The Investigation of Thermodynamics Parameters and Adsorption Kinetic of The Maxilon Blue 5G Dye on Turkey Green Clay

Abstract

Maxilon Blue 5G dye and Turkey green clay minerals used in adsorption experiments are of great importance recently due to their biological and physicochemical properties. Therefore, kinetic parameters of the adsorption of maxilon blue 5G dye on green clay were investigated. Studies were performed under adsorption conditions such as pH (5-11), maxilon blue 5G dye concentration (0.5.10-6 - 2.10-5 M) and temperature (298-328 K). Turkey green clay and maxilon blue 5G dye were characterized by BET, SEM and XRF. The most favorable conditions for the dye adsorption of clay mineral, which is the support substance, were found to be pH 11 and the temperature was 328 K. The kinetic datas obtained from experimental studies were investigated on three different kinetic models such as pseudo-first-order, pseudo-second-order and intraparticle diffusion and it was determined that the adsorption event was carried out more compatible with the second order equation. Thermodynamic functions such as activation enegy (Ea), enthalpy (ΔH), Gibbs free mechanism (ΔG) and entropy (ΔS) were calculated. According to the results obtained from the experimental datas, the interaction between green clay and maxilon blue 5G are a physical interaction and experimental processes of adsorption are endothermic. These results indicated that green clay can be used as an adsorbent for the adsorption of the maxilon blue 5G (MB-5G).

Keywords

• Maxilon blue 5G,thermodynamics,green clay,adsorption

References

1. Ali I, 2010. The quest for active carbon adsorbent substitutes: Inexpensive adsorbents for toxic metal ions removal from wastewater. Separation and Purification Reviews 39(3):95-171.
2. Ali I, Asim M, Khan TA, 2012. Low cost adsorbents for removal of organic pollutants from wastewater. Journal of Environmental Management 113C:170-183.
3. Ali I, 2012. New generation adsorbents for water treatment. Chemical Reviews 112(10):5073-5091.
4. Alkan M, Doğan M, Turhan Y, Demirbaş Ö, Turan P, 2008. Adsorption kinetics and mechanism of maxilon Blue 5G dye on sepiolite from aqueous solutions. The Chemical Engineering Journal 139(2):213-223.
5. Auta M, Hameed BH, 2012. Acid modified local clay beads as effective low-cost adsorbent for dynamic. adsorption of methylene blue. Journal of Industrial and Engineering Chemistry 19(4):1153–1161.
6. Auta M, Hameed BH, 2011. Preparation of waste tea activated carbon using potassium acetate as an activating agent for adsorption of acid blue 25 dye. The Chemical Engineering Journal 171(2):502-509.
7. Auta V, Hameed BH, 2012. Modified mesoporous clay adsorbent for adsorption isotherm and kinetics of methylene blue. The Chemical Engineering Journal s 198–199:219–227.
8. Anonymous, 2016. https://www.leaf.tv/articles/greenclay-benefits/. (07.12.2016)

9. Banat IM, Nigam P, Singh D, Marchant R, 1996. Microbial decolorization of textile-dye-containing effluents: A review. Bioresource Technology 58(3):217-227.
10. Basibuyuk M, Forster CF, 2003. An examination of the adsorption characteristics of a basic dye (Maxilon Red BL-N) on to live activated sludge system. Process Biochem, (38): 1311–1316.
11. Chiou MS, Ho PY, Li HY, 2004. Adsorption of anionic dyes in acid solutions using chemically cross-linked chitosan beads. Dyes and Pigments 60(1):69-84.
12. Choy KKH, McKay G, Porter JF, 1999. Sorption of acid dyes from effluents using activated carbon. Resource Conservation Research, 27, 57-71.
13. Crini G, 2006. Non-conventional low-cost adsorbents for dye removal: A review. Bioresource Technology 97(9):1061-1085.
14. Çalımlı MH, Demirbaş Ö, Aygün A, Alma MH, Nas MS, Şen F, 2018. Immobilization kinetics and mechanism of bovine serum albumin on diatomite clay from aqueous solutions. Applied Water Science, 8:209. Doi: 10.1007/s13201-018-0858-8.
15. Demirbaş Ö, Nas MS, 2016. Kinetics and mechanism of the adsorption of methylene blue from aqueous solution onto turkish green clay. Archives of Current Research International, 6(3): 1-10.
16. Doğan M, Alkan M, Demirbaş Ö, Özdemir Y, Özmetin C, 2006. Adsorption kinetics of Maxilon Blue GRL onto sepiolite from aqueous solutions. The Chemical Engineering Journal 124(1-3):89-101.
17. Ghaedi M, Hossainian H, Montazerozohori M, Shokrollahi A, Shojaipour F, Soylak M, Purkait MK, 2011. A novel acorn based adsorbent for the removal of brilliant green. Desalination 281:226–233.
18. Ho YS, Mckay G. 1998. Sorption of dye from aqueous solution by peat. Chem. Eng. J, 70(2):115–124.
19. Hunter RJ, 1999. Introduction to modern colloid science. Oxford University Press. New York. USA.
20. Khattri SD, Singh MK, 1999. Colour removal from dye wastewater using sugar cane dust as an adsorbent. Adsorption Science & Technology, 17(4):269–282.
21. Lagergren S, 1898. About the theory of so called adsorption of soluble substances. Kungliga Svenska Vetenskapsakademiens Handlingar, 24, 1-39, 1898.
22. Laidler KJ, Meiser JM, 1999. Physical Chemistry. Houghton Mifflin. p.852. New York-ABD
23. Mall ID, Upadhyay SN, 1995. Treatment of methyl violet bearing wastewater from paper mill effluent using low cost adsorbents. J.Indian Pulp Paper Technol. Assoc, 7(1): 51-57.
24. McKay G, Otterburn MS, Sweeney AG, 1980. The removal of colour from effluent using various adsorbents–III. Silica: Rate processes. Water Research (14): 15–20.
25. McKay G, Porter JF, Prasad GR, 1999. The removal of dye colours from aqueous solutions by adsorption on low-cost materials. Water, Air and Soil Pollution, 114(3-4): 423–438.
26. Namasivayam C, Muniasamy N, Gayatri K, Rani M, Ranganathan K, 1996. Removal of dyes from aqueous solutions by cellulosic waste orange peel. Bioresource Technology 57(1):37–43.
27. Nandi BK, Goswami A, Purkait MK, 2009. Adsorption characteristics of brilliant green dye on kaolin. Journal of Hazardous Materials, (161):387–395.
28. Nas MS, Gür A, Gür T, Yönten V, 2017. Exploring thermodynamics and kinetic parameters of immobilized catalase enzyme via adsorption on krill clay. Desalination and Water Treatment (67): 178-186.
29. Rehman MSU, Munir M, Ashfaq M, Rashid N, Nazar MF, Danish M, Han JI, 2013. Adsorption of brilliant green dye from aqueous solution onto red clay. Chemical Engineering Journal (228): 54–62.
30. Savk A, Sen B, Demirkan B. Kuyuldar E, Aygun A, Nas MS, Sen F, 2018a. Graphene oxide-chitosan furnished monodisperse platinum nanoparticles as ımportantly competent and reusable nanosorbents for methylene blue removal. Chitosan-Based Adsorbents for Wastewater Treatment. Materials Research Forum LLC. USA. 24 pages. DOI: http://dx.doi.org/10.21741/9781945291753-11.
31. Savk A, Sen B, Demirkan B, Kuyuldar E, Aygun A, Nas MS, Sen F, 2018b. Novel Chitosan-Based Nanocomposites for Dye Removal Applications. Chitosan-based adsorbents for wastewater treatment. Materials Research Forum LLC. USA. 24 DOI: http://dx.doi.org/10.21741/9781945291753-3.
32. Singh D, 2000. Studies of the adsorption thermodynamics of oxamyl on fly ash. Adsorption Science&Technology 18(8): 741-748.
33. Singh KP, Mohan D, Sinha. S, Tondon GS, Gosh D, 2003. Color removal from wastewater using low-cost activated carbon derived from agricultural waste material. Ind. Eng. Chem. Res (42):1965–1976.
34. Şen F, Demirbaş Ö. Çalımlı MH, Aygün A, Alma MH, Nas MS, 2018. Dye removal from aqueous solution using polymer composite films. Applied Water Science 8:206.
35. Wang CC, Juang LC, Hsu TC, Lee CK, Lee JF, Huang FC, 2004. Adsorption of basic dyes onto montmorillonite. Journal of Colloid and Interface Science (273): 80–86.
36. Wang P, Cao M, Wang C, Ao Y, Hou J, Qian J, 2014. Kinetics and thermodynamics of adsorption of methylene blue by a magnetic graphene–carbon nanotube composite. Applied Surface Science (290): 116-124.
37. Wang S, Li H. 2005. Dye adsorption on unburned carbon: Kinetics and equilibrium. Journal of Hazardous Materials, 126(1–3): 71–77.
38. Weber WJ, Morris JC, 1963. Kinetics of adsorption on carbon from solution. Journal of Sanitary Engineering Division ASCE, (18): 31-42.
39. Williams LB, Haydel SE, Giese Jr RF, Eberl DD, 2008. Chemical and mineralogical characteristics of French green clays used for healing. Clays Clay Miner, 56(4):437–452.
40. Yener J, Kopac T, Dogu G, Dogu T, 2006. Adsorption of Basic Yellow 28 from aqueous solutions with clinoptilolite and amberlite. Journal of Colloid and Interface Science (294): 255–264.
41. Yenisoy-Karakaş S, Aygün A, Güneş M, Tahtasakal E, 2004. Physical and chemical characteristics of polymer-based spherical activated carbon and its ability to adsorb organics, Carbon (42): 477–484.