Year 2020, Volume 10 , Issue 1, Pages 163 - 170 2020-03-01

Hydrothermal Synthesis and Characterization of New Organic Compound Based on Phenol-4-Sulfonic Acid and 1,3-Bis(4-Pyridyl)Propane
Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu

Mustafa Burak ÇOBAN [1]


In this study, the new 2D organic compound [PSA2][BPP2] (psa=phenol-4-sulfonic acid, bpp=1,3-Bis(4-pyridyl)propane was hydrothermally synthesized and characterized by single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), elemental analysis, and solid-state UV-vis absorption spectra. The crystal structure analysis of the compound indicates that complex crystallizes in the orthorhombic crystal system Pca21 space group and its asymmetric unit consists of two discrete psa and bpp ligand. The ring of phenol and pyridyl groups is almost planar. Additionally, crystal structure of the compound is linked via intermolecular O – H…O and C – H…O hydrogen bonds as well as intramolecular C–H…π and between the bpp molecules π - π interactions, which form two-dimensional structure and provide structural stability.

Bu çalışmada, yeni iki-boyutlu organik bileşik [PSA2][BPP2] (psa=fenol-4-sülfonik asit, bpp=1,3-Bis(4-piridil)propan) hidrotermal yöntem ile sentezlendi, tek kristal X-ışını kırınımı, toz kristal X-ışını kırınım yöntemi (PXRD), element analizi ve katı-hal UV-vis spektroskopisi ile karakterize edildi. Kristal yapı analizi, bileşiğin ortorombik kristal sisteminde Pca21 uzay grubunda kristalleştiğini ve asimetrik biriminde iki psa ve iki bpp ligandından oluştuğunu göstermektedir. Fenol ve piridil grupları neredeyse düzlemseldir. Ek olarak, bileşiğin kristal yapısı moleküller arası O–H…O, C–H…O hidrojen bağlarının yanı sıra molekül içi C–H…π ve bpp molekülleri arasında meydana gelen π - π etkileşimleriyle iki-boyutlu yapıyı oluşturmuş ve yapısal kararlılık sağlamıştır.

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Primary Language tr
Subjects Physics, Applied
Journal Section Fizik / Physics
Authors

Orcid: 0000-0003-3488-5284
Author: Mustafa Burak ÇOBAN (Primary Author)
Institution: Balıkesir University Center of Science and Technology Application and Research
Country: Turkey


Dates

Application Date : September 13, 2019
Acceptance Date : October 10, 2019
Publication Date : March 1, 2020

Bibtex @research article { jist620043, journal = {Journal of the Institute of Science and Technology}, issn = {2146-0574}, eissn = {2536-4618}, address = {}, publisher = {Igdir University}, year = {2020}, volume = {10}, pages = {163 - 170}, doi = {10.21597/jist.620043}, title = {Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu}, key = {cite}, author = {ÇOBAN, Mustafa Burak} }
APA ÇOBAN, M . (2020). Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu. Journal of the Institute of Science and Technology , 10 (1) , 163-170 . DOI: 10.21597/jist.620043
MLA ÇOBAN, M . "Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu". Journal of the Institute of Science and Technology 10 (2020 ): 163-170 <https://dergipark.org.tr/en/pub/jist/issue/52503/620043>
Chicago ÇOBAN, M . "Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu". Journal of the Institute of Science and Technology 10 (2020 ): 163-170
RIS TY - JOUR T1 - Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu AU - Mustafa Burak ÇOBAN Y1 - 2020 PY - 2020 N1 - doi: 10.21597/jist.620043 DO - 10.21597/jist.620043 T2 - Journal of the Institute of Science and Technology JF - Journal JO - JOR SP - 163 EP - 170 VL - 10 IS - 1 SN - 2146-0574-2536-4618 M3 - doi: 10.21597/jist.620043 UR - https://doi.org/10.21597/jist.620043 Y2 - 2019 ER -
EndNote %0 Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu %A Mustafa Burak ÇOBAN %T Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu %D 2020 %J Journal of the Institute of Science and Technology %P 2146-0574-2536-4618 %V 10 %N 1 %R doi: 10.21597/jist.620043 %U 10.21597/jist.620043
ISNAD ÇOBAN, Mustafa Burak . "Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu". Journal of the Institute of Science and Technology 10 / 1 (March 2020): 163-170 . https://doi.org/10.21597/jist.620043
AMA ÇOBAN M . Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu. Iğdır Üniv. Fen Bil Enst. Der.. 2020; 10(1): 163-170.
Vancouver ÇOBAN M . Fenol-4-Sülfonik Asit ve 1,3-Bis(4-Piridil)Propan Tabanlı Yeni Organik Bileşiğin Hidrotermal Sentezi ve Karakterizasyonu. Journal of the Institute of Science and Technology. 2020; 10(1): 170-163.