Production of Porous Carbon by the Synergistic Chemical and Physical Activations and its Capacitive Performance

Year 2023, , 1888 - 1901, 01.09.2023

Murat Yılmaz , Mikail Baykal , Ahmed A. Farghaly , Müslüm Demir

https://doi.org/10.21597/jist.1180016

Abstract

Biomass-derived carbons have been extensively investigated for supercapacitor applications thanks to their advantages such as high specific capacitance value, low cost, environmental friendliness, and readily available natural materials. In this study, unique oxygen-rich porous carbons were successfully prepared by combining chemical KOH and physical CO2 activation methods. The physical and textural properties of as-prepared carbon materials are highly dependent on the synthesis conditions. The resulting PC-4K-CO2 porous carbon exhibited a hierarchical porous structure consisting of micropores, mesopores, and macropores along with a large surface area of 1318.4 cm2/g, which allowed high exposure of electrocatalytic sites and ion diffusion/transfer facilitated. As a supercapacitor electrode material, PC-4K-CO2 porous carbon prepared at 800 °C with synergic activation of KOH and CO2 showed the highest specific capacitance of 151 F/g at a current density of 0.5 A/g in the 1 M KOH electrolyte. Besides, the electrode prepared with the PC-4K-CO2 sample has achieved an excellent long-cycling life with only an 8.6% loss of its initial capacitance over 500 cycles even at a current density of 5 A/g. The current study emphasizes the environmental significance of turning pistachio shells into electrode materials for high-performance supercapacitors.

Keywords

Pistachio shells, supercapacitor, biochar, physical activating, KOH activating

Supporting Institution

The Scientific Research Council of Osmaniye Korkut Ata University and The Scientific and Technological Research Council of Turkey (TUBITAK)

Project Number

2020-PT2-002 and TEYDEP 2200261

Thanks

The Scientific Research Council of Osmaniye Korkut Ata University and The Scientific and Technological Research Council of Turkey (TUBITAK) both provided funding for this project under the terms of projects 2020-PT2-002 and TEYDEP 2200261, respectively. The authors also thank MSLM27 Technology Development and Consulting Company for their financial and consultancy support.

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