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Year 2025, Volume: 8 Issue: 2, 203 - 212, 15.09.2025
https://doi.org/10.58692/jotcsb.1553333

Abstract

References

  • Al-Amiery, A., Salman, T. A., Alazawi, K. F., Shaker, L. M., Kadhum, A. A. H., Takriff, M. S. (2020). “Quantum Chemical elucidation on corrosion inhibition efficency of Schiff Base: DFT investigations supported by weight loss and SEM techniques”, International Journal of Low—Carbon Technologies, 15, 202-209. http:// doi:10.1093/ijlct/ctz074.
  • AlFalah, M. G. K., Kamberli E., Abbar A. H., Kandemirli F., Saracoğlu M. (2020). “Corrosion performance of electrospinning nanofiber ZnO-NiO-CuO/PCL coated on mild steel in acid solution”, Surfaces and Interfaces, 21, 100760.https://doi.org/10.1016/j.surfin.2020.100760.
  • Arunagiri, V., Prasannan, A., Udomsin, J., Lai, J. Y., Wang, C. F., Hong, P. D., Tsai, H. C. (2021). “Facile fabrication of eco-friendly PCL/Poly-D, L-Lactic acid (PDLLA) modified melamine sorbent for oil spill cleaning and water/oil (W/O) emulsion separation”, Separation and Purification Technology 259, 118081.https://doi.org/10.1016/j.seppur.2020.118081.
  • Berrisoul, A., Ouarhach, A., Benhiba, Romane, F. A., Guenbour, A., Dikici, B., Bentiss, F., Zarrouk, A., Dafali, A. (2022). “Assessment of corrosion inhibition performance of origanum compactum extract for mild steel in 1 M HCl: Weight loss, electrochemical, SEM/EDX, XPS, DFT and molecular dynamic simulation”, Industrial Corps & Products 187, 115310. https://doi.org/10.1016/j.indcrop.2022.115310.
  • Brough, D. & Jouhara, H. (2020). “The Aluminium industry: A review on state-of-the-art technologies, environmental impacts and possibilities for waste heat recovery“, International Journal of Thermofluids 1 - 2, 10007.https://doi.org/10.1016/j.ijft.2019.100007.
  • Chin, P. Y. Y., Cheok, Q., Glowacz, A., Caesarendra, W. (2020). “A review of In-Vivo and In-Vitro Real-Time Corrosion Monitoring Systems of Biodegradable Metal Implants”, applied sciences, 10, 3141. https:// doi:10.3390/app10093141.
  • Gnedenkov, A. S., Kononenko, Y. I., Sinebryukhov, S. L., Filonina, V. S., Vyaliy, I. E., Nomerovskii, A. D., Ustinov, A. Y., Gnedenkov, S. V. (2023). “The Effect of Smart PEO-Coatings Impregnated with Corrosion Inhibitors on the Protective Properties of AlMg3 Aluminium Alloy”, mateials, 16, 2215. https://doi.org/10.3390/ma16062215.
  • Hegde, M., Mohan, J., Warraich, M. Q. M. Kavanagh, Y., Duffy, B., Tobin, E. F. (2023). “Cavitation erosion and corrosion resistance of hydrophobic sol-gel coatings on aluminium alloy”, Wear 524-525, 204766. https://doi.org/10.1016/j.wear.2023.204766.
  • Kaufman, J. G. (2019). “Corrosion of Aluminium and Aluminium Alloys“, Book Chapter, Properties and Selection of Aluminium Alloys, ASM International.
  • Knigge, S., Mueller, M., Fricke, L., Schilling, T., Glasmacher, B. (2023) “In Vitro Investigation of Corrosion Control of Magnesium with Degradable PCL Coatings for Cardiovascular Grafts”, Coatings, 13,94. https://doi.org/10.3390/coatings13010094.
  • Krüger, L., Tuchscheerer, F., Mandel, M., Müller, S., Liebsch, S. (2012). “Corrosion behaviour of aluminium alloys in ethanol fuels”, Journal of Material Sciences, 47:2798-2806. DOI 10.1007/s10853-011-6108-1.
  • Kumar, S., Singh, R., Maurya, S. N., Vikram, J. (2023). “Monitoring of Corrosion in the Pipeline of a Distribution Network Using Weight Loss Method and Image Processing Technique”, Journal of Materials Engineering and Performance, Vol. 32, No.19, 8731-8737.
  • Mansfeld, F. & Kenkel, J. V. (1975). “Galvanic Corrosion of Al Alloys-III. The Effect of Area Ratio”, Corrosion Science, Vol. 15, 239-250.
  • Nesane, T., Madala, N. E., Kabanda, M. M., Murulana, L. C. (2023). “Experimental and theoretical studies on the inhibitory potential of Lippia javanica leaf extract for aluminium corrosion in 1M HCl medium”, Journal of Adhesion Science and Technology, Vol. 37, No. 24, 3517-3551. https://doi.org/10.1080/01694243.2023.2211788.
  • Pesha, T., Mulaudzi, V. L., Cele, M. L., Mothapo, M. P., Ratshisindi, F. (2023). “Evaluation of corrosion inhibition effect of glycerol stearate on aluminium metal by electrochemical techniques”, Arabian Journal of Chemistry, 16, 104798. https://doi.org/10.1016/j.arabjc.2023.104798.
  • Rajzer, I., Menaszek, E., Kwiatkowski, R., Planell, J. A., Castano, O. (2014). “Electrospun gelatin/caprolactone fibrous scaffold modified with calcium phosphate for bone tissue engineering”, Materials Science and Engineering C, Vol. 44, 183-190. http://dx.doi.org/10.1016/j.msec.2014.08.017.
  • Rodic, P., Milosev, I., Lekka, M., Andreatta F., Fedrizzi, L. (2018). “Corrosion behaviour and chemical stability of transparent hybrid sol-gel coatings deposited on aluminium in acidic and alkaline solutions”, Progress in Organic Coatings 124, 286-295. https://doi.org/10.1016/j.porgcoat.2018.02.025
  • Ruhi, G., Modi, O. P., Singh, I. B., Jha, A.K., Yegneswaran, A.H. (2006). “Wear and electrochemical characterization of sol-gel alumina coating on chemically pre-treated mild steel substrate”, Surfaces And Coatings Technologies. 201:1866-1872. https: //doi:10.1016/j.surfcoat.2006.03.013.
  • Sabarirajan, N., Sait, A. N., Thanikodi, S., Giri, J. (2025). “A novel technique to examine the corrosion resistance of FSW dissimilar aluminium alloys under three diferent corrosion solutions”, The International Journal of Advanced Manufacturing Technology, Vol. 136:133-144.
  • Sun, Y. (2023) “The use of aluminium alloys in structures: Review and outlook”, Structures 57, 105290,. https://doi.org/10.1016/j.istruc.2023.105290
  • Tran, D. T., Chen, F. H., Wu, G. L., Ching, P. C. O., Yeh, M. L. (2023). “Influence of Spin Coating and Dip Coating with Gelatin/Hydroxyapatite for Bioresorbable Mg Alloy Orthopedic Implants: In Vitro and In Vivo Studies”, ACS Biomater. Sci. Eng, 9,2, 705-718. https://doi.org/10.1021/acsbiomaterials.2c01122.
  • Usman, A. D., Victoria, A. F., Okoro, L. N. (2015a). “Weight Loss Corrosion Study of Some Metals in Acid Medium”, Journal of Advances in Chemistry , Vol. 11, No.2, 3434-3440.
  • Usman, A. D., Okoro, L. N. (2015b). “A review: Weight Loss Studies on the Corrosion Behaviour of Some Metals in Various Media”, Chemical Science Reviews and Letters, Vol. 4, No.13, 17-24.
  • Vega, A. S., Berriozabal, G., Urbegain, A., Minudri, D., Somers, A., Forsyth, M., Caracena, R., Marinova, N. (2024). "Exploring Sustainable Coating Solutions for Applications in Highly Corrosive Environments", Coatings, 14, 521:1-23. doi.org/10.3390/coatings14050521.
  • Vinodhini, S. P. & Xavier, J. R. (2023). “Effects of carbon nanotubes-based composites on the corrosion protection and mechanical properties of polymer coatings in chloride environments ”, Materials Science and Engineeering B 295, 116621. https://doi.org/10.1016/j.mseb.2023.116621.
  • Xu, Z., Feng, X., Huang, J., Wu, S., Zhou, P., Li, H. (2022). “Suspension Flame Spray Construction of Porous” PCL/Hydroxyapatite Coatings for Marine Ecological Remediation”, J Therm Spray Tech, 31:1490-1498. https://doi.org/10.1007/s11666-022-01384-2.
  • Yanardag T., Bayraktar N., Yanardag Y. K., Ozgen Y., Aksut A. A. (2020). “The Inhibitor Effects Of Cannabis Sativa L. Extracts On The Corrosion Of Aluminium In H2so4 Solutıons”
  • Zehra, S., Mobin, M., Aslam, R. (2022). “Corrosion prevention and protection methods”, Eco-Friendly Corrosion Inhibitors, Chapter-2, Edited by : L. Guo, C. Verma, D. Zhang. Elsevier.

Evaluation of Corrosion Inhibition Performance and Surface Characterization of PCL-Coated Aluminum Alloys

Year 2025, Volume: 8 Issue: 2, 203 - 212, 15.09.2025
https://doi.org/10.58692/jotcsb.1553333

Abstract

Corrosion is a natural and unavoidable process that must be controlled to minimize damage to metals across various industries. One effective method for corrosion inhibition is the use of polymer coatings. In this study, Al alloy coupons were coated with a 10% concentrated solution of compound polycaprolactone (PCL)  using a dip coater. Different dip-coating parameters were tested, including drying time, dwell time, speed, and number of cycles. Both coated and uncoated Al alloy coupons were immersed in 1 M HCl solution for 1, 2, 3, 7, and 15 days. Corrosion behavior was evaluated using the weight loss method. Among the samples, Sample 3 (5 cycles, 200 mm/s speed, 60 s dwell time, 30 s drying time) showed the highest corrosion inhibition efficiency, while Sample 4 (5 cycles, 300 mm/s speed, 60 s dwell time, 60 s dry time) exhibited the poorest performance. In addition to the weight loss analysis, SEM-EDX and FTIR analyses were conducted on Sample 2 and an uncoated Fe alloy coupon before and after corrosion testing.

References

  • Al-Amiery, A., Salman, T. A., Alazawi, K. F., Shaker, L. M., Kadhum, A. A. H., Takriff, M. S. (2020). “Quantum Chemical elucidation on corrosion inhibition efficency of Schiff Base: DFT investigations supported by weight loss and SEM techniques”, International Journal of Low—Carbon Technologies, 15, 202-209. http:// doi:10.1093/ijlct/ctz074.
  • AlFalah, M. G. K., Kamberli E., Abbar A. H., Kandemirli F., Saracoğlu M. (2020). “Corrosion performance of electrospinning nanofiber ZnO-NiO-CuO/PCL coated on mild steel in acid solution”, Surfaces and Interfaces, 21, 100760.https://doi.org/10.1016/j.surfin.2020.100760.
  • Arunagiri, V., Prasannan, A., Udomsin, J., Lai, J. Y., Wang, C. F., Hong, P. D., Tsai, H. C. (2021). “Facile fabrication of eco-friendly PCL/Poly-D, L-Lactic acid (PDLLA) modified melamine sorbent for oil spill cleaning and water/oil (W/O) emulsion separation”, Separation and Purification Technology 259, 118081.https://doi.org/10.1016/j.seppur.2020.118081.
  • Berrisoul, A., Ouarhach, A., Benhiba, Romane, F. A., Guenbour, A., Dikici, B., Bentiss, F., Zarrouk, A., Dafali, A. (2022). “Assessment of corrosion inhibition performance of origanum compactum extract for mild steel in 1 M HCl: Weight loss, electrochemical, SEM/EDX, XPS, DFT and molecular dynamic simulation”, Industrial Corps & Products 187, 115310. https://doi.org/10.1016/j.indcrop.2022.115310.
  • Brough, D. & Jouhara, H. (2020). “The Aluminium industry: A review on state-of-the-art technologies, environmental impacts and possibilities for waste heat recovery“, International Journal of Thermofluids 1 - 2, 10007.https://doi.org/10.1016/j.ijft.2019.100007.
  • Chin, P. Y. Y., Cheok, Q., Glowacz, A., Caesarendra, W. (2020). “A review of In-Vivo and In-Vitro Real-Time Corrosion Monitoring Systems of Biodegradable Metal Implants”, applied sciences, 10, 3141. https:// doi:10.3390/app10093141.
  • Gnedenkov, A. S., Kononenko, Y. I., Sinebryukhov, S. L., Filonina, V. S., Vyaliy, I. E., Nomerovskii, A. D., Ustinov, A. Y., Gnedenkov, S. V. (2023). “The Effect of Smart PEO-Coatings Impregnated with Corrosion Inhibitors on the Protective Properties of AlMg3 Aluminium Alloy”, mateials, 16, 2215. https://doi.org/10.3390/ma16062215.
  • Hegde, M., Mohan, J., Warraich, M. Q. M. Kavanagh, Y., Duffy, B., Tobin, E. F. (2023). “Cavitation erosion and corrosion resistance of hydrophobic sol-gel coatings on aluminium alloy”, Wear 524-525, 204766. https://doi.org/10.1016/j.wear.2023.204766.
  • Kaufman, J. G. (2019). “Corrosion of Aluminium and Aluminium Alloys“, Book Chapter, Properties and Selection of Aluminium Alloys, ASM International.
  • Knigge, S., Mueller, M., Fricke, L., Schilling, T., Glasmacher, B. (2023) “In Vitro Investigation of Corrosion Control of Magnesium with Degradable PCL Coatings for Cardiovascular Grafts”, Coatings, 13,94. https://doi.org/10.3390/coatings13010094.
  • Krüger, L., Tuchscheerer, F., Mandel, M., Müller, S., Liebsch, S. (2012). “Corrosion behaviour of aluminium alloys in ethanol fuels”, Journal of Material Sciences, 47:2798-2806. DOI 10.1007/s10853-011-6108-1.
  • Kumar, S., Singh, R., Maurya, S. N., Vikram, J. (2023). “Monitoring of Corrosion in the Pipeline of a Distribution Network Using Weight Loss Method and Image Processing Technique”, Journal of Materials Engineering and Performance, Vol. 32, No.19, 8731-8737.
  • Mansfeld, F. & Kenkel, J. V. (1975). “Galvanic Corrosion of Al Alloys-III. The Effect of Area Ratio”, Corrosion Science, Vol. 15, 239-250.
  • Nesane, T., Madala, N. E., Kabanda, M. M., Murulana, L. C. (2023). “Experimental and theoretical studies on the inhibitory potential of Lippia javanica leaf extract for aluminium corrosion in 1M HCl medium”, Journal of Adhesion Science and Technology, Vol. 37, No. 24, 3517-3551. https://doi.org/10.1080/01694243.2023.2211788.
  • Pesha, T., Mulaudzi, V. L., Cele, M. L., Mothapo, M. P., Ratshisindi, F. (2023). “Evaluation of corrosion inhibition effect of glycerol stearate on aluminium metal by electrochemical techniques”, Arabian Journal of Chemistry, 16, 104798. https://doi.org/10.1016/j.arabjc.2023.104798.
  • Rajzer, I., Menaszek, E., Kwiatkowski, R., Planell, J. A., Castano, O. (2014). “Electrospun gelatin/caprolactone fibrous scaffold modified with calcium phosphate for bone tissue engineering”, Materials Science and Engineering C, Vol. 44, 183-190. http://dx.doi.org/10.1016/j.msec.2014.08.017.
  • Rodic, P., Milosev, I., Lekka, M., Andreatta F., Fedrizzi, L. (2018). “Corrosion behaviour and chemical stability of transparent hybrid sol-gel coatings deposited on aluminium in acidic and alkaline solutions”, Progress in Organic Coatings 124, 286-295. https://doi.org/10.1016/j.porgcoat.2018.02.025
  • Ruhi, G., Modi, O. P., Singh, I. B., Jha, A.K., Yegneswaran, A.H. (2006). “Wear and electrochemical characterization of sol-gel alumina coating on chemically pre-treated mild steel substrate”, Surfaces And Coatings Technologies. 201:1866-1872. https: //doi:10.1016/j.surfcoat.2006.03.013.
  • Sabarirajan, N., Sait, A. N., Thanikodi, S., Giri, J. (2025). “A novel technique to examine the corrosion resistance of FSW dissimilar aluminium alloys under three diferent corrosion solutions”, The International Journal of Advanced Manufacturing Technology, Vol. 136:133-144.
  • Sun, Y. (2023) “The use of aluminium alloys in structures: Review and outlook”, Structures 57, 105290,. https://doi.org/10.1016/j.istruc.2023.105290
  • Tran, D. T., Chen, F. H., Wu, G. L., Ching, P. C. O., Yeh, M. L. (2023). “Influence of Spin Coating and Dip Coating with Gelatin/Hydroxyapatite for Bioresorbable Mg Alloy Orthopedic Implants: In Vitro and In Vivo Studies”, ACS Biomater. Sci. Eng, 9,2, 705-718. https://doi.org/10.1021/acsbiomaterials.2c01122.
  • Usman, A. D., Victoria, A. F., Okoro, L. N. (2015a). “Weight Loss Corrosion Study of Some Metals in Acid Medium”, Journal of Advances in Chemistry , Vol. 11, No.2, 3434-3440.
  • Usman, A. D., Okoro, L. N. (2015b). “A review: Weight Loss Studies on the Corrosion Behaviour of Some Metals in Various Media”, Chemical Science Reviews and Letters, Vol. 4, No.13, 17-24.
  • Vega, A. S., Berriozabal, G., Urbegain, A., Minudri, D., Somers, A., Forsyth, M., Caracena, R., Marinova, N. (2024). "Exploring Sustainable Coating Solutions for Applications in Highly Corrosive Environments", Coatings, 14, 521:1-23. doi.org/10.3390/coatings14050521.
  • Vinodhini, S. P. & Xavier, J. R. (2023). “Effects of carbon nanotubes-based composites on the corrosion protection and mechanical properties of polymer coatings in chloride environments ”, Materials Science and Engineeering B 295, 116621. https://doi.org/10.1016/j.mseb.2023.116621.
  • Xu, Z., Feng, X., Huang, J., Wu, S., Zhou, P., Li, H. (2022). “Suspension Flame Spray Construction of Porous” PCL/Hydroxyapatite Coatings for Marine Ecological Remediation”, J Therm Spray Tech, 31:1490-1498. https://doi.org/10.1007/s11666-022-01384-2.
  • Yanardag T., Bayraktar N., Yanardag Y. K., Ozgen Y., Aksut A. A. (2020). “The Inhibitor Effects Of Cannabis Sativa L. Extracts On The Corrosion Of Aluminium In H2so4 Solutıons”
  • Zehra, S., Mobin, M., Aslam, R. (2022). “Corrosion prevention and protection methods”, Eco-Friendly Corrosion Inhibitors, Chapter-2, Edited by : L. Guo, C. Verma, D. Zhang. Elsevier.
There are 28 citations in total.

Details

Primary Language English
Subjects Electrochemical Technologies, Materials Engineering (Other)
Journal Section Full-length articles
Authors

Fatma Kandemirli 0000-0001-6097-2184

Ersin Kamberli 0000-0001-9047-4274

Bahar Nazli 0000-0001-8841-8636

Publication Date September 15, 2025
Submission Date September 20, 2024
Acceptance Date July 28, 2025
Published in Issue Year 2025 Volume: 8 Issue: 2

Cite

APA Kandemirli, F., Kamberli, E., & Nazli, B. (2025). Evaluation of Corrosion Inhibition Performance and Surface Characterization of PCL-Coated Aluminum Alloys. Journal of the Turkish Chemical Society Section B: Chemical Engineering, 8(2), 203-212. https://doi.org/10.58692/jotcsb.1553333

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J. Turk. Chem. Soc., Sect. B: Chem. Eng. (JOTCSB)