Doğal Adsorbent Kullanarak Sulardan Maxilon Golden Yellow’un Renk Gideriminde Ortam Koşullarının İncelenmesi
Year 2021,
Volume: 11 Issue: 1, 144 - 160, 15.06.2021
Ezgi Güneş Gürdal
,
Erkan Kalıpcı
Abstract
Bu çalışmada; Maxilon Golden Yellow GL EC 400% (MGY-GE) boyasının Nevsehir (Türkiye) Cin Deresi dere yatağına ait doğal kil (DK) ile sulu çözeltilerden gideriminde ortam koşulları araştırılmıştır. Adsorpsiyon koşulları; MGY-GE boyasının 100 mg/L konsantrasyonunda, 2.0 g adsorbent kullanılarak, farklı temas süresi, çözelti pH’ı ve sıcaklığında incelenmiştir. Adsorpsiyon sürecinin Langmuir ve Freundlich izotermlerine uygunlukları araştırılmıştır. MGY-GE boyası gideriminde kullanılan DK için deneysel verilerin Langmuir izoterm modeline uyum gösterdiği bulunmuştur. Doğal kil için en yüksek renk giderimi; pH 8’de (%98.44) 300 dakika ve 25 oC'de elde edilmiştir. Sonuç olarak; doğal kilin MGY-GE boyasının sulu çözeltiden gideriminde kulanılabileceği ve bu doğal kilin yüksek tutma kapasitesine sahip olduğu belirlenmiştir. Düşük maliyetli ve bol miktarda bulunan doğal kil, MGY-GE boyasının giderimi için diğer adsorbentlere tercihen kullanılabilir.
References
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- Kalıpcı, E. (2019). Adsorption of Cadmium (II) By Using Clays Modified With Ultrasound. International Journal of Global Warming.18(2):155-172.
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- Kuleyin, A., Aydin, F. (2011). Removal of Reactive Textile Dyes (Remazol Brillant Blue R And Remazol Yellow) by Surfactant‐Modified Natural Zeolite. Environmental Progress & Sustainable Energy. 30(2):141-151.
- Li, P., Gao, B., Li, A.,Yang, H. (2020). Evaluation of The Selective Adsorption of Silica-Sand/Anionized-Starch Composite For Removal of Dyes and Cupper (II) From Their Aqueous Mixtures. International journal of Biological Macromolecules. 149: 1285-1293.
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- Uysal, Y., Kereci, F.N. (2016).Tekstil Atık Külü İle Tekstil Atıksuyundan Renk Giderimi. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 19(3):82-86.
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Examination of Ambient Conditions of Maxilon Golden Yellow for Color Removal From Waters by Using Natural Adsorbent
Year 2021,
Volume: 11 Issue: 1, 144 - 160, 15.06.2021
Ezgi Güneş Gürdal
,
Erkan Kalıpcı
Abstract
In this study, ambient conditions for removal of Maxilon Golden Yellow GL EC 400% (MGY-GE) dye from aqueous solutions by using natural clay (NC) of Nevsehir (Turkey) Cin stream bed were investigated.Adsorption conditions were examined at 100 mg/L concentration of MGY-GE dye using 2.0 g adsorbent, different contact time, solution pH and temperature.The fitting of adsorption process with respect to Langmuir and Freundlich isotherms was examined. Experimental data for NC used in MGY-GE dye removal has been found to adapt to the Langmuir isotherm model.The highest color removal was obtained during 300 minutes and 25 oC at pH 8 (98.44%) for natural clay. As a result; it was indicated that natural clay can be used for the removal from aqueous solution of MGY-GE dye has high adsorption capacity for dye. Abundantly in nature and low-cost clay can be used for the removal of MGY-GE dye in preference to other adsorbents.
References
- Adeyemo, A.A., Adeoye, I.O., Bello, O.S. (2017). Adsorption of Dyes Using Different Types of Clay: A Review. Applied Water Science.7:543-568.
- Doğan, M., Karaoğlu, M. H., Alkan, M. (2009). Adsorption Kinetics of Maxilon Yellow 4GL and Maxilon Red GRL Dyes on Kaolinite. J. Hazard. Mater., 165(1-3):1142-51.
- Dogan, M., Alkan, M. (2010).Adsorption Kinetics of Methyl Violet Onto Perlite. Chemosphere, 50:517-528.
- Elmoubarki, R., Mahjoubi, F.Z., Tounsadi, H., Moustadraf, J., Abdennouri, M., Zouhri, A., Albani, A. El, Barka, N. (2015). Adsorption Of Textile Dyes On Raw And Decanted Moroccan Clays: Kinetics, Equilibrium And Thermodynamics. Water Resources and Industry.9:16–29.
- Freundlich, H.M.F. (1906). Over the adsorption in solution, J. Phys. Chem.57:385-471.
- Fytıanos, K., Voudrıas, E., Kokkalıs, E. (2000). Sorption-Desorption Behaviour of 2,4-Dichlorophenol by Marine Sediments. Chemosphere.40(1): 3-6.
- Gürses, A., Yalcın, M., Dogar, C. (2002). Electrocoagulation of Some Reactive Dyes: A Statistical Investigation Of Some Electrochemical Variables. Waste Management. 22:491-499.
- Gupta, V.K., Suhas, T.L. (2009). Application of Lowcost Adsorbents For Dye Removal-A Review. Journal of Environmental Management. 90:2313-2342.
- Gok, O., Ozcan, A.S., Ozcan, A.(2010).Adsorption Behavior of A Textile Dye of Reactive Blue 19 From Aqueous Solutions Onto Modified Bentonite. Appl. Surf. Sci. 256:5439–5443.
- Juang, R.S.,Wu, F.C., Tseng, R.L. (1997). The Ability of Activated Clay For The Adsorption of Dyes From Aqueous Solutions. Environmental Technology.18:525-531.
- Kadhom, M., Albayati, N., Alalwan, H., & Al-Furaiji, M. (2020). Removal of Dyes By Agricultural Waste. Sustainable Chemistry and Pharmacy, 16: 100259.
- Kayacan, S.(2007). Removal of Dye Materials From Aqueous Solutions by Adsorption on Coals and Cokes, Yüksek Lisans Tezi, Ankara Üniversitesi, Fen Bilimleri Enstitüsü, Ankara.
- Kalıpcı, E., Sahinkaya, S., Dortkol, M., Aras, S. (2016). Decolorization of Basic Textile Dyes Using A Novel Adsorbent Modification Method: Ultrasonic-Acid Modification. International Journal of Environmental Research. 10(1):31-40.
- Kalıpcı, E. (2016). Removal of Methylene Blue From Aqueous Solution by Natural Olive Pomace Modified with Ultrasounds and Acid. Environment Protection Engineering. 42(3):5-17.
- Kalıpcı, E. (2019). Adsorption of Cadmium (II) By Using Clays Modified With Ultrasound. International Journal of Global Warming.18(2):155-172.
- Kaykıoğlu, G., Güneş, E. (2014). Pirinç Kabuğu Kullanılarak Üretilen Manyetik Nanopartiküller İle Sulu Çözeltilerden Renk Giderimi, NKUBAP.00.17.AR.12.07 Nolu BAP Projesi, Namık Kemal Üniversitesi, 1-55.
- Kuleyin, A., Aydin, F. (2011). Removal of Reactive Textile Dyes (Remazol Brillant Blue R And Remazol Yellow) by Surfactant‐Modified Natural Zeolite. Environmental Progress & Sustainable Energy. 30(2):141-151.
- Li, P., Gao, B., Li, A.,Yang, H. (2020). Evaluation of The Selective Adsorption of Silica-Sand/Anionized-Starch Composite For Removal of Dyes and Cupper (II) From Their Aqueous Mixtures. International journal of Biological Macromolecules. 149: 1285-1293.
- Mingfei, Z., Peng, L.(2009).Adsorption of Methylene Blue From Aqueous Solutions by Modified Expanded Graphite Powder. Desalination, 249 (1):331-336, 2009.
- Ngulube, T., Gumbo, J.R., Masindi, V., Maity, A. (2017). An Update On Synthetic Dyes Adsorption Onto Clay Based Minerals: A State-Of-Art Review. Journal of Environmental Management. 191:35-57.
- Ouardi, M. El, Qourzal, S., Alahiane, S., Assabbane, A., Douch, J., (2015). Effective Removal of Nitrates Ions from Aqueous Solution Using New Clay as Potential Low-Cost Adsorbent. Journal of Encapsulation and Adsorption Sciences.5(4):178-190.
- Öden, M., Küçükçongar, S. (2017). Removal of Dyes from Wastewater by Adsorption Using Modified Boron Enrichment Waste: Thermodynamic Criteria. Eurasian Journal of Environmental Research. 1(1):12-18.
- Sun, Q., Yang, L. (2003).The Adsorption of Basic Dyes From Aqueous Solution on Modified Peat-Resin Particle. Water Research. 37:1535-1544.
- Tara, N., Siddiqui, S. I., Rathi, G., Chaudhry, S. A., Asiri, A. M. (2020). Nano-Engineered Adsorbent For The Removal of Dyes From Water: A Review. Current Analytical Chemistry. 16(1):14-40.
- Uyar, G. (2012). A Low-Cost Adsorbent For Dye Removal:Methylene Blue Removal By Alginate-Montmorillonite Hybride Beads. Yüksek Lisans Tezi, İstanbul Teknik Üniversitesi, Fen Bilimleri Enstitüsü.
- Uysal, Y., Kereci, F.N. (2016).Tekstil Atık Külü İle Tekstil Atıksuyundan Renk Giderimi. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 19(3):82-86.
- URL-1:https://pubchem.ncbi.nlm.nih.gov/compound/Basic-Yellow-28, (Erişim Tarihi: 09 Mart 2021).
- URL-2:http://www.rsc.org/suppdata/c5/ra/c5ra13004b/c5ra13004b1.pdf,2015.,(Erişim Tarihi:12 Mart 2018).
- Weber, W., Dıgıano, F. (1996). Process Dynamics in Environmental Systems. Wiley, 1st Ed.:New York, USA.
- Wu, J., Yang, J., Feng, P., Huang, G., Xu, C., Lin, B. (2020). High-Efficiency Removal Of Dyes From Wastewater By Fully Recycling Litchi Peel Biochar. Chemosphere, 246:125734.
- Xia, L., Zhou, S., Zhang, C., Fu, Z., Wang, A., Zhang, Q., ... & Xu, W. (2020). Environment-Friendly Juncus Effusus-Based Adsorbent With A Three-Dimensional Network Structure For Highly Efficient Removal of Dyes From Wastewater. Journal of Cleaner Production, 259, 120812.