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A Study on Sb and F Doped Tin Oxide Thin Films Preparing in Condition of Different Temperature and Molarity and Their Physical Comparison

Year 2019, Volume: 9 Issue: 2, 811 - 822, 01.06.2019

Ahmet Battal , Bahattin Düzgün

https://doi.org/10.21597/jist.466735

Abstract

This article is about tin oxide (SnO2:Sb:F) thin films prepared (7 samples at each experiment step) successfully on the glass substrate by using spray pyrolysis method. Different solution molarities and different substrate temperatures were used to prepare precursor solution and fabricate thin films, respectively. And then these thin film’s structural, optical and morphological properties were compared. XRD patterns displayed that the deposited films were polycrystalline with tetragonal structure irrespective of molarity and substrate temperature. Each film has a transmittance of more than 60% in visible region. Optical band gap values were found to be in the range of 3.74-3.95 eV. The SEM and AFM images demonstrated that nanocrystalline particles covered all film surfaces. The best optimum property was found at thin films (0.15 M) prepared with at 520 ˚C and the grains are larger for thin films at 520 C when compared with 480 C. Finally, it is understood that when substrate temperature and molarity increased, more regular structure was obtained.

Keywords

spray pyrolysis SnO2:Sb:F thin films solution molarity and substrate temperatures

Thanks

The authors thank for support to The Council of Higher Education and Atatürk University Scientific Research Projects (2011/218) Centre Turkey.

References

  • Battal A, Tatar D, Kocyigit A, Duzgun B, 2015. Materials Focus, 4: 445-456.
  • Carvalho DHQ, Schiavon MA, Raposo MT, de Paiva R, Alves JLA, Paniago RM, Speziali NL, Ferlauto AS, Ardisson JD, 2012. 15th Brazilian Workshop on Semiconductor Physics, 28: 22-27.
  • El-Zahed H, El-Korashy A, Rahem MA, 2002. Vacuum, 68: 19-27.
  • Huang H, Ng MH, Wu YL, Kong LB, 2015. Materials & Design, 88: 384-389.
  • Ikhmayies, S.J. and Ahmad-Bitar, R.N., 2012. Using HF rather than NH4F as doping source for spray-deposited SnO2:F thin films. Journal of Central South University of Technology, 19, 791-796.
  • Kadhim IH, Abu Hassan H, 2017. Journal of Electronic Materials, 46: 1419-1426.
  • Kou XY, Xie N, Chen F, Wang TS, Guo LL, Wang C, Wang QJ, J Ma, Sun YF, Zhang H, Lu GY, 2018. Sensors and Actuators B-Chemical, 256: 861-869.
  • Kumar KDA, Valanarasu S, Jeyadheepan K, Kim H-S, Vikraman D, 2017. Journal of Materials Science: Materials in Electronics, 29: 3648-3656.
  • Liu, XZ, Ning, HL, Chen, WF, Fang, ZQ, Yao, RH, Wang, XF, Deng, YX, Yuan, WJ, Wu, WJ, Peng, JB, 2018. Nanomaterials, 8: 293-307.
  • Martin EJJ, Yan M, Lane M, Ireland J, Kannewurf CR, Chang RPH, 2004. Thin Solid Films, 461: 309-315.
  • Moholkar, A.V., Pawar, S.M., Rajpure, K.Y. and Bhosale, C.H., 2008a. Effect of concentration of SnCl4 on sprayed fluorine doped tin oxide thin films. Journal of Alloys and Compounds, 455, 440-446.
  • Moholkar, A.V., Pawar, S.M., Rajpure, K.Y., Almaric, S.N., Patil, P.S. and Bhosale, C.H., 2008b. Solvent-dependent growth of sprayed FTO thin films with mat-like morphology. Solar Energy Material Solar Cells. 92, 1439-1444.
  • Musyaro'ah, IH, Indayani W, Gunawan B, Yudhoyono G, Endarko, 2017. International Conference on Engineering, Science and Nanotechnology, 2016. (Icesnano 2016), 1788.
  • Priyadarshini DM, Mannam R, Rao MSR, DasGupta N, 2017. Applied Surface Science, 418: 414-417.
  • Ravichandran K, Muruganantham G, Sakthivel B, Philominathan P, 2009. Journal of Ovonic Research, 5: 63-69.
  • Ravichandran K, Muruganantham G, Saravanakumar K, Karnan S, Kannan B, Chandramohan R, Sakthivel B, 2009. Surface Engineering, 25: 82-87.
  • Tripathi A, Shukla RK, 2014. Bulletin of Materials Science, 37: 417-423.
  • Vazquez-Arreguin, R, Aguilar-Frutis, M, Falcony-Guajardo, C, Castaneda-Galvan, A, Mariscal-Becerra, L, Gallardo-Hernandez, S, Alarcon-Flores, G, Garcia-Rocha, M, 2016. ECS Journal of Solid State Science And Technology, 5: 3, Q101- Q 107.
  • Vikraman D, Park HJ, Kim SI, Thaiyan M, 2016. Journal of Alloys and Compounds, 686: 616-627.
  • Wohlmuth W, Adesida I, Thin Solid Films, 2015. 479: 223-231.
  • Yusoff, ARBM , Gavim, AEX, Macedo, AG, da Silva, WJ, Schneider, FK, Teridi, MAM, 2018. Materials Today Chemistry, 10: 104-111.
  • Yuwono AH, Arini T, Lalasari LH, Sofyan N, Ramahdita G, Nararya A, Firdiyono F, Andriyah L, Subhan A, 2017. International Journal of Technology, 8: 1336.
  • Zhu BL, Liu F, Li K, Lv K, Wu J, Gan ZH, Liu J, Zeng DW, Xie CS, 2017. Ceramics International, 43: 10288-10298.

Year 2019, Volume: 9 Issue: 2, 811 - 822, 01.06.2019

Ahmet Battal , Bahattin Düzgün

https://doi.org/10.21597/jist.466735

Abstract

References

  • Battal A, Tatar D, Kocyigit A, Duzgun B, 2015. Materials Focus, 4: 445-456.
  • Carvalho DHQ, Schiavon MA, Raposo MT, de Paiva R, Alves JLA, Paniago RM, Speziali NL, Ferlauto AS, Ardisson JD, 2012. 15th Brazilian Workshop on Semiconductor Physics, 28: 22-27.
  • El-Zahed H, El-Korashy A, Rahem MA, 2002. Vacuum, 68: 19-27.
  • Huang H, Ng MH, Wu YL, Kong LB, 2015. Materials & Design, 88: 384-389.
  • Ikhmayies, S.J. and Ahmad-Bitar, R.N., 2012. Using HF rather than NH4F as doping source for spray-deposited SnO2:F thin films. Journal of Central South University of Technology, 19, 791-796.
  • Kadhim IH, Abu Hassan H, 2017. Journal of Electronic Materials, 46: 1419-1426.
  • Kou XY, Xie N, Chen F, Wang TS, Guo LL, Wang C, Wang QJ, J Ma, Sun YF, Zhang H, Lu GY, 2018. Sensors and Actuators B-Chemical, 256: 861-869.
  • Kumar KDA, Valanarasu S, Jeyadheepan K, Kim H-S, Vikraman D, 2017. Journal of Materials Science: Materials in Electronics, 29: 3648-3656.
  • Liu, XZ, Ning, HL, Chen, WF, Fang, ZQ, Yao, RH, Wang, XF, Deng, YX, Yuan, WJ, Wu, WJ, Peng, JB, 2018. Nanomaterials, 8: 293-307.
  • Martin EJJ, Yan M, Lane M, Ireland J, Kannewurf CR, Chang RPH, 2004. Thin Solid Films, 461: 309-315.
  • Moholkar, A.V., Pawar, S.M., Rajpure, K.Y. and Bhosale, C.H., 2008a. Effect of concentration of SnCl4 on sprayed fluorine doped tin oxide thin films. Journal of Alloys and Compounds, 455, 440-446.
  • Moholkar, A.V., Pawar, S.M., Rajpure, K.Y., Almaric, S.N., Patil, P.S. and Bhosale, C.H., 2008b. Solvent-dependent growth of sprayed FTO thin films with mat-like morphology. Solar Energy Material Solar Cells. 92, 1439-1444.
  • Musyaro'ah, IH, Indayani W, Gunawan B, Yudhoyono G, Endarko, 2017. International Conference on Engineering, Science and Nanotechnology, 2016. (Icesnano 2016), 1788.
  • Priyadarshini DM, Mannam R, Rao MSR, DasGupta N, 2017. Applied Surface Science, 418: 414-417.
  • Ravichandran K, Muruganantham G, Sakthivel B, Philominathan P, 2009. Journal of Ovonic Research, 5: 63-69.
  • Ravichandran K, Muruganantham G, Saravanakumar K, Karnan S, Kannan B, Chandramohan R, Sakthivel B, 2009. Surface Engineering, 25: 82-87.
  • Tripathi A, Shukla RK, 2014. Bulletin of Materials Science, 37: 417-423.
  • Vazquez-Arreguin, R, Aguilar-Frutis, M, Falcony-Guajardo, C, Castaneda-Galvan, A, Mariscal-Becerra, L, Gallardo-Hernandez, S, Alarcon-Flores, G, Garcia-Rocha, M, 2016. ECS Journal of Solid State Science And Technology, 5: 3, Q101- Q 107.
  • Vikraman D, Park HJ, Kim SI, Thaiyan M, 2016. Journal of Alloys and Compounds, 686: 616-627.
  • Wohlmuth W, Adesida I, Thin Solid Films, 2015. 479: 223-231.
  • Yusoff, ARBM , Gavim, AEX, Macedo, AG, da Silva, WJ, Schneider, FK, Teridi, MAM, 2018. Materials Today Chemistry, 10: 104-111.
  • Yuwono AH, Arini T, Lalasari LH, Sofyan N, Ramahdita G, Nararya A, Firdiyono F, Andriyah L, Subhan A, 2017. International Journal of Technology, 8: 1336.
  • Zhu BL, Liu F, Li K, Lv K, Wu J, Gan ZH, Liu J, Zeng DW, Xie CS, 2017. Ceramics International, 43: 10288-10298.
There are 23 citations in total.

Details

Primary Language English
Subjects Metrology, Applied and Industrial Physics
Journal Section Fizik / Physics
Authors

Ahmet Battal 0000-0003-0208-1564

Bahattin Düzgün This is me

Publication Date June 1, 2019
Submission Date October 2, 2018
Acceptance Date February 8, 2019
Published in Issue Year 2019 Volume: 9 Issue: 2

Cite

APA Battal, A., & Düzgün, B. (2019). A Study on Sb and F Doped Tin Oxide Thin Films Preparing in Condition of Different Temperature and Molarity and Their Physical Comparison. Journal of the Institute of Science and Technology, 9(2), 811-822. https://doi.org/10.21597/jist.466735
AMA Battal A, Düzgün B. A Study on Sb and F Doped Tin Oxide Thin Films Preparing in Condition of Different Temperature and Molarity and Their Physical Comparison. J. Inst. Sci. and Tech. June 2019;9(2):811-822. doi:10.21597/jist.466735
Chicago Battal, Ahmet, and Bahattin Düzgün. “A Study on Sb and F Doped Tin Oxide Thin Films Preparing in Condition of Different Temperature and Molarity and Their Physical Comparison”. Journal of the Institute of Science and Technology 9, no. 2 (June 2019): 811-22. https://doi.org/10.21597/jist.466735.
EndNote Battal A, Düzgün B (June 1, 2019) A Study on Sb and F Doped Tin Oxide Thin Films Preparing in Condition of Different Temperature and Molarity and Their Physical Comparison. Journal of the Institute of Science and Technology 9 2 811–822.
IEEE A. Battal and B. Düzgün, “A Study on Sb and F Doped Tin Oxide Thin Films Preparing in Condition of Different Temperature and Molarity and Their Physical Comparison”, J. Inst. Sci. and Tech., vol. 9, no. 2, pp. 811–822, 2019, doi: 10.21597/jist.466735.
ISNAD Battal, Ahmet - Düzgün, Bahattin. “A Study on Sb and F Doped Tin Oxide Thin Films Preparing in Condition of Different Temperature and Molarity and Their Physical Comparison”. Journal of the Institute of Science and Technology 9/2 (June 2019), 811-822. https://doi.org/10.21597/jist.466735.
JAMA Battal A, Düzgün B. A Study on Sb and F Doped Tin Oxide Thin Films Preparing in Condition of Different Temperature and Molarity and Their Physical Comparison. J. Inst. Sci. and Tech. 2019;9:811–822.
MLA Battal, Ahmet and Bahattin Düzgün. “A Study on Sb and F Doped Tin Oxide Thin Films Preparing in Condition of Different Temperature and Molarity and Their Physical Comparison”. Journal of the Institute of Science and Technology, vol. 9, no. 2, 2019, pp. 811-22, doi:10.21597/jist.466735.
Vancouver Battal A, Düzgün B. A Study on Sb and F Doped Tin Oxide Thin Films Preparing in Condition of Different Temperature and Molarity and Their Physical Comparison. J. Inst. Sci. and Tech. 2019;9(2):811-22.