Research Article

Evaluation of Corrosion Inhibition Performance and Surface Characterization of PCL-Coated Aluminum Alloys

Volume: 8 Number: 2 September 15, 2025
EN

Evaluation of Corrosion Inhibition Performance and Surface Characterization of PCL-Coated Aluminum Alloys

Abstract

Corrosion is a natural and unavoidable process that must be controlled to minimize damage to metals across various industries. One effective method for corrosion inhibition is the use of polymer coatings. In this study, Al alloy coupons were coated with a 10% concentrated solution of compound polycaprolactone (PCL)  using a dip coater. Different dip-coating parameters were tested, including drying time, dwell time, speed, and number of cycles. Both coated and uncoated Al alloy coupons were immersed in 1 M HCl solution for 1, 2, 3, 7, and 15 days. Corrosion behavior was evaluated using the weight loss method. Among the samples, Sample 3 (5 cycles, 200 mm/s speed, 60 s dwell time, 30 s drying time) showed the highest corrosion inhibition efficiency, while Sample 4 (5 cycles, 300 mm/s speed, 60 s dwell time, 60 s dry time) exhibited the poorest performance. In addition to the weight loss analysis, SEM-EDX and FTIR analyses were conducted on Sample 2 and an uncoated Fe alloy coupon before and after corrosion testing.

Keywords

References

  1. Al-Amiery, A., Salman, T. A., Alazawi, K. F., Shaker, L. M., Kadhum, A. A. H., Takriff, M. S. (2020). “Quantum Chemical elucidation on corrosion inhibition efficency of Schiff Base: DFT investigations supported by weight loss and SEM techniques”, International Journal of Low—Carbon Technologies, 15, 202-209. http:// doi:10.1093/ijlct/ctz074.
  2. AlFalah, M. G. K., Kamberli E., Abbar A. H., Kandemirli F., Saracoğlu M. (2020). “Corrosion performance of electrospinning nanofiber ZnO-NiO-CuO/PCL coated on mild steel in acid solution”, Surfaces and Interfaces, 21, 100760.https://doi.org/10.1016/j.surfin.2020.100760.
  3. Arunagiri, V., Prasannan, A., Udomsin, J., Lai, J. Y., Wang, C. F., Hong, P. D., Tsai, H. C. (2021). “Facile fabrication of eco-friendly PCL/Poly-D, L-Lactic acid (PDLLA) modified melamine sorbent for oil spill cleaning and water/oil (W/O) emulsion separation”, Separation and Purification Technology 259, 118081.https://doi.org/10.1016/j.seppur.2020.118081.
  4. Berrisoul, A., Ouarhach, A., Benhiba, Romane, F. A., Guenbour, A., Dikici, B., Bentiss, F., Zarrouk, A., Dafali, A. (2022). “Assessment of corrosion inhibition performance of origanum compactum extract for mild steel in 1 M HCl: Weight loss, electrochemical, SEM/EDX, XPS, DFT and molecular dynamic simulation”, Industrial Corps & Products 187, 115310. https://doi.org/10.1016/j.indcrop.2022.115310.
  5. Brough, D. & Jouhara, H. (2020). “The Aluminium industry: A review on state-of-the-art technologies, environmental impacts and possibilities for waste heat recovery“, International Journal of Thermofluids 1 - 2, 10007.https://doi.org/10.1016/j.ijft.2019.100007.
  6. Chin, P. Y. Y., Cheok, Q., Glowacz, A., Caesarendra, W. (2020). “A review of In-Vivo and In-Vitro Real-Time Corrosion Monitoring Systems of Biodegradable Metal Implants”, applied sciences, 10, 3141. https:// doi:10.3390/app10093141.
  7. Gnedenkov, A. S., Kononenko, Y. I., Sinebryukhov, S. L., Filonina, V. S., Vyaliy, I. E., Nomerovskii, A. D., Ustinov, A. Y., Gnedenkov, S. V. (2023). “The Effect of Smart PEO-Coatings Impregnated with Corrosion Inhibitors on the Protective Properties of AlMg3 Aluminium Alloy”, mateials, 16, 2215. https://doi.org/10.3390/ma16062215.
  8. Hegde, M., Mohan, J., Warraich, M. Q. M. Kavanagh, Y., Duffy, B., Tobin, E. F. (2023). “Cavitation erosion and corrosion resistance of hydrophobic sol-gel coatings on aluminium alloy”, Wear 524-525, 204766. https://doi.org/10.1016/j.wear.2023.204766.

Details

Primary Language

English

Subjects

Electrochemical Technologies, Materials Engineering (Other)

Journal Section

Research Article

Publication Date

September 15, 2025

Submission Date

September 20, 2024

Acceptance Date

July 28, 2025

Published in Issue

Year 2025 Volume: 8 Number: 2

APA
Kandemirli, F., Kamberli, E., & Nazli, B. (2025). Evaluation of Corrosion Inhibition Performance and Surface Characterization of PCL-Coated Aluminum Alloys. Journal of the Turkish Chemical Society Section B: Chemical Engineering, 8(2), 203-212. https://doi.org/10.58692/jotcsb.1553333
AMA
1.Kandemirli F, Kamberli E, Nazli B. Evaluation of Corrosion Inhibition Performance and Surface Characterization of PCL-Coated Aluminum Alloys. JOTCSB. 2025;8(2):203-212. doi:10.58692/jotcsb.1553333
Chicago
Kandemirli, Fatma, Ersin Kamberli, and Bahar Nazli. 2025. “Evaluation of Corrosion Inhibition Performance and Surface Characterization of PCL-Coated Aluminum Alloys”. Journal of the Turkish Chemical Society Section B: Chemical Engineering 8 (2): 203-12. https://doi.org/10.58692/jotcsb.1553333.
EndNote
Kandemirli F, Kamberli E, Nazli B (September 1, 2025) Evaluation of Corrosion Inhibition Performance and Surface Characterization of PCL-Coated Aluminum Alloys. Journal of the Turkish Chemical Society Section B: Chemical Engineering 8 2 203–212.
IEEE
[1]F. Kandemirli, E. Kamberli, and B. Nazli, “Evaluation of Corrosion Inhibition Performance and Surface Characterization of PCL-Coated Aluminum Alloys”, JOTCSB, vol. 8, no. 2, pp. 203–212, Sept. 2025, doi: 10.58692/jotcsb.1553333.
ISNAD
Kandemirli, Fatma - Kamberli, Ersin - Nazli, Bahar. “Evaluation of Corrosion Inhibition Performance and Surface Characterization of PCL-Coated Aluminum Alloys”. Journal of the Turkish Chemical Society Section B: Chemical Engineering 8/2 (September 1, 2025): 203-212. https://doi.org/10.58692/jotcsb.1553333.
JAMA
1.Kandemirli F, Kamberli E, Nazli B. Evaluation of Corrosion Inhibition Performance and Surface Characterization of PCL-Coated Aluminum Alloys. JOTCSB. 2025;8:203–212.
MLA
Kandemirli, Fatma, et al. “Evaluation of Corrosion Inhibition Performance and Surface Characterization of PCL-Coated Aluminum Alloys”. Journal of the Turkish Chemical Society Section B: Chemical Engineering, vol. 8, no. 2, Sept. 2025, pp. 203-12, doi:10.58692/jotcsb.1553333.
Vancouver
1.Fatma Kandemirli, Ersin Kamberli, Bahar Nazli. Evaluation of Corrosion Inhibition Performance and Surface Characterization of PCL-Coated Aluminum Alloys. JOTCSB. 2025 Sep. 1;8(2):203-12. doi:10.58692/jotcsb.1553333

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J. Turk. Chem. Soc., Sect. B: Chem. Eng. (JOTCSB)