Determination of Atmospheric Concentrations of Benzo [a] Pyrene with Active Sampler in Erzurum City Center

Abstract

Fifty one atmospheric air samples were collected from sampling station installed in a point where domestic heating was intensive at the city center of Erzurum from February 5 to April 7 in 2008. The atmospheric gas and particle phase concentration of Benzo [a] Pyrene (BaP) of which carcinogenic effect is more than the other PAH compounds were investigated by using Tecora hi-vol sampling instrument (average 0.320 m3 min-1). The rst 28 days of sampling period were between February 5 - March 15, while the other part, 23 days, were between March 16 - April 7. The average concentration of total (gas+particle) amount of BaP in the period of February- March was measured as 10.25 ± 9.18 ng m3, whereas it was measured as 4.45 ± 1.47 ng m3 in the period of March- April. Furthermore, the values of the daily and monthly concentration of BaP were compared with the literature and it was observed that the present values were close to the values in the regions with the same characteristics. 

Keywords

• Air Pollution,PAH,Benzo,a,pyrene,Erzurum

Erzurum Kent Merkezinde Aktif Örnekleyici ile Benzo [a] Pyrene’ nin Atmosferik Konsantrasyonlarının Belirlenmesi

Abstract

Erzurum kent merkezinde yoğun evsel ısınmanın olduğu bir noktaya kurulan örnekleme istasyonundan 2008 yılının Şubat, Mart ve Nisan ayları arasında toplam 51 adet atmosferik hava örnekleri toplanmıştır. Tecora hi-vol örnekleme cihazı (ortalama 0.320 m3 dak-1) kullanılarak toplanan atmosferik hava örneklerinde PAH bile- şenlerinden kanserojenik etkisi diğerlerine göre daha fazla olan Benzo [a] Pyrene’ nin (BaP’ nin) Erzurum kent merkezinde atmosferik gaz ve partikül faz derişimleri araştırılmıştır. Örneklemenin 28 günü 5 Şubat - 15 Mart ayları arasında, 23 günüde 16 Mart - 7 Nisan ayları arasında yapılmıştır. BaP’ nin Şubat-Mart dönemi ortalama top- lam (gaz+partikül) konsantrasyon değeri 10.25 ± 9.18 ng m3 iken, Mart-Nisan örneklemesinde ise ortalama toplam (gaz+partikül) konsantrasyon değeri 4.45 ± 1.47 ng m3 ölçülmüştür. Ayrıca BaP’ nin günlük ve aylık konsantrasyon değişimleri literatürdeki diğer kent merkezleri ile karşılaştırılmış ve bulunan değerlerin aynı karakteristik özellik- lere sahip bölgeler için yakın değerler aldığı görülmüştür. 

Keywords

• Hava Kirliliği,PAH,Benzo,a,pyrene,Erzurum

References

1. Ari, A., 2008. Eskişehir Atmosferindeki Polisiklik Aromatik Hid- rokarbonların (PAH’ların) Derişimlerinin ve Kaynaklarının Belirlenmesi, Yüksek Lisans Tezi, Anadolu Universitesi, Mü- hendislik Mimarlık Fakültesi, Eskişehir, Türkiye.
2. Arey, J., Atkinson, R., Zielinska, B., McElroy, P.A., 1989. Diurnal concentrations of volatile polycyclic aromatic hydrocarbons and nitroarenes during a photochemical episode in Glendora, California. Environmental Science and Technology, 23: 321- 327.
3. Bozlaker, A., Müezzinoğlu, A., Odabaşı, M., 2008. Atmospheric concentrations, dry deposition and air-soil exchange of polyc- yclic aromatic hydrocarbons (PAHs) in an industrial region in Turkey. Journal of Hazardous Material, 153: 1093-1102.
4. Bayraktar, H., 2006. Erzurum Kent Atmosferinde Partikül Madde Kompozisyonu. Doktora Tezi, Atatürk Üniversitesi Fen Bi- limleri Enstitüsü, Erzurum, Türkiye.
5. Bartolome, L., Cortazar, E., Raposo, J.C., Usobiaga, A., Zuloaga, O., Etxebarria, N., Fernandez, L.A., 2005. Simultaneous mic- rowave-assisted extraction of polycyclic aromatic hydrocar- bons, polychlorinated biphenyls, phthalate esters and nonyl- phenols in sediments. Journal of Chromotography A, 1068: 229-236.
6. Baloğlu, Z., 2005. Polisiklik Aromatik Hidrokarbon (PAH)’ lardan Benzo (a) Pirenin Sızma, Riviera ve Prina Zeytinyağlarında Belirlenmesi. Yüksek Lisans Tezi, Ankara Üniversitesi Fen Bilimleri Enstitüsü, Ankara, Türkiye.
7. Chen, Y., Feng, Y., Xiong, S., Liu, D., Wang, G., Sheng, G., Fu, J., 2011. Polycyclic aromatic hydrocarbons in the atmosphere of Shangai, China. Environmental Monitoring and Assessment, 172: 235-247.
8. Callen, M. S., Lopez, J. M. Mastral, A.M., 2010. Seasonal va- riation of benzo(a)pyrene in the Spanish airborne PM10. Multivariate linear regression model applied to estimate BaP concentrations Original Researh Article. Journal of Hazardous Materials, 180:648-655.

9. Chaemfa C., Barber J. L., Kim K., Harner T., Jones K. C., 2009. Further studies on the uptake of persistent organic pollutants (POPs) by polyurethane foam disk passive air samplers. At- mospheric Environment, 43: 3843-3849.
10. Cotham, W. E., Bidleman, T. F., 1995. Polycyclic aromatic hydro- carbons and polychlorinated biphenyls in air at an urban and a rural site near Lake Michigan. Environ Sci Technol, 29: 2782- 2789.
11. Demircioglu, E., Sofuoglu, A., Odabasi, M., 2011. Particle-phase dry deposition and air-soil gaz exchange of polycyclic aroma- tic hydrocarbons (PAHs) in Izmir, Turkey. Journal of Hazardo- us Materials, 186: 328-335.
12. Esen, F., Tasdemir, Y., Vardar , N., 2008. Atmospheric concentra- tions of PAHs, their possible sources and gas-to-particle par- titioning at a residential site of Bursa, Turkey. Atmospheric Research, 88: 243-255.
13. Gaga, E.O., Ari A., 2011. Gas-particle partitioning of polycyclic aromatic hydrocarbons (PAHs) in an urban traf c site in Eski- sehir, Turkey. Atmospheric Research, 99: 207-216.
14. Gaga, E.O., Tuncel, G., Tuncel, S.G., 2009. Sources and wet depo- sition uxes of polycyclic aromatichydrocarbons (PAHs) in a 1000 m high urban site at the Central Anatolia (Turkey). Envi- ronmental Forensics, 10: 286-298.
15. Gaga, E.O., 2004. Investigation of polycyclic aromatic hydrocarbon (PAH) deposition in Ankara. Doktora Tezi, Orta Doğu Teknik Üniversitesi, Ankara, Türkiye.
16. He, J., Balasubramanian, R., 2010. A comparative evaluation of passive and active samplers for measurements of gaseous semi-volatile organic compounds in the tropical atmosphere. Atmospheric Environment, 44: 884-891.
17. Halsall, C. J., Coleman, P. J., Davis, B. J., 1994. Polycyclic aro- matic hydrocarbons in UK urban air. Environ Sci Technol, 28: 2380-2386.
18. Kishida, M., Nishikawa, A., Fujimori, K., Shibutani, Y., 2011. Gas- particle concentrations of atmospheric polycyclic aromatic hydrocarbons at an urban and a residential site in Osaka, Ja- pan: Effect of the formation of atmospherically stable layer on their temporal change. Journal of Hazardous Materials, 192: 1340-1349.
19. Khalili, N. R., 1992. Atmospheric polycyclic aromatic hydrocar- bons in Chicago: characteristics and receptor modeling. PhD thesis, Pritzker Department of Environmental Engineering. Chicago, IL: Illinois Institute of Technology.
20. Liu, Y., Tao, S., Yang, Y., Dou, H., Yang, Y., Coveney, R. M., 2007. Inhalation exposure of traf c police of cers to polycyclic aro- matic hydrocarbons (PAHs) during the winter in Beijing, Chi- na. Science of the Total Environment, 383: 98-105.
21. Lin, T. C., Chang, F. H., Hsieh, J. H., Chao, H. R., Chao, M. R., 2002. Characteristics of polycyclic aromatic hydrocarbons and total suspended particulate in indoor and outdoor atmosp- here of a Taiwanese temple. Journal of Hazardous Materials, 95: 1-12.
22. Lewis, R. G., Kelly, T. J., Chuang, J. C., Callahan, P. J., Coutant, R. W., 1991. Phase distributions of airborne polycyclic aromatic hydrocarbons in two US cities. Montreal, Canada: Proc 9th World Clean Air Congress and Exhibition.
23. Ortiz, R., Vega, S., Gutieerrez R., Gibson, R., Schettino, B., Rami- rez, M.L., 2012. Presence of Polycyclic Aromatic Hydrocar- bons (PAHs) in Top Soils from Rural Terrains in Mexico City. Bull Environ Contam Toxicol, 88:428-432.
24. Odabasi, M., Cetin, E., Sofuoglu, A., 2006. Determination of oc- tanol-air partition coef cients and supercooled liquid vapor pressures of PAHs as a function of temperature: application to gas-particle partitioning in an urban atmosphere. Atmospheric Environment, 40: 6615-6625.
25. Odabaşı, M., Sofuoğlu, A., Vardar, N., Taşdemir, Y. and Holsen, T. M., 1999. Measurement of dry deposition and air-water exchange of Polycyclic Aromatic Hydrocarbons (PAHs) with the Water Surface Sampler. Environmental Science and Techno- logy, 33: 426-434.
26. Pandey, S.K., Kim, K.H., Brown, R.J.C., 2011. A review of techni- ques for the determination of polycyclic aromatic hydrocar- bons in air. Trends in Analytical Chemistry, 30: 11.
27. Tsapakis, M., Stephanou, E. G., 2005. Occurrence of gaseous and particulate polycyclic aromatic hydrocarbons in the urban at- mosphere: study of sources and ambient temperature effect on the gas/particle concentration and distribution. Environmental Pollution, 133: 147-156.
28. Vasilakos, Ch., Levi, N., Maggos, Th., Hatzianetis, J., Michopoulos, J., Helmis, C., 2007. Gas particle concentration and characte- rization of sources of PAHs in the atmosphere of a suburban area in Athens, Greece. Journal of Hazardous Materials, 140: 45-51.
29. Xiao, R., Du, X., He, X., Zhang, Y., Yi, Z., Li, F., 2008. Vertical distribution of polycyclic aromatic hydrocarbons (PAHs) in Hunpu wastewater irrigated area in northeast China under dif- ferent land use patterns. Environ Monit Assess, 142: 23-34.
30. Zhang, H. B., Luo, Y. M., Wong, M. H., Zhao, Q. G., Zhang, G. L., 2006. Distributions and Concentrations of PAHs in Hong Kong Soils. Environmental Pollution, 141: 107-114.