Benzonorbornadien Oksit’in Mikrodalga Destekli ve Montmorillonite-K10 Katalizli Alkolizi: Wagner–Meerwein Düzenlenmesi ile Regioseçici Yeni Alkoksi Alkollerin Sentezi

Year 2022, Volume: 12 Issue: 3, 1690 - 1702, 01.09.2022

Ramazan Koçak

https://doi.org/10.21597/jist.1106341

Abstract

Bu çalışmada, benzonorbornadien epoksitinin alkollerle mikrodalga destekli halka açılma tepkimeleri incelendi. Ucuz ve çevreci heterojen montmorillonite-K10 katalizörü eşliğinde yüksek verim ile kısa reaksiyon süresinde (10 dakikaya kadar) Wagner–Meerwein düzenlenmesi ile regioseçici olarak yeni alkoksi alkoller sentezlendi. Ürünler sadece süzme ile saflaştırıldı.

Keywords

Benzonorbornadien oksit, alkoksi alkol, montmorillonite-K10, Wagner–Meerwein düzenlenmesi, mikrodalga

Thanks

Bu çalışmaya katkılarından dolayı, Atatürk Üniversitesi Fen Fakültesi Kimya Bölümü’ne teşekkür ederiz.

Microwave Assisted and Montmorillonite-K10 Catalyzed Alcohollysis of Benzonorbornadiene Oxide: Synthesis of Regioselective New Alkoxy Alcohols by Wagner–Meerwein Rearrangement

Abstract

In this study, microwave assisted ring opening of benzonorbornadiene epoxide with alcohols was investigated. New alkoxy alcohols were synthesized regioselectively by Wagner–Meerwein rearrangement in short reaction times (up to 10 minutes) with high yield in the presence of a cheap and environmentally friendly heterogeneous montmorillonite-K10 catalyst. The products were purified by filtration only.

Keywords

Benzonorbornadiene oxide, alkoxy alcohol, montmorillonite-K10, Wagner–Meerwein rearrangement, microwave

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