Research Article
BibTex RIS Cite

Pedochemical Drivers of Boron Distribution in Saline and Alkaline Agricultural Soil Profiles

Year 2026, Volume: 16 Issue: 1, 386 - 395, 01.03.2026
https://doi.org/10.21597/jist.1808515
https://izlik.org/JA39ZG62TL

Abstract

This study seeks to examine the vertical distribution of boron (B) concentration throughout the soil profile and its correlation with descriptive pedochemical properties in soil samples from the eastern Iğdır Plain. Soil samples were collected from 17 distinct locations at five depth intervals (0-20, 20-40, 40-60, 60-80, and 80-100 cm) and examined for pH, electrical conductivity (EC), calcium carbonate equivalent (CCE), organic matter (OM), and soil textural fractions (sand, clay, silt). The findings indicated that B concentration was elevated, particularly in the surface layers, and diminished markedly with greater depth. The maximum B concentration of 75.6 mg/kg was recorded at the surface, whereas the minimum value of 2.0 mg/kg was detected in the deeper layers. This suggests that B accumulation is confined to the surface layer due to specific surface soil properties, limited rainfall, and persistent evaporation. Correlation analyses revealed significant negative correlations between B and sand (r= -0.57**), as well as positive correlations with clay (r= 0.42**) and CCE (r= 0.76**). Organic matter content was higher in the surface layers and decreased with depth, which contributed to B retention. The pH remained alkaline across the profile, restricting B solubility and adsorption. Boron mobility within the soil profile is closely associated with both physical (texture) and chemical properties (pH, CCE, EC, and OM). Consequently, both the surface and the entire soil profile must be considered in B management strategies. This research offers valuable data to inform region-specific fertilization practices, sustainable soil management, and land reclamation strategies.

References

  • Ardahanlioglu, O., Oztas, T., Evren, S., Yilmaz, H., & Yildirim, Z. N. (2003). Spatial variability of exchangeable sodium, electrical conductivity, soil pH and boron content in salt- and sodium-affected areas of the Igdir Plain (Turkey). Journal of Arid Environments, 54(3), 495–503.
  • Bell, R. W., & Dell, B. (2008). Micronutrients for sustainable food, feed, fibre and bioenergy production. Paris: International Fertilizer Industry Association (IFA).
  • Bowichean, R., Bell, R. W., Cheng, M., Thanachit, S., & Anusontpornperm, S. (2024). Release kinetics of boron in acidic soils as affected by calcium form different sources. Applied and Environmental Soil Science, 2024(1), 6418954.
  • Chahal, S., R, P., Singh, B. P., & Gautam, S. K. (2024). Evaluation of boron toxicity in soil and influencing factors: A case study of sodic soils of Panipat, India. Environmental Monitoring and Assessment, 197(1), 8.
  • Das, A. K., & Purkait, A. (2020). Boron dynamics in soil: Classification, sources, factors, fractions, and kinetics. Communications in Soil Science and Plant Analysis, 51(22), 2778–2790.
  • Elrashidi, M. A., & O'Connor, G. A. (1982). Boron sorption and desorption in soils. Soil Science Society of America Journal, 46(1), 27–31.
  • Galić, L., Vukadinović, V., Nikolin, I., & Lončarić, Z. (2025). Soil properties and microelement availability in crops for human health: An overview. Crops, 5(4), 40.
  • Gee, G. W., & Bauder, J. W. (1986). Particle‐size analysis. In A. Klute (Ed.), Methods of soil analysis: Part 1. Physical and mineralogical methods (pp. 383–411). Madison, WI: ASA and SSSA.
  • Goldberg, S. (1997). Reactions of boron with soils. Plant and Soil, 193(1), 35–48.
  • Goldberg, S., & Suarez, D. L. (2012). Role of organic matter on boron adsorption-desorption hysteresis of soils. Soil Science, 177(7), 417–423.
  • Goldberg, S., Corwin, D. L., Shouse, P. J., & Suarez, D. L. (2005). Prediction of boron adsorption by field samples of diverse textures. Soil Science Society of America Journal, 69(5), 1379–1388.
  • Goldberg, S., Forster, H. S., & Heick, E. L. (1993). Boron adsorption mechanisms on oxides, clay minerals, and soils inferred from ionic strength effects. Soil Science Society of America Journal, 57(3), 704–708.
  • Goldberg, S., Suarez, D. L., & Shouse, P. J. (2008). Influence of soil solution salinity on boron adsorption by soils. Soil Science, 173(6), 368–374.
  • Gupta, U. C. (1972). Effects of boron and lime on boron concentration and growth of forage legumes under greenhouse conditions. Communications in Soil Science and Plant Analysis, 3(5), 355–365.
  • Karaoğlu, M. (2011). Zirai meteorolojik açıdan Iğdır iklim etüdü. Journal of the Institute of Science and Technology, 1(1), 97–104.
  • Karaoğlu, M., & Çelim, Ş. (2018). Doğu Anadolu Bölgesi ve Iğdır’ın jeolojisi ve toprak özellikleri. Journal of Agriculture, 1(1), 14–26.
  • Keren, R. (1996). Boron. In D. L. Sparks (Ed.), Methods of soil analysis: Part 3. Chemical methods (pp. 603–626). Madison, WI: ASA and SSSA.
  • Loeppert, R. H., & Suarez, D. L. (1996). Carbonate and gypsum. In D. L. Sparks (Ed.), Methods of soil analysis: Part 3. Chemical methods (pp. 437–474). Madison, WI: ASA and SSSA.
  • Majidi, A., Rahnemaie, R., Hassani, A., & Malakouti, M. J. (2010). Adsorption and desorption processes of boron in calcareous soils. Chemosphere, 80(7), 733–739.
  • Marzadori, C., Antisari, L. V., Ciavatta, C., & Sequi, P. (1991). Soil organic matter influence on adsorption and desorption of boron. Soil Science Society of America Journal, 55(6), 1582–1585.
  • Mustapha, S., & Fagam, A. S. (2007). Influence of parent material on the contents and distribution of B and Zn in upland soils of Bauchi State, Nigeria. International Journal of Environmental Science & Technology, 4(3), 359–362.
  • Nelson, D. W., & Sommers, L. E. (1996). Total carbon, organic carbon, and organic matter. In D. L. Sparks (Ed.), Methods of soil analysis: Part 3. Chemical methods (pp. 961–1010). Madison, WI: ASA and SSSA.
  • Núñez-Gómez, D., Martínez-Nicolás, J. J., Legua, P., Giménez-Valero, C., Maciá-Vázquez, A. A., & Melgarejo, P. (2024). Comparative evaluation of boron sorption dynamics on zeolites in irrigation waters: An isothermal modeling approach. Molecules, 29(11), 2545.
  • R Core Team. (2025). R: A language and environment for statistical computing (Version 4.4.1) [Computer software]. Vienna, Austria: R Foundation for Statistical Computing. Retrieved from https://www.R-project.org/
  • Richards, L. A. (1954). Diagnosis and improvement of saline and alkaline soils (Vol. 78). Washington, DC: USDA.
  • Sarkar, D., De, D. K., Das, R., & Mandal, B. (2014). Removal of organic matter and oxides of iron and manganese from soil influences boron adsorption in soil. Geoderma, 214, 213–216.
  • Sarkar, D., Mandal, B., Kundu, M. C., & Bhat, J. A. (2008). Soil properties influence distribution of extractable boron in soil profile. Communications in Soil Science and Plant Analysis, 39(15–16), 2319–2332.
  • Sharma, K. R., Srivastava, P. C., Srivastava, P., & Singh, V. P. (2006). Effect of farmyard manure application on boron adsorption–desorption characteristics of some soils. Chemosphere, 65(5), 769–777.
  • Sparks, D. L., Page, A. L., Helmke, P. A., & Loeppert, R. H. (1996). Methods of soil analysis: Part 3. Chemical methods. Madison, WI: ASA and SSSA.
  • Steiner, F., & Lana, M. D. C. (2013). Effect of pH on boron adsorption in some soils of Paraná, Brazil. Chilean Journal of Agricultural Research, 73(2), 181–186.
  • Thomas, G. W. (1996). Soil pH and soil acidity. In D. L. Sparks (Ed.), Methods of soil analysis: Part 3. Chemical methods (pp. 475–490). Madison, WI: ASA and SSSA.
  • Tlili, A., Dridi, I., Attaya, R., & Gueddari, M. (2019). Boron characterization, distribution in particle-size fractions, and its adsorption–desorption process in a semiarid Tunisian soil. Journal of Chemistry, 2019(1), 2508489.
  • Tlili, A., Dridi, I., De Feudis, M., Vittori Antisari, L., & Jedidi, N. (2024). Boron characterization and distribution in particle-size fractions and humic substances in forest and agricultural Tunisian soils. Euro-Mediterranean Journal for Environmental Integration, 1, 1–14.
  • Varol, M., Deliboran, A., Aytop, H., & Ateş, Ö. (2023). Boron contamination and related health risk assessment in the soils collected from olive groves in İzmir province, Türkiye. Chemosphere, 343, 140210.
  • Yermiyahu, U., & Ben-Gal, A. (2017). Boron in arid zone agriculture: Israeli case studies. Journal of Boron, 2(3), 128–141.
  • Yılmaz, E., & Çiçek, İ. (2018). Detailed Köppen-Geiger climate regions of Turkey. Journal of Human Sciences, 15(1), 225–242.
  • Zhang, X., Li, M. J., Zhan, L. Q., Wu, W., & Liu, H. B. (2020). Boron availability in top- and sub-soils as affected by topography and climate. Nutrient Cycling in Agroecosystems, 118(1), 91–101.

Year 2026, Volume: 16 Issue: 1, 386 - 395, 01.03.2026
https://doi.org/10.21597/jist.1808515
https://izlik.org/JA39ZG62TL

Abstract

Bu çalışma, Doğu Iğdır Ovası'ndan alınan toprak örneklerinde bor (B) konsantrasyonunun toprak profili boyunca dikey dağılımını ve tanımlayıcı pedokimyasal özelliklerle korelasyonunu incelemeyi amaçlamaktadır. Toprak örnekleri 17 farklı noktadan beş derinlik aralığında (0-20 cm, 20-40 cm, 40-60 cm, 60-80 cm ve 80-100 cm) toplanmış ve pH, elektriksel iletkenlik (EC), kalsiyum karbonat eşdeğeri (CCE), organik madde (OM) ve toprak tekstürel fraksiyonları (kum, kil, silt) açısından incelenmiştir. Bulgular, B konsantrasyonunun özellikle yüzey katmanlarında yüksek olduğunu ve derinlik arttıkça belirgin şekilde azaldığını göstermiştir. Maksimum B konsantrasyonu 75,6 mg/kg olarak yüzeyde kaydedilirken, minimum değer 2,0 mg/kg olarak daha derin katmanlarda tespit edilmiştir. Bu durum, bor birikiminin belirli yüzey toprağı özellikleri, sınırlı yağış ve sürekli buharlaşma nedeniyle yüzey katmanıyla sınırlı olduğunu göstermektedir. Korelasyon analizleri, B ile derinlik (r = 0,57*) ve kum (r = -0,57**) arasında önemli negatif korelasyonların yanı sıra kil (r = 0,42**) ve CCE (r = 0,76**) ile pozitif korelasyonlar olduğunu ortaya koymuştur. Organik madde içeriği yüzey katmanlarında daha yüksekti ve derinlikle birlikte azaldı, bu da B tutulmasına katkıda bulundu. Profil boyunca pH alkalin kalmış, bu da B çözünürlüğünü ve adsorpsiyonunu kısıtlamıştır. Toprak profilindeki bor hareketliliği hem fiziksel (tekstür) hem de kimyasal özelliklerle (pH, CCE, EC, OM) yakından ilişkilidir. Sonuç olarak, B yönetim stratejilerinde hem yüzey hem de tüm toprak profili dikkate alınmalıdır. Bu araştırma, bölgeye özgü gübreleme uygulamaları, sürdürülebilir toprak yönetimi ve arazi ıslah stratejileri hakkında bilgi vermek için değerli veriler sunmaktadır.

References

  • Ardahanlioglu, O., Oztas, T., Evren, S., Yilmaz, H., & Yildirim, Z. N. (2003). Spatial variability of exchangeable sodium, electrical conductivity, soil pH and boron content in salt- and sodium-affected areas of the Igdir Plain (Turkey). Journal of Arid Environments, 54(3), 495–503.
  • Bell, R. W., & Dell, B. (2008). Micronutrients for sustainable food, feed, fibre and bioenergy production. Paris: International Fertilizer Industry Association (IFA).
  • Bowichean, R., Bell, R. W., Cheng, M., Thanachit, S., & Anusontpornperm, S. (2024). Release kinetics of boron in acidic soils as affected by calcium form different sources. Applied and Environmental Soil Science, 2024(1), 6418954.
  • Chahal, S., R, P., Singh, B. P., & Gautam, S. K. (2024). Evaluation of boron toxicity in soil and influencing factors: A case study of sodic soils of Panipat, India. Environmental Monitoring and Assessment, 197(1), 8.
  • Das, A. K., & Purkait, A. (2020). Boron dynamics in soil: Classification, sources, factors, fractions, and kinetics. Communications in Soil Science and Plant Analysis, 51(22), 2778–2790.
  • Elrashidi, M. A., & O'Connor, G. A. (1982). Boron sorption and desorption in soils. Soil Science Society of America Journal, 46(1), 27–31.
  • Galić, L., Vukadinović, V., Nikolin, I., & Lončarić, Z. (2025). Soil properties and microelement availability in crops for human health: An overview. Crops, 5(4), 40.
  • Gee, G. W., & Bauder, J. W. (1986). Particle‐size analysis. In A. Klute (Ed.), Methods of soil analysis: Part 1. Physical and mineralogical methods (pp. 383–411). Madison, WI: ASA and SSSA.
  • Goldberg, S. (1997). Reactions of boron with soils. Plant and Soil, 193(1), 35–48.
  • Goldberg, S., & Suarez, D. L. (2012). Role of organic matter on boron adsorption-desorption hysteresis of soils. Soil Science, 177(7), 417–423.
  • Goldberg, S., Corwin, D. L., Shouse, P. J., & Suarez, D. L. (2005). Prediction of boron adsorption by field samples of diverse textures. Soil Science Society of America Journal, 69(5), 1379–1388.
  • Goldberg, S., Forster, H. S., & Heick, E. L. (1993). Boron adsorption mechanisms on oxides, clay minerals, and soils inferred from ionic strength effects. Soil Science Society of America Journal, 57(3), 704–708.
  • Goldberg, S., Suarez, D. L., & Shouse, P. J. (2008). Influence of soil solution salinity on boron adsorption by soils. Soil Science, 173(6), 368–374.
  • Gupta, U. C. (1972). Effects of boron and lime on boron concentration and growth of forage legumes under greenhouse conditions. Communications in Soil Science and Plant Analysis, 3(5), 355–365.
  • Karaoğlu, M. (2011). Zirai meteorolojik açıdan Iğdır iklim etüdü. Journal of the Institute of Science and Technology, 1(1), 97–104.
  • Karaoğlu, M., & Çelim, Ş. (2018). Doğu Anadolu Bölgesi ve Iğdır’ın jeolojisi ve toprak özellikleri. Journal of Agriculture, 1(1), 14–26.
  • Keren, R. (1996). Boron. In D. L. Sparks (Ed.), Methods of soil analysis: Part 3. Chemical methods (pp. 603–626). Madison, WI: ASA and SSSA.
  • Loeppert, R. H., & Suarez, D. L. (1996). Carbonate and gypsum. In D. L. Sparks (Ed.), Methods of soil analysis: Part 3. Chemical methods (pp. 437–474). Madison, WI: ASA and SSSA.
  • Majidi, A., Rahnemaie, R., Hassani, A., & Malakouti, M. J. (2010). Adsorption and desorption processes of boron in calcareous soils. Chemosphere, 80(7), 733–739.
  • Marzadori, C., Antisari, L. V., Ciavatta, C., & Sequi, P. (1991). Soil organic matter influence on adsorption and desorption of boron. Soil Science Society of America Journal, 55(6), 1582–1585.
  • Mustapha, S., & Fagam, A. S. (2007). Influence of parent material on the contents and distribution of B and Zn in upland soils of Bauchi State, Nigeria. International Journal of Environmental Science & Technology, 4(3), 359–362.
  • Nelson, D. W., & Sommers, L. E. (1996). Total carbon, organic carbon, and organic matter. In D. L. Sparks (Ed.), Methods of soil analysis: Part 3. Chemical methods (pp. 961–1010). Madison, WI: ASA and SSSA.
  • Núñez-Gómez, D., Martínez-Nicolás, J. J., Legua, P., Giménez-Valero, C., Maciá-Vázquez, A. A., & Melgarejo, P. (2024). Comparative evaluation of boron sorption dynamics on zeolites in irrigation waters: An isothermal modeling approach. Molecules, 29(11), 2545.
  • R Core Team. (2025). R: A language and environment for statistical computing (Version 4.4.1) [Computer software]. Vienna, Austria: R Foundation for Statistical Computing. Retrieved from https://www.R-project.org/
  • Richards, L. A. (1954). Diagnosis and improvement of saline and alkaline soils (Vol. 78). Washington, DC: USDA.
  • Sarkar, D., De, D. K., Das, R., & Mandal, B. (2014). Removal of organic matter and oxides of iron and manganese from soil influences boron adsorption in soil. Geoderma, 214, 213–216.
  • Sarkar, D., Mandal, B., Kundu, M. C., & Bhat, J. A. (2008). Soil properties influence distribution of extractable boron in soil profile. Communications in Soil Science and Plant Analysis, 39(15–16), 2319–2332.
  • Sharma, K. R., Srivastava, P. C., Srivastava, P., & Singh, V. P. (2006). Effect of farmyard manure application on boron adsorption–desorption characteristics of some soils. Chemosphere, 65(5), 769–777.
  • Sparks, D. L., Page, A. L., Helmke, P. A., & Loeppert, R. H. (1996). Methods of soil analysis: Part 3. Chemical methods. Madison, WI: ASA and SSSA.
  • Steiner, F., & Lana, M. D. C. (2013). Effect of pH on boron adsorption in some soils of Paraná, Brazil. Chilean Journal of Agricultural Research, 73(2), 181–186.
  • Thomas, G. W. (1996). Soil pH and soil acidity. In D. L. Sparks (Ed.), Methods of soil analysis: Part 3. Chemical methods (pp. 475–490). Madison, WI: ASA and SSSA.
  • Tlili, A., Dridi, I., Attaya, R., & Gueddari, M. (2019). Boron characterization, distribution in particle-size fractions, and its adsorption–desorption process in a semiarid Tunisian soil. Journal of Chemistry, 2019(1), 2508489.
  • Tlili, A., Dridi, I., De Feudis, M., Vittori Antisari, L., & Jedidi, N. (2024). Boron characterization and distribution in particle-size fractions and humic substances in forest and agricultural Tunisian soils. Euro-Mediterranean Journal for Environmental Integration, 1, 1–14.
  • Varol, M., Deliboran, A., Aytop, H., & Ateş, Ö. (2023). Boron contamination and related health risk assessment in the soils collected from olive groves in İzmir province, Türkiye. Chemosphere, 343, 140210.
  • Yermiyahu, U., & Ben-Gal, A. (2017). Boron in arid zone agriculture: Israeli case studies. Journal of Boron, 2(3), 128–141.
  • Yılmaz, E., & Çiçek, İ. (2018). Detailed Köppen-Geiger climate regions of Turkey. Journal of Human Sciences, 15(1), 225–242.
  • Zhang, X., Li, M. J., Zhan, L. Q., Wu, W., & Liu, H. B. (2020). Boron availability in top- and sub-soils as affected by topography and climate. Nutrient Cycling in Agroecosystems, 118(1), 91–101.
There are 37 citations in total.

Details

Primary Language English
Subjects Land Capability and Soil Productivity
Journal Section Research Article
Authors

Fatih Gökmen 0000-0003-3371-1186

Submission Date October 22, 2025
Acceptance Date January 12, 2026
Publication Date March 1, 2026
DOI https://doi.org/10.21597/jist.1808515
IZ https://izlik.org/JA39ZG62TL
Published in Issue Year 2026 Volume: 16 Issue: 1

Cite

APA Gökmen, F. (2026). Pedochemical Drivers of Boron Distribution in Saline and Alkaline Agricultural Soil Profiles. Journal of the Institute of Science and Technology, 16(1), 386-395. https://doi.org/10.21597/jist.1808515
AMA 1.Gökmen F. Pedochemical Drivers of Boron Distribution in Saline and Alkaline Agricultural Soil Profiles. J. Inst. Sci. and Tech. 2026;16(1):386-395. doi:10.21597/jist.1808515
Chicago Gökmen, Fatih. 2026. “Pedochemical Drivers of Boron Distribution in Saline and Alkaline Agricultural Soil Profiles”. Journal of the Institute of Science and Technology 16 (1): 386-95. https://doi.org/10.21597/jist.1808515.
EndNote Gökmen F (March 1, 2026) Pedochemical Drivers of Boron Distribution in Saline and Alkaline Agricultural Soil Profiles. Journal of the Institute of Science and Technology 16 1 386–395.
IEEE [1]F. Gökmen, “Pedochemical Drivers of Boron Distribution in Saline and Alkaline Agricultural Soil Profiles”, J. Inst. Sci. and Tech., vol. 16, no. 1, pp. 386–395, Mar. 2026, doi: 10.21597/jist.1808515.
ISNAD Gökmen, Fatih. “Pedochemical Drivers of Boron Distribution in Saline and Alkaline Agricultural Soil Profiles”. Journal of the Institute of Science and Technology 16/1 (March 1, 2026): 386-395. https://doi.org/10.21597/jist.1808515.
JAMA 1.Gökmen F. Pedochemical Drivers of Boron Distribution in Saline and Alkaline Agricultural Soil Profiles. J. Inst. Sci. and Tech. 2026;16:386–395.
MLA Gökmen, Fatih. “Pedochemical Drivers of Boron Distribution in Saline and Alkaline Agricultural Soil Profiles”. Journal of the Institute of Science and Technology, vol. 16, no. 1, Mar. 2026, pp. 386-95, doi:10.21597/jist.1808515.
Vancouver 1.Fatih Gökmen. Pedochemical Drivers of Boron Distribution in Saline and Alkaline Agricultural Soil Profiles. J. Inst. Sci. and Tech. 2026 Mar. 1;16(1):386-95. doi:10.21597/jist.1808515