4-(3-metil-3-fenilsiklobütil)-2-(2-(piridin-4-ylmetilen)hidrazinil) tiyazol’un Sentezi, Karakterizasyonu, Kristalografik Yapısı ve Hirshfeld Yüzeyinin İncelenmesi

Year 2018, Volume: 8 Issue: 1, 157 - 168, 31.03.2018

Fatih Şen

https://doi.org/10.21597/jist.407864

Cited By: 3

Abstract

Bu çalışmada, 4-(3-metil-3-fenilsiklobütil)-2-(2-(piridin-4-ylmetilen)hidrazinil)tiyazol [C20H20N4S] molekülü sentezlendi ve IR, 1H NMR 13C NMR spektroskopileri ile karakterize edildi. Kristalografik ve moleküler yapısı tek kristal X−ışınları kırınımı tekniği ile belirlenmiştir. Bileşik ortorombik P 212121 uzay grubu ile kristalleşmiştir ve birim hücre parametreleri a=6.208(5) Å, b=15.938(5) Å, c=19.573(5) Å ve α=β=γ=90.00°’dır.Bileşiğin moleküller yapısındaki önemli etkileşimleri belirleyebilmek için PLATON ve Crystal Explorer programları kullanılmış ve kristal örgüsündeki moleküllerin paketlenmesinin doğası anlaşılmaya çalışılmıştır.

Keywords

Hirshfeld yüzeyi, siklobütan, x-ışını kırınımı

Synthesis, characterization, crystallographic structure and investigation of Hirshfeld surface of 4-(3-methyl-3- phenylcyclobutyl)-2-(2-(pyridin-4-ylmethylene)hydrazinyl)thiazole

Abstract

In this study, the title compound 4-(3-methyl-3-phenylcyclobutyl)-2-(2-(pyridin-4-ylmethylene) hydrazinyl)thiazole [C20H20N4S] was synthesized, characterized with IR, 1H NMR 13C NMR. Crystallographic and molecular structure determined by single-crystal X-ray diffraction techniques. The compound was crystallized in the orthorhombic space group P 212121 with a = 6.208(5) Å, b = 15.938(5) Å, c = 19.573(5) Å, and α=β=γ=90.00°. PLATON and Crystal Explorer programs were used to determine the remarkable interactions between the molecules and the nature of packing the molecules in the crystal has been tried to be understood.

Keywords

Cyclobutane, Hirshfeld surface, x-ray diffraction

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