Fabrication of Highly Efficient Fe3O4/SSIP/GO Composite Films for Removal of Methylene Blue Dye
Year 2023,
Volume: 13 Issue: 4, 2829 - 2837, 01.12.2023
Mehmet Salih Nas
,
Mehmet Harbi Çalımlı
,
Özkan Demirbaş
Abstract
In this paper, we report the preparation of a new Fe3O4/SSIP/GO composite film for the purification of methylene blue dye from solution media. The preparation process of composite film was carried out to improve the interaction between the inner part of the sunflower stalk (SSIP) and surface matrix using magnetite/Graphene Oxide (Fe3O4/GO) minerals at weight ratios (0.2/4/0.2:w/w/w). The characterizations of as-developed Fe3O4/SSIP/GO composite film was successfully carried out by some advanced techniques such as FT-IR, SEM, and TGA analyses. Adsorption kinetic studies were evaluated in three different aspects as a pseudo-first-order model, pseudo-second-order model, and intraparticle diffusion-type model. Based on the R2 results, it was seen that the Pseudo-second order kinetic model (0.999) acted more harmoniously than the pseudo-first-order (0.960) and intra-particle diffusion technique models (0.974). In the light of these findings, it can be said that the prepared Fe3O4/SSIP/GO composite film used for removal of methylene blue dye can be considered as a promising material
Project Number
MÜF0520A12
References
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- Li, Y., Liu, F., Xia, B., Du, Q., Zhang, P., Wang, D., Wang, Z., & Xia, Y. (2010). Removal of copper from aqueous solution by carbon nanotube/calcium alginate composites. Journal of Hazardous Materials, 177(1–3), 876–880. https://doi.org/10.1016/J.JHAZMAT.2009.12.114
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- P., V., S., C., & W., A. (2009). Bioethanol production from enzymatically saccharified sunflower stalks using steam explosion as pretreatment. https://ir.swu.ac.th/jspui/handle/123456789/15454
- Parvin, S., Biswas, B. K., Rahman, M. A., Rahman, M. H., Anik, M. S., & Uddin, M. R. (2019). Study on adsorption of Congo red onto chemically modified egg shell membrane. Chemosphere, 236, 124326. https://doi.org/10.1016/J.CHEMOSPHERE.2019.07.057
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- Wei, Y., Han, B., Hu, X., Lin, Y., Wang, X., & Deng, X. (2012). Synthesis of Fe3O4 Nanoparticles and their Magnetic Properties. Procedia Engineering, 27, 632–637. https://doi.org/10.1016/J.PROENG.2011.12.498
- Wekoye, J. N., Wanyonyi, W. C., Wangila, P. T., & Tonui, M. K. (2020). Kinetic and equilibrium studies of Congo red dye adsorption on cabbage waste powder. https://doi.org/10.1016/j.enceco.2020.01.004
- Xu, M., Qi, M., Goff, H. D., & Cui, S. W. (2020). Polysaccharides from sunflower stalk pith: Chemical, structural and functional characterization. Food Hydrocolloids, 100, 105082. https://doi.org/10.1016/J.FOODHYD.2019.04.053
Year 2023,
Volume: 13 Issue: 4, 2829 - 2837, 01.12.2023
Mehmet Salih Nas
,
Mehmet Harbi Çalımlı
,
Özkan Demirbaş
Supporting Institution
Iğdır Üniversitesi
Project Number
MÜF0520A12
Thanks
Bu proje çalışmasının istenilen şekilde yürütülmesinde finanse eden Iğdır Üniversitesi Bilimsel Araştırma Projeleri biriminde görevli herkese teşekkür ederim.
References
- Bayat, R., Bingül Reçber, Z., Bekmezci, M., Nas, M. S., Calimli, M. H., Demirbas, O., Akin, M., & Şen, F. (2022). Synthesis and application of AuNi@AC nano adsorbents for the removal of Maxilon Blue 5G azo dye from aquatic mediums. Food and Chemical Toxicology, 167, 113303. https://doi.org/10.1016/J.FCT.2022.113303
- Baysal, M., Bilge, K., Yılmaz, B., Papila, M., & Yürüm, Y. (2018). Preparation of high surface area activated carbon from waste-biomass of sunflower piths: Kinetics and equilibrium studies on the dye removal. Journal of Environmental Chemical Engineering, 6(2), 1702–1713. https://doi.org/10.1016/J.JECE.2018.02.020
- Benzait, Z., Chen, P., & Trabzon, L. (2021). Enhanced synthesis method of graphene oxide. Nanoscale Advances, 3(1), 223–230. https://doi.org/10.1039/D0NA00706D
- Bingül Reçber, Z., Burhan, H., Bayat, R., Nas, M. S., Calimli, M. H., Demirbas, Ö., Şen, F., & Hassan, K. M. (2022). Fabrication of activated carbon supported modified with bimetallic-platin ruthenium nano sorbent for removal of azo dye from aqueous media using enhanced ultrasonic wave. Environmental Pollution, 302, 119033. https://doi.org/10.1016/J.ENVPOL.2022.119033
- Çalımlı, M. H., Demirbaş, Ö., Aygün, A., Alma, M. H., Nas, M. S., Khan, A., Asiri, A. M., & Şen, F. (2019). Equilibrium, Kinetics and Thermodynamics of Bovine Serum Albumin from Carbon Based Materials Obtained from Food Wastes. BioNanoScience, 9(3), 692–701. https://doi.org/10.1007/S12668-019-00633-Z
- Cheng, S., Zhang, L., Xia, H., Peng, J., Shu, J., Li, C., Jiang, X., & Zhang, Q. (2017). Adsorption behavior of methylene blue onto waste-derived adsorbent and exhaust gases recycling. RSC Advances, 7(44), 27331–27341. https://doi.org/10.1039/C7RA01482A
- Dahri, M. K., Kooh, M. R. R., & Lim, L. B. L. (2015). Original Article. Alexandria Engineering Journal, 4(54), 1253–1263. https://doi.org/10.1016/J.AEJ.2015.07.005
- Demirbaş, O., Alkan, M., & Doğan, M. (2002). The removal of victoria blue from aqueous solution by adsorption on a low-cost material. Adsorption, 8(4), 341–349. https://doi.org/10.1023/A:1021589514766/METRICS
- Demirbaş, Ö., Çalımlı, M. H., Demirkan, B., Alma, M. H., Nas, M. S., Khan, A., Asiri, A. M., & Şen, F. (2019). Thermodynamics, Kinetics, and Adsorption Properties of Biomolecules onto Carbon-Based Materials Obtained from Food Wastes. BioNanoScience, 3(9), 672–682. https://doi.org/10.1007/S12668-019-00628-W
- Demirbaş, Ö., Turhan, Y., & Alkan, M. (2014). Thermodynamics and kinetics of adsorption of a cationic dye onto sepiolite. New Pub: Balaban, 54(3), 707–714. https://doi.org/10.1080/19443994.2014.886299
- Follain, N., Saiah, R., Fatyeyeva, K., Randrianandrasana, N., Leblanc, N., Marais, S., & Lecamp, L. (2015). Hydrophobic surface treatments of sunflower pith using eco-friendly processes. Cellulose, 22(1), 245–259. https://doi.org/10.1007/S10570-014-0490-1
- Ghaedi, M., Hajjati, S., Mahmudi, Z., Tyagi, I., Agarwal, S., Maity, A., & Gupta, V. K. (2015). Modeling of competitive ultrasonic assisted removal of the dyes – Methylene blue and Safranin-O using Fe3O4 nanoparticles. Chemical Engineering Journal, 268, 28–37. https://doi.org/10.1016/J.CEJ.2014.12.090
- Ho, Y. S., & McKay, G. (1999). Pseudo-second order model for sorption processes. Process Biochemistry, 34(5), 451–465. https://doi.org/10.1016/S0032-9592(98)00112-5
- Jalali, M., & Aboulghazi, F. (2013). Sunflower stalk, an agricultural waste, as an adsorbent for the removal of lead and cadmium from aqueous solutions. Journal of Material Cycles and Waste Management, 15(4), 548–555. https://doi.org/10.1007/S10163-012-0096-3/TABLES/5
- Jiang, C., Wang, X., Qin, D., Da, W., Hou, B., Hao, C., & Wu, J. (2019). Construction of magnetic lignin-based adsorbent and its adsorption properties for dyes. Journal of Hazardous Materials, 369, 50–61. https://doi.org/10.1016/J.JHAZMAT.2019.02.021
- Knapik, E., & Stopa, J. (2018). Fibrous deep-bed filtration for oil/water separation using sunflower pith as filter media. Ecological Engineering, 121, 44–52. https://doi.org/10.1016/J.ECOLENG.2017.07.021
- Li, Y., Liu, F., Xia, B., Du, Q., Zhang, P., Wang, D., Wang, Z., & Xia, Y. (2010). Removal of copper from aqueous solution by carbon nanotube/calcium alginate composites. Journal of Hazardous Materials, 177(1–3), 876–880. https://doi.org/10.1016/J.JHAZMAT.2009.12.114
- Liu, J., Wang, N., Zhang, H., & Baeyens, J. (2019). Adsorption of Congo red dye on FexCo3-xO4 nanoparticles. Journal of Environmental Management, 238, 473–483. https://doi.org/10.1016/J.JENVMAN.2019.03.009
- Nandi, B. K., Goswami, A., & Purkait, M. K. (2009). Adsorption characteristics of brilliant green dye on kaolin. Journal of Hazardous Materials, 161(1), 387–395. https://doi.org/10.1016/J.JHAZMAT.2008.03.110
- Nas, M. S. (2021). AgFe2O4/MWCNT nanoparticles as novel catalyst combined adsorption-sonocatalytic for the degradation of methylene blue under ultrasonic irradiation. Journal of Environmental Chemical Engineering, 9(3), 105207. https://doi.org/10.1016/J.JECE.2021.105207
- Nas, M. S., & Kaya, H. (2020). Synthesis and sonocatalytic performance of bimetallic AgCu@MWCNT nanocatalyst for the degradation of methylene blue under ultrasonic irradiation. Https://Doi.Org/10.1080/24701556.2020.1799406, 51(5), 614–626. https://doi.org/10.1080/24701556.2020.1799406
- Nas, M. salih. (2019). The Investigation of Thermodynamics Parameters and Adsorption Kinetic of The Maxilon Blue 5G Dye on Turkey Green Clay. Journal of the Institute of Science and Technology, 749–758. https://doi.org/10.21597/JIST.475791
- Oguntimein, G. B. (2015). Biosorption of dye from textile wastewater effluent onto alkali treated dried sunflower seed hull and design of a batch adsorber. Journal of Environmental Chemical Engineering, 3(4), 2647–2661. https://doi.org/10.1016/J.JECE.2015.09.028
- P., V., S., C., & W., A. (2009). Bioethanol production from enzymatically saccharified sunflower stalks using steam explosion as pretreatment. https://ir.swu.ac.th/jspui/handle/123456789/15454
- Parvin, S., Biswas, B. K., Rahman, M. A., Rahman, M. H., Anik, M. S., & Uddin, M. R. (2019). Study on adsorption of Congo red onto chemically modified egg shell membrane. Chemosphere, 236, 124326. https://doi.org/10.1016/J.CHEMOSPHERE.2019.07.057
- Podder, M. S., & Majumder, C. B. (2015). SD/MnFe2O4 composite, a biosorbent for As(III) and As(V) removal from wastewater: Optimization and isotherm study. Journal of Molecular Liquids, 212, 382–404. https://doi.org/10.1016/J.MOLLIQ.2015.09.011
- Şen, F., Demirbaş, Ö., Çalımlı, M. H., Aygün, A., Alma, M. H., & Nas, M. S. (2018). The dye removal from aqueous solution using polymer composite films. Applied Water Science, 8(7). https://doi.org/10.1007/S13201-018-0856-X
- Tang, S., Xia, D., Yao, Y., Chen, T., Sun, J., Yin, Y., Shen, W., & Peng, Y. (2019). Dye adsorption by self-recoverable, adjustable amphiphilic graphene aerogel. Journal of Colloid and Interface Science, 554, 682–691. https://doi.org/10.1016/J.JCIS.2019.07.041
- Wei, Y., Han, B., Hu, X., Lin, Y., Wang, X., & Deng, X. (2012). Synthesis of Fe3O4 Nanoparticles and their Magnetic Properties. Procedia Engineering, 27, 632–637. https://doi.org/10.1016/J.PROENG.2011.12.498
- Wekoye, J. N., Wanyonyi, W. C., Wangila, P. T., & Tonui, M. K. (2020). Kinetic and equilibrium studies of Congo red dye adsorption on cabbage waste powder. https://doi.org/10.1016/j.enceco.2020.01.004
- Xu, M., Qi, M., Goff, H. D., & Cui, S. W. (2020). Polysaccharides from sunflower stalk pith: Chemical, structural and functional characterization. Food Hydrocolloids, 100, 105082. https://doi.org/10.1016/J.FOODHYD.2019.04.053