sentezlendi ve kristal yapısı
belirlendi. Bileşik, monoklinik kristal sisteminde P21/n uzay grubunda a=3.8749 (8) Å, b=10.177 (2) Å,
c=20.403 (4) Å, α= γ = 90°, β =91.78° ve Z=2 birim hücre parametrelerinde kristallendi. Bileşikteki Pd
iyonu inversiyon merkezinde ve dörtlü bir koordinasyona sahiptir. N–Pd–N* ve Cl–Pd–Cl* açıları 180°
olduğu için, Pd iyonu kare düzlem geometriye sahiptir. Bileşikteki CH···O, CH···Cl ve π···π
etkileşimleri, bc düzleminde ve a ekseni boyunca 3 boyutlu bir yapı oluşturmaktadır.

Keywords

Tek kristal yapı, Pd bileşiği, hidrojen bağ etkileşimleri

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