Kimyasal Çöktürme Yöntemiyle Persülfat Aktivasyonu için Aktif Karbon Destekli Demir ve Kobalt Bazlı Katalizör Sentezi ve Eritromisin Degradasyonu için Uygulaması

Hatice Erdem; Mehmet Erdem

doi:10.31466/kfbd.1336484

TR EN

Kimyasal Çöktürme Yöntemiyle Persülfat Aktivasyonu için Aktif Karbon Destekli Demir ve Kobalt Bazlı Katalizör Sentezi ve Eritromisin Degradasyonu için Uygulaması

Abstract

Kalıcı organik kirleticilerin sucul ortamlardan ileri oksidasyon yöntemleriyle giderimi için etkili, ekonomik ve çevre dostu heterojen katalizörlerin geliştirilmesi son zamanlarda oldukça önem kazanmıştır. Bu çalışmada, aktif karbon (AC) destekli demir (CP-Fe) ve kobalt (CP-Co) bazlı katalizörler kimyasal çöktürme yöntemiyle hazırlanmıştır. Hazırlanan katalizörler FTIR, FESEM, EDX-haritalama, XRD, pHpzc, Boehm titrasyonu ve BET yüzey alanı teknikleri kullanılarak karakterize edilmiştir. AC destekli CP-Fe ve CP-Co katalizörlerin spesifik yüzey alanlarının sırasıyla 396.42 ve 441.76 m2/g olduğu ve her iki katalizörün de mezo gözenekli bir yapıya sahip olduğu belirlenmiştir. Demir ve kobaltın AC yüzeyine homojen bir şekilde yayılmış olduğu, demirin manyetit (Fe3O4) ve kobaltın ise amorf yapıda olduğu tespit edilmiştir. Katalizörlerin katalitik aktiviteleri, persülfat aktivasyonu ile eritromisin (ERY) degradasyonunda test edilmiştir. CP-Fe katalizör varlığında ERY 60 dk’da %96 oranında degrede olurken, CP-Co katalizör varlığında 30 dk içinde tamamen degrede olmuştur. Her iki katalizörün de adsorpsiyon ve degradasyonun birlikte sinerjik etkisiyle ERY’yi parçalamada ve gidermede yüksek katalitik aktivite gösterdiği belirlenmiştir.

Keywords

Aktif karbon, Destek materyali, Katalizör sentezi, İleri oksidasyon, Bozunma, Kalıcı organik kirletici

Synthesis of Activated Carbon-Supported Iron and Cobalt Based Catalysts by Chemical Precipitation Route for Persulfate Activation and Its Application for Erythromycin Degradation

Abstract

The development of efficient, economical and environmentally friendly heterogeneous catalysts for the removal of persistent organic pollutants from aquatic environments has recently become important. In this study, the activated carbon (AC) supported iron (CP-Fe) and cobalt (CP-Co) based catalysts were successfully prepared by the chemical precipitation method. The prepared catalysts were characterized using FTIR, FESEM, EDX-mapping, XRD, pHpzc, Boehm titration and BET surface area. It was determined that the specific surface areas of CP-Fe and CP-Co catalysts were 396.42 and 441.76 m2/g, respectively, and both catalysts had a mesoporous structure. SEM-EDX and XRD analysis showed that the iron and cobalt were uniformly dispersed on the AC support surface and iron in the structure was in the form of magnetite (Fe3O4) and the cobalt was in the amorphous form. The catalytic activities of the catalysts were evaluated for degradation of erythromycin (ERY) by persulfate activation. While 96% of ERY was decomposed for 60 min in the presence of CP-Fe catalyst, it was completely decomposed within 30 min in the presence of CP-Co catalyst. It was determined that both catalysts showed high catalytic activity for ERY removal with the synergistic effect of adsorption and degradation.

Keywords

Activated carbon, Supporting material, Catalyst synthesis, Advanced oxidation, Degradation, Persistent organic pollutant

Supporting Institution

TÜBİTAK

Project Number

117Y300

Thanks

Bu çalışma 117Y300 numaralı proje ile Türkiye Bilimsel ve Teknolojik Araştırma Kurumu (TÜBİTAK) tarafından desteklenmiştir. Katkılarından dolayı TÜBİTAK'a teşekkür ederiz.

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Details

Primary Language

Turkish

Subjects

Chemical Engineering (Other)

Journal Section

Research Article

Authors

Hatice Erdem
0000-0002-7666-8301
Türkiye

Mehmet Erdem ^*
0000-0002-3544-7203
Türkiye

Early Pub Date

December 18, 2023

Publication Date

December 15, 2023

Submission Date

August 2, 2023

Acceptance Date

November 24, 2023

Published in Issue

Year 2023 Volume: 13 Number: 4

DOI

https://doi.org/10.31466/kfbd.1336484

IZ

https://izlik.org/JA97HP58ZF

APA

Erdem, H., & Erdem, M. (2023). Kimyasal Çöktürme Yöntemiyle Persülfat Aktivasyonu için Aktif Karbon Destekli Demir ve Kobalt Bazlı Katalizör Sentezi ve Eritromisin Degradasyonu için Uygulaması. Karadeniz Fen Bilimleri Dergisi, 13(4), 1780-1797. https://doi.org/10.31466/kfbd.1336484

AMA

1.Erdem H, Erdem M. Kimyasal Çöktürme Yöntemiyle Persülfat Aktivasyonu için Aktif Karbon Destekli Demir ve Kobalt Bazlı Katalizör Sentezi ve Eritromisin Degradasyonu için Uygulaması. KFBD. 2023;13(4):1780-1797. doi:10.31466/kfbd.1336484

Chicago

Erdem, Hatice, and Mehmet Erdem. 2023. “Kimyasal Çöktürme Yöntemiyle Persülfat Aktivasyonu Için Aktif Karbon Destekli Demir Ve Kobalt Bazlı Katalizör Sentezi Ve Eritromisin Degradasyonu Için Uygulaması”. Karadeniz Fen Bilimleri Dergisi 13 (4): 1780-97. https://doi.org/10.31466/kfbd.1336484.

EndNote

Erdem H, Erdem M (December 1, 2023) Kimyasal Çöktürme Yöntemiyle Persülfat Aktivasyonu için Aktif Karbon Destekli Demir ve Kobalt Bazlı Katalizör Sentezi ve Eritromisin Degradasyonu için Uygulaması. Karadeniz Fen Bilimleri Dergisi 13 4 1780–1797.

IEEE

[1]H. Erdem and M. Erdem, “Kimyasal Çöktürme Yöntemiyle Persülfat Aktivasyonu için Aktif Karbon Destekli Demir ve Kobalt Bazlı Katalizör Sentezi ve Eritromisin Degradasyonu için Uygulaması”, KFBD, vol. 13, no. 4, pp. 1780–1797, Dec. 2023, doi: 10.31466/kfbd.1336484.

ISNAD

Erdem, Hatice - Erdem, Mehmet. “Kimyasal Çöktürme Yöntemiyle Persülfat Aktivasyonu Için Aktif Karbon Destekli Demir Ve Kobalt Bazlı Katalizör Sentezi Ve Eritromisin Degradasyonu Için Uygulaması”. Karadeniz Fen Bilimleri Dergisi 13/4 (December 1, 2023): 1780-1797. https://doi.org/10.31466/kfbd.1336484.

JAMA

1.Erdem H, Erdem M. Kimyasal Çöktürme Yöntemiyle Persülfat Aktivasyonu için Aktif Karbon Destekli Demir ve Kobalt Bazlı Katalizör Sentezi ve Eritromisin Degradasyonu için Uygulaması. KFBD. 2023;13:1780–1797.

MLA

Erdem, Hatice, and Mehmet Erdem. “Kimyasal Çöktürme Yöntemiyle Persülfat Aktivasyonu Için Aktif Karbon Destekli Demir Ve Kobalt Bazlı Katalizör Sentezi Ve Eritromisin Degradasyonu Için Uygulaması”. Karadeniz Fen Bilimleri Dergisi, vol. 13, no. 4, Dec. 2023, pp. 1780-97, doi:10.31466/kfbd.1336484.

Vancouver

1.Hatice Erdem, Mehmet Erdem. Kimyasal Çöktürme Yöntemiyle Persülfat Aktivasyonu için Aktif Karbon Destekli Demir ve Kobalt Bazlı Katalizör Sentezi ve Eritromisin Degradasyonu için Uygulaması. KFBD. 2023 Dec. 1;13(4):1780-97. doi:10.31466/kfbd.1336484

The published articles in The Black Sea Journal of Sciences are licensed under Creative Commons Attribution-NonCommercial 4.0 International

Kimyasal Çöktürme Yöntemiyle Persülfat Aktivasyonu için Aktif Karbon Destekli Demir ve Kobalt Bazlı Katalizör Sentezi ve Eritromisin Degradasyonu için Uygulaması

Abstract

Keywords

Synthesis of Activated Carbon-Supported Iron and Cobalt Based Catalysts by Chemical Precipitation Route for Persulfate Activation and Its Application for Erythromycin Degradation

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