Investigation on Characteristics of Natural Starch Based Coating as Potential Urea-Fertilizer Coating
Year 2025,
Volume: 22 Issue: 3, 636 - 644, 29.09.2025
Halus Satriawan
,
Eka Rahmı
Marıana Marıana
Ernawita Ernawita
Abstract
The conventional fertilizer application oftentimes inefficient due to rapid release and leaching, which in turn caused pollution to the environment. The technique to control or slowing down the release of nutrients of the fertilizer in a controlled manner known as slow-release fertilizer (SRF). In sustainable agriculture, the utilization of natural starch as coating materials give alternative of the use of non-green materials. The abundance of natural starches may be serve as potential sources for sustainable fertilizer coatings. This study aims to investigate the properties of the urea fertilizer coated with several natural starch materials and to identify the most potent natural starch coating agents. The research was conducted as follows: 1) formulation of fertilizer coatings sourced from 7 natural starches (porang, gadong, sago, taro, sorghum, glutinous rice, and mung bean starches) and one synthetic materials (carboxymethoxyl cellulose, CMC); 2) granulation of urea fertilizer with coatings produced from the formulation, 3) manufacture of fertilizer coating from 7 natural starches. The SRF fertilizers were then tested for drip resistance and nutrient release. Formulation of fertilizer coatings was 2% w/v of natural starch with polyethylene glycol (PEG) and gum arabic. Granulation with coatings resulted in 73% of the granule produced met the desired size criteria (2.5-5 mm in size). Drip resistance test showed that CMC showed the highest durability, followed by gayong starch and sorghum starch, consecutively. Comparison of nitrogen nutrient release of urea-SRF on distilled water and 2% citric acid showed higher urea-SRF solubility in 2% citric acid. Natural starches—particularly gadong, glutinous rice, sorghum, sago, and porang—have shown potential as natural coating materials. However, since the observed parameters were limited to water hatches and nitrogen release, further research is needed to optimize the use of these starches as slow-release fertilizer (SRF) coatings across a broader range of parameters.
Ethical Statement
There is no need to obtain permission from the ethics committee for this study.
Supporting Institution
Universitas Almuslim, Kemdikbudristek
Thanks
All author thanks to Direktorat Riset, Teknologi, dan Pengabdian Kepada Masyarakat Kemdikbudristek for supporting in this research.
References
-
Cerri, B. C., Borelli, L. M., Stelutti, I. M., Soares, M. R. and Da Silva, M. A. (2020). Evaluation of new environmental friendly particulate soil fertilizers based on agroindustry wastes biopolymers and sugarcane vinasse. Waste Management, 108: 144–153. https://doi.org/10.1016/j.wasman.2020.04.038
-
Chen, L., Xie, Z., Zhuang, X., Chen, X. and Jing, X. (2008). Controlled release of urea encapsulated by starch-g-poly (L-lactide). Carbohydrate Polymers, 72(2): 342-348.
-
Chen, Y., Li, W. and Zhang, S. (2021). A multifunctional eco-friendly fertilizer used keratin-based superabsorbent as coatings for slow-release urea and remediation of contaminated soil. Progress in Organic Coatings, 154: 106158. https://doi.org/10.1016/j.porgcoat.2021.106158
-
Demirkiran, A. R. (2017). The Determination and limitation of ammonia losses from fertilizers within soils by using different organic materials. Journal of Multidiciplinary Engineering Sciences and Technology (JMEST), 4(10): 8314- 8317.
-
Fan, Y., Xu, J., Gao, X., Fu, X. and Yang, X. (2019). Effect of alginate on the release of amide nitrogen for soilless cultivation applications. Scientia Horticulturae, 256: 108545. https://doi.org/10.1016/j.scienta.2019.108545
-
Fertahi, S., Ilsouk, M., Zeroual, Y., Oukarroum, A. and Barakat, A. (2021). Recent trends in organic coating based on biopolymers and biomass for controlled and slow release fertilizers. Journal of Controlled Release, 330: 341–361. https://doi.org/10.1016/j.jconrel.2020.12.026
-
Firmanda, A., Fahma, F., Syamsu, K., Suryanegara, L. and Wood, K. (2022). Controlled/slow‐release fertilizer based on cellulose composite and its impact on sustainable agriculture: Review. Biofuels, Bioproducts and Biorefining, 16(6): 1909–1930. https://doi.org/10.1002/bbb.2433
-
Himmah, N. I. F., Djajakirana, G. and Darmawan, D. (2018). Nutrient release performance of starch coated NPK fertilizers and their effects on corn growth. SAINS TANAH - Journal of Soil Science and Agroclimatology, 15(2): 104. https://doi.org/10.15608/stjssa.v15i2.19694
-
Karakuş, Ö., Gençoğlan, C. and Gençoğlan, S. (2022). Determination of nitrogen leaching under precipitation conditions from weighted lysimeter planted walnut (Juglans regia L.). Journal of Tekirdag Agricultural Faculty, 19(1): 192-203.
-
Kim, S. R. B., Choi, Y.-G., Kim, J.-Y. and Lim, S.-T. (2015). Improvement of water solubility and humidity stability of tapioca starch film by incorporating various gums. LWT - Food Science and Technology, 64(1): 475–482. https://doi.org/10.1016/j.lwt.2015.05.009
-
Lawrencia, D., Wong, S. K., Low, D. Y. S., Goh, B. H., Goh, J. K., Ruktanonchai, U. R., Soottitantawat, A., Lee, L. H. and Tang, S. Y. (2021). Controlled Release Fertilizers: A Review on coating materials and mechanism of release. Plants, 10(2): 238. https://doi.org/10.3390/plants10020238
-
Lestari, R. S. D., Jayanudin, J., Irawanto, D., Rozak, R., Wardana, R. L. A. and Muhammad, F. (2020). Preparation and characterization Double Cross Link Glutaraldehyde Chitosan as Urea Fertilizer Matrix. Jurnal Integrasi Proses, 9(2): 27. https://doi.org/10.36055/jip.v9i2.9221 (In Bahasa).
-
Muslim, S., Fitriani, L., Suharty, N., Erizal, Z., Febriyenti, F., Salman, S., Aldi, Y. and Akmal, D. (2015). Use of bioblend polystyrene/starch for coating urea granules as slow release fertilizer. Journal of Chemical and Pharmaceutical Research, 7(11): 478–484.
-
Naz, M. Y. and Sulaiman, S. A. (2017). Attributes of natural and synthetic materials pertaining to slow-release urea coating industry. Reviews in Chemical Engineering, 33(3): 293-308.
-
Ningtias, D. (2017). Mixture of zeolit and sago starch as coating agent of urea and its application as nitroge slow relase fertilizer. (B.Sc. Thesis) IPB University, Faculty of Mathematics and Natural Sciences, Bogor, Indonesia (In Bahasa).
-
Noviana, G., Ardiani, F., Santi, I. S. and Hartono, H. (2023). The effect of different fertilization frequency on some nutrient content of palm plant grown in peat swamp. Journal of Tekirdağ Agricultural Faculty, 20(3): 586-590.
-
Olad, A., Zebhi, H., Salari, D., Mirmohseni, A. and Reyhani Tabar, A. (2018). Slow-release NPK fertilizer
encapsulated by carboxymethyl cellulose-based nanocomposite with the function of water retention in soil. Materials Science and Engineering: C, 90: 333–340. https://doi.org/10.1016/j.msec.2018.04.083
-
Purnomo, C. W. and Saputra, H. (2021). Manufacturing of slow and controlled release fertilizer. In: Controlled Release Fertilizers for Sustainable Agriculture, Ed(s): Lewu, F. B., Volova, T., Thomas, S. and Rakhimol K. R. Elsevier, Netherlands. https://doi.org/10.1016/B978-0-12-819555-0.00006-6
-
Salimi, M., Channab, B. E., El Idrissi, A., Zahouily, M. and Motamedi, E. (2023). A comprehensive review on starch: Structure, modification, and applications in slow/controlled-release fertilizers in agriculture. Carbohydrate Polymers, 322: 121326.
-
Sarwono, A., Man, Z. and Bustam, M. A. (2013). Improvement of hydrophobicity of urea modified tapioca starch film with lignin for slow release fertilizer. Advanced Materials Research, 626: 350-354.
-
Suci, Ida, A. and Astar I. (2022). Enkapsulasi urea menggunakan biokomposit zeolit alam alginat-pati sagu sebagai model pupuk lepas lambat (slow release fertilizer). Al-Kimia, 10(1): 1- 11 (In Bahasa)
-
Tanan, W., Panichpakdee, J., Suwanakood, P. and Saengsuwan, S. (2021). Biodegradable hydrogels of cassava starch-g-polyacrylic acid/natural rubber/polyvinyl alcohol as environmentally friendly and highly efficient coating material for slow-release urea fertilizers. Journal of Industrial and Engineering Chemistry, 101: 237–252. https://doi.org/10.1016/j.jiec.2021.06.008
-
Trenkel, M. (2010). Slow-and Controlled-Release and Stabilized Fertilizers: An Option for Enhancing Nutrient Use Efficiency in Agriculture. International Fertilizer Industry Association (IFA) Publisher. Paris, France.
-
Versino, F., Urriza, M. and García, M. A. (2019). Eco-compatible cassava starch films for fertilizer controlled-release. International Journal of Biological Macromolecules, 134: 302–307. https://doi.org/10.1016/j.ijbiomac.2019.05.037
Investigation on Characteristics of Natural Starch Based Coating as Potential Urea-Fertilizer Coating
Year 2025,
Volume: 22 Issue: 3, 636 - 644, 29.09.2025
Halus Satriawan
,
Eka Rahmı
Marıana Marıana
Ernawita Ernawita
Abstract
The conventional fertilizer application oftentimes inefficient due to rapid release and leaching, which in turn caused pollution to the environment. The technique to control or slowing down the release of nutrients of the fertilizer in a controlled manner known as slow-release fertilizer (SRF). In sustainable agriculture, the utilization of natural starch as coating materials give alternative of the use of non-green materials. The abundance of natural starches may be serve as potential sources for sustainable fertilizer coatings. This study aims to investigate the properties of the urea fertilizer coated with several natural starch materials and to identify the most potent natural starch coating agents. The research was conducted as follows: 1) formulation of fertilizer coatings sourced from 7 natural starches (porang, gadong, sago, taro, sorghum, glutinous rice, and mung bean starches) and one synthetic materials (carboxymethoxyl cellulose, CMC); 2) granulation of urea fertilizer with coatings produced from the formulation, 3) manufacture of fertilizer coating from 7 natural starches. The SRF fertilizers were then tested for drip resistance and nutrient release. Formulation of fertilizer coatings was 2% w/v of natural starch with polyethylene glycol (PEG) and gum arabic. Granulation with coatings resulted in 73% of the granule produced met the desired size criteria (2.5-5 mm in size). Drip resistance test showed that CMC showed the highest durability, followed by gayong starch and sorghum starch, consecutively. Comparison of nitrogen nutrient release of urea-SRF on distilled water and 2% citric acid showed higher urea-SRF solubility in 2% citric acid. Natural starches—particularly gadong, glutinous rice, sorghum, sago, and porang—have shown potential as natural coating materials. However, since the observed parameters were limited to water hatches and nitrogen release, further research is needed to optimize the use of these starches as slow-release fertilizer (SRF) coatings across a broader range of parameters.
Ethical Statement
There is no need to obtain permission from the ethics committee for this study.
Supporting Institution
Universitas Almuslim, Kemdikbudristek
Thanks
All author thanks to Direktorat Riset, Teknologi, dan Pengabdian Kepada Masyarakat Kemdikbudristek for supporting in this research.
References
-
Cerri, B. C., Borelli, L. M., Stelutti, I. M., Soares, M. R. and Da Silva, M. A. (2020). Evaluation of new environmental friendly particulate soil fertilizers based on agroindustry wastes biopolymers and sugarcane vinasse. Waste Management, 108: 144–153. https://doi.org/10.1016/j.wasman.2020.04.038
-
Chen, L., Xie, Z., Zhuang, X., Chen, X. and Jing, X. (2008). Controlled release of urea encapsulated by starch-g-poly (L-lactide). Carbohydrate Polymers, 72(2): 342-348.
-
Chen, Y., Li, W. and Zhang, S. (2021). A multifunctional eco-friendly fertilizer used keratin-based superabsorbent as coatings for slow-release urea and remediation of contaminated soil. Progress in Organic Coatings, 154: 106158. https://doi.org/10.1016/j.porgcoat.2021.106158
-
Demirkiran, A. R. (2017). The Determination and limitation of ammonia losses from fertilizers within soils by using different organic materials. Journal of Multidiciplinary Engineering Sciences and Technology (JMEST), 4(10): 8314- 8317.
-
Fan, Y., Xu, J., Gao, X., Fu, X. and Yang, X. (2019). Effect of alginate on the release of amide nitrogen for soilless cultivation applications. Scientia Horticulturae, 256: 108545. https://doi.org/10.1016/j.scienta.2019.108545
-
Fertahi, S., Ilsouk, M., Zeroual, Y., Oukarroum, A. and Barakat, A. (2021). Recent trends in organic coating based on biopolymers and biomass for controlled and slow release fertilizers. Journal of Controlled Release, 330: 341–361. https://doi.org/10.1016/j.jconrel.2020.12.026
-
Firmanda, A., Fahma, F., Syamsu, K., Suryanegara, L. and Wood, K. (2022). Controlled/slow‐release fertilizer based on cellulose composite and its impact on sustainable agriculture: Review. Biofuels, Bioproducts and Biorefining, 16(6): 1909–1930. https://doi.org/10.1002/bbb.2433
-
Himmah, N. I. F., Djajakirana, G. and Darmawan, D. (2018). Nutrient release performance of starch coated NPK fertilizers and their effects on corn growth. SAINS TANAH - Journal of Soil Science and Agroclimatology, 15(2): 104. https://doi.org/10.15608/stjssa.v15i2.19694
-
Karakuş, Ö., Gençoğlan, C. and Gençoğlan, S. (2022). Determination of nitrogen leaching under precipitation conditions from weighted lysimeter planted walnut (Juglans regia L.). Journal of Tekirdag Agricultural Faculty, 19(1): 192-203.
-
Kim, S. R. B., Choi, Y.-G., Kim, J.-Y. and Lim, S.-T. (2015). Improvement of water solubility and humidity stability of tapioca starch film by incorporating various gums. LWT - Food Science and Technology, 64(1): 475–482. https://doi.org/10.1016/j.lwt.2015.05.009
-
Lawrencia, D., Wong, S. K., Low, D. Y. S., Goh, B. H., Goh, J. K., Ruktanonchai, U. R., Soottitantawat, A., Lee, L. H. and Tang, S. Y. (2021). Controlled Release Fertilizers: A Review on coating materials and mechanism of release. Plants, 10(2): 238. https://doi.org/10.3390/plants10020238
-
Lestari, R. S. D., Jayanudin, J., Irawanto, D., Rozak, R., Wardana, R. L. A. and Muhammad, F. (2020). Preparation and characterization Double Cross Link Glutaraldehyde Chitosan as Urea Fertilizer Matrix. Jurnal Integrasi Proses, 9(2): 27. https://doi.org/10.36055/jip.v9i2.9221 (In Bahasa).
-
Muslim, S., Fitriani, L., Suharty, N., Erizal, Z., Febriyenti, F., Salman, S., Aldi, Y. and Akmal, D. (2015). Use of bioblend polystyrene/starch for coating urea granules as slow release fertilizer. Journal of Chemical and Pharmaceutical Research, 7(11): 478–484.
-
Naz, M. Y. and Sulaiman, S. A. (2017). Attributes of natural and synthetic materials pertaining to slow-release urea coating industry. Reviews in Chemical Engineering, 33(3): 293-308.
-
Ningtias, D. (2017). Mixture of zeolit and sago starch as coating agent of urea and its application as nitroge slow relase fertilizer. (B.Sc. Thesis) IPB University, Faculty of Mathematics and Natural Sciences, Bogor, Indonesia (In Bahasa).
-
Noviana, G., Ardiani, F., Santi, I. S. and Hartono, H. (2023). The effect of different fertilization frequency on some nutrient content of palm plant grown in peat swamp. Journal of Tekirdağ Agricultural Faculty, 20(3): 586-590.
-
Olad, A., Zebhi, H., Salari, D., Mirmohseni, A. and Reyhani Tabar, A. (2018). Slow-release NPK fertilizer
encapsulated by carboxymethyl cellulose-based nanocomposite with the function of water retention in soil. Materials Science and Engineering: C, 90: 333–340. https://doi.org/10.1016/j.msec.2018.04.083
-
Purnomo, C. W. and Saputra, H. (2021). Manufacturing of slow and controlled release fertilizer. In: Controlled Release Fertilizers for Sustainable Agriculture, Ed(s): Lewu, F. B., Volova, T., Thomas, S. and Rakhimol K. R. Elsevier, Netherlands. https://doi.org/10.1016/B978-0-12-819555-0.00006-6
-
Salimi, M., Channab, B. E., El Idrissi, A., Zahouily, M. and Motamedi, E. (2023). A comprehensive review on starch: Structure, modification, and applications in slow/controlled-release fertilizers in agriculture. Carbohydrate Polymers, 322: 121326.
-
Sarwono, A., Man, Z. and Bustam, M. A. (2013). Improvement of hydrophobicity of urea modified tapioca starch film with lignin for slow release fertilizer. Advanced Materials Research, 626: 350-354.
-
Suci, Ida, A. and Astar I. (2022). Enkapsulasi urea menggunakan biokomposit zeolit alam alginat-pati sagu sebagai model pupuk lepas lambat (slow release fertilizer). Al-Kimia, 10(1): 1- 11 (In Bahasa)
-
Tanan, W., Panichpakdee, J., Suwanakood, P. and Saengsuwan, S. (2021). Biodegradable hydrogels of cassava starch-g-polyacrylic acid/natural rubber/polyvinyl alcohol as environmentally friendly and highly efficient coating material for slow-release urea fertilizers. Journal of Industrial and Engineering Chemistry, 101: 237–252. https://doi.org/10.1016/j.jiec.2021.06.008
-
Trenkel, M. (2010). Slow-and Controlled-Release and Stabilized Fertilizers: An Option for Enhancing Nutrient Use Efficiency in Agriculture. International Fertilizer Industry Association (IFA) Publisher. Paris, France.
-
Versino, F., Urriza, M. and García, M. A. (2019). Eco-compatible cassava starch films for fertilizer controlled-release. International Journal of Biological Macromolecules, 134: 302–307. https://doi.org/10.1016/j.ijbiomac.2019.05.037