Research Article
BibTex RIS Cite

Removal Of Boron From Boron Solutions By Chemical Precipitation

Year 2019, Volume: 9 Issue: 3, 1343 - 1350, 01.09.2019
https://doi.org/10.21597/jist.515526

Abstract

Due to the toxic effect of boron and its compounds on specified concentrations, it is necessary for boron and its compounds to be eliminated from wastewater prior to the discharging into the receiving environment. Today, it is introduced by a numerous of researchers that the removal of boron through the various physicochemical methods is applicable. In this paper, the elimination of boron from industrial wastewater by means of chemical precipitation with Ca(OH)2 as inorganic salt has been studied. Through the tests pH, boron concentration, Ca(OH)2 amount and temperature have been utilized as the parameters of the study. Ultimately, under optimum pH, by increasing the concentration, the temperature and the amount of Ca(OH)2, elimination of boron up to 98% has been achieved. It is considered that some part of the eliminated boron has been chemically precipitated as calcium borate while another part has been eliminated by the precipitation together with the ensued calcium sulphate.

References

  • Boncukcuoğlu R., Kocakerim, MM., Kocadağistan E. and Yılmaz, MT. 2003. Recovery of Boron of The Sieve Reject in The Production, Resources Conservation And Recycling, 37:2, 147-157.
  • Demirtaş, A., 2010, Borun İnsan Beslenmesi ve Sağlığı Açısından Önemi, Atatürk Üniversitesi Ziraat Fakültesi Toprak Bölümü, 25240-Erzurum, 41 (1): 75-80.
  • Franson, M. N., Greenberg, A. E., Trussell, R. R., Cîesceri, L. S., 1985. Standard Methods for The Examination of Water and Wastewater. American Public Health Association, p:133-136 Washington D.C.
  • Greeberg AE., Trussell RR. and Clesceri LS., 1985. Standard Methods for the examination of water and wastewater, American Public Health Association, 16th ed., Washington D.C.; p:133-136
  • Hatcher, JT., Wilcox, LV., 1950. Colorimetric Determination Of Boron Using Carmine. Anal. Chem. 22 (4): 22-567.
  • Hobbs MY., and Reardon EJ., 1999. Effect of pH on boron coprecipitation by calcite, Geochemica et Cosmochemica Acta, 63: 1013-1021.
  • Kemp HK., 1956. Calcium Borates, Chapter 11, The Chemistry of Borates, Printed by W.S. Cowell LTD, Butter Market, Ipswitch, Borax Consolidated Ltd, p: 68-71, London.
  • Kıpçak AS., Derun EM., and Pişkin S., 2014. Characterization and determination of the neutron transmission properties of sodium-calcium and sodium borates from different regions in Turkey, J. Radional Nucl. Chem.,301:175-188,
  • Korkmaz, M., 2007. Borun İnsan Sağlığına Etkisi, Celal Bayar Üniversitesi Tıp Fakültesi Biyoloji Anabilim Dalı, Manisa, 41 (1): 75-80.
  • Mc Kee. JE. and Wolf HW., 1963. Water Quality Criteria’, Califomia State Water Resources Control Board, USA, Publication No: 3-A, pp. 1-467, USA.
  • O’Melia, Charles R., 1972. Coagulation and Floculation, In Physicochemical Prosess for Water Quality Control, ed. W. J. Webber Willey İnterscience, Chapter 2, New York
  • Özkan A. and Yekeler M., 2003. Coagulation and Floculation Characteristics of Celestite with Different Inorganic Salts and Polymers. Chemical Engineering and Processing 43 (2004): 873-879.
  • Remy P., Muhr H., Plasari E., Ouerdiane I., 2005. Removal of Boron from Wastewater by Precipitation of a Sparingly Soluble Salt, 24 (1): 105-110. Seiler HF., 1989. Handbook on toxicity inorganic compounds, Marcel Decker Inc., Newyork.
  • Selimoğlu V., 2006. Endüstriyel Atıksulardan Kimyasal Reaksiyon-Koagülasyon Metodu ile Bor Giderimi, Atatürk Üniversitesi, Fen Bilimleri Enstitüsü, Yüksek Lisans Tezi (Basılmış).
  • Yılmaz AE., Boncukcuoğlu R., Bayer S., Fil BA., and Kocakerim MM., 2012. Boron removal by means chemical precipitation with calcium hydroxide and calcium borates formations, Korean J. Chem. Eng., 29 (10): 1382-1387.

Bor Çözeltilerinden Kimyasal Çöktürmeyle Bor Giderimi

Year 2019, Volume: 9 Issue: 3, 1343 - 1350, 01.09.2019
https://doi.org/10.21597/jist.515526

Abstract

Bor ve bileĢikleri belirli konsantrasyonların üzerinde çevrede toksik etkiye sahip olacağından endüstriyel atıksulardan alıcı ortama deĢarj edilmeden giderilmesi gerekmektedir. Günümüzde birçok araĢtırmacı tarafından çeĢitli fizikokimyasal yöntemlerle bor gideriminin mümkün olduğu ortaya konmuĢtur. Bu yöntem ile borun, inorganik bir tuz olan Ca(OH)2 ile kimyasal yöntemle çöktürülmesi suretiyle bor iĢleyen endüstri atıksularından giderimine çalıĢılmıĢtır. Denemelerde pH, bor konsantrasyonu, Ca(OH)2 miktarı ve sıcaklık parametre olarak kullanılmıĢtır. Sonuç olarak, optimum pH için konsantrasyon, sıcaklık ve Ca(OH)2 miktarının artırılması ile %98’e varan oranda bor giderimi sağlanmıĢtır. Yöntemde ortamda bulunan borun bir kısmının kimyasal olarak kalsiyum borata dönüĢtürülerek bir kısmının da oluĢan kalsiyum sülfatla birlikte çöktürülerek giderildiği düĢünülmektedir.

References

  • Boncukcuoğlu R., Kocakerim, MM., Kocadağistan E. and Yılmaz, MT. 2003. Recovery of Boron of The Sieve Reject in The Production, Resources Conservation And Recycling, 37:2, 147-157.
  • Demirtaş, A., 2010, Borun İnsan Beslenmesi ve Sağlığı Açısından Önemi, Atatürk Üniversitesi Ziraat Fakültesi Toprak Bölümü, 25240-Erzurum, 41 (1): 75-80.
  • Franson, M. N., Greenberg, A. E., Trussell, R. R., Cîesceri, L. S., 1985. Standard Methods for The Examination of Water and Wastewater. American Public Health Association, p:133-136 Washington D.C.
  • Greeberg AE., Trussell RR. and Clesceri LS., 1985. Standard Methods for the examination of water and wastewater, American Public Health Association, 16th ed., Washington D.C.; p:133-136
  • Hatcher, JT., Wilcox, LV., 1950. Colorimetric Determination Of Boron Using Carmine. Anal. Chem. 22 (4): 22-567.
  • Hobbs MY., and Reardon EJ., 1999. Effect of pH on boron coprecipitation by calcite, Geochemica et Cosmochemica Acta, 63: 1013-1021.
  • Kemp HK., 1956. Calcium Borates, Chapter 11, The Chemistry of Borates, Printed by W.S. Cowell LTD, Butter Market, Ipswitch, Borax Consolidated Ltd, p: 68-71, London.
  • Kıpçak AS., Derun EM., and Pişkin S., 2014. Characterization and determination of the neutron transmission properties of sodium-calcium and sodium borates from different regions in Turkey, J. Radional Nucl. Chem.,301:175-188,
  • Korkmaz, M., 2007. Borun İnsan Sağlığına Etkisi, Celal Bayar Üniversitesi Tıp Fakültesi Biyoloji Anabilim Dalı, Manisa, 41 (1): 75-80.
  • Mc Kee. JE. and Wolf HW., 1963. Water Quality Criteria’, Califomia State Water Resources Control Board, USA, Publication No: 3-A, pp. 1-467, USA.
  • O’Melia, Charles R., 1972. Coagulation and Floculation, In Physicochemical Prosess for Water Quality Control, ed. W. J. Webber Willey İnterscience, Chapter 2, New York
  • Özkan A. and Yekeler M., 2003. Coagulation and Floculation Characteristics of Celestite with Different Inorganic Salts and Polymers. Chemical Engineering and Processing 43 (2004): 873-879.
  • Remy P., Muhr H., Plasari E., Ouerdiane I., 2005. Removal of Boron from Wastewater by Precipitation of a Sparingly Soluble Salt, 24 (1): 105-110. Seiler HF., 1989. Handbook on toxicity inorganic compounds, Marcel Decker Inc., Newyork.
  • Selimoğlu V., 2006. Endüstriyel Atıksulardan Kimyasal Reaksiyon-Koagülasyon Metodu ile Bor Giderimi, Atatürk Üniversitesi, Fen Bilimleri Enstitüsü, Yüksek Lisans Tezi (Basılmış).
  • Yılmaz AE., Boncukcuoğlu R., Bayer S., Fil BA., and Kocakerim MM., 2012. Boron removal by means chemical precipitation with calcium hydroxide and calcium borates formations, Korean J. Chem. Eng., 29 (10): 1382-1387.
There are 15 citations in total.

Details

Primary Language Turkish
Subjects Environmental Engineering
Journal Section Çevre Mühendisliği / Environment Engineering
Authors

Veysel Selimoğlu 0000-0002-3375-1842

Recep Boncukcuoğlu 0000-0002-6096-5280

Publication Date September 1, 2019
Submission Date January 21, 2019
Acceptance Date May 13, 2019
Published in Issue Year 2019 Volume: 9 Issue: 3

Cite

APA Selimoğlu, V., & Boncukcuoğlu, R. (2019). Bor Çözeltilerinden Kimyasal Çöktürmeyle Bor Giderimi. Journal of the Institute of Science and Technology, 9(3), 1343-1350. https://doi.org/10.21597/jist.515526
AMA Selimoğlu V, Boncukcuoğlu R. Bor Çözeltilerinden Kimyasal Çöktürmeyle Bor Giderimi. J. Inst. Sci. and Tech. September 2019;9(3):1343-1350. doi:10.21597/jist.515526
Chicago Selimoğlu, Veysel, and Recep Boncukcuoğlu. “Bor Çözeltilerinden Kimyasal Çöktürmeyle Bor Giderimi”. Journal of the Institute of Science and Technology 9, no. 3 (September 2019): 1343-50. https://doi.org/10.21597/jist.515526.
EndNote Selimoğlu V, Boncukcuoğlu R (September 1, 2019) Bor Çözeltilerinden Kimyasal Çöktürmeyle Bor Giderimi. Journal of the Institute of Science and Technology 9 3 1343–1350.
IEEE V. Selimoğlu and R. Boncukcuoğlu, “Bor Çözeltilerinden Kimyasal Çöktürmeyle Bor Giderimi”, J. Inst. Sci. and Tech., vol. 9, no. 3, pp. 1343–1350, 2019, doi: 10.21597/jist.515526.
ISNAD Selimoğlu, Veysel - Boncukcuoğlu, Recep. “Bor Çözeltilerinden Kimyasal Çöktürmeyle Bor Giderimi”. Journal of the Institute of Science and Technology 9/3 (September 2019), 1343-1350. https://doi.org/10.21597/jist.515526.
JAMA Selimoğlu V, Boncukcuoğlu R. Bor Çözeltilerinden Kimyasal Çöktürmeyle Bor Giderimi. J. Inst. Sci. and Tech. 2019;9:1343–1350.
MLA Selimoğlu, Veysel and Recep Boncukcuoğlu. “Bor Çözeltilerinden Kimyasal Çöktürmeyle Bor Giderimi”. Journal of the Institute of Science and Technology, vol. 9, no. 3, 2019, pp. 1343-50, doi:10.21597/jist.515526.
Vancouver Selimoğlu V, Boncukcuoğlu R. Bor Çözeltilerinden Kimyasal Çöktürmeyle Bor Giderimi. J. Inst. Sci. and Tech. 2019;9(3):1343-50.