Comparison of Polyacrylonitrile-and Polypyrrole-based Electrochemical Sensors for Detection of Propamocarb in Food Samples

Year 2022, Volume: 9 Issue: 3, 801 - 808, 31.08.2022

Selcan Karakuş Cihat Tasaltın İlke Gürol Barbaros Akkurt Gülsen Baytemir Nevin Taşaltın

https://doi.org/10.18596/jotcsa.1087096

Abstract

Food safety is a crucial issue; all countries have struggled against pesticides for years. In this study, Polypyrrole (PPy)- and Polyacrylonitrile (PAN)-based non-enzymatic electrochemical sensors were investigated to detect the pesticide propamocarb (PM) in food samples. Under the experimental conditions, the proposed strategy exhibited a high selectivity of the disposable PPy-based and PAN-based sensors for the determination of propamocarb pesticide in the concentration of 1 μM with a rapid detection within 1 min at pH 7.4 and 25 °C. We demonstrated the detection of PM residues on cucumber and tomato samples with good electrochemical performances towards the real-time usability on real food samples. PAN-based non-enzymatic electrochemical sensor has good sensitivity, higher selectivity, and stability than PPy-based non-enzymatic electrochemical sensor. The prepared PAN-based non-enzymatic electrochemical sensor is a potential candidate to be used in devices which perform food safety in agricultural products.

Keywords

food safety, pesticides, electrochemical sensors, polypyrrole, polyacrylonitrile

Supporting Institution

TUBITAK

Project Number

120N816

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