Parçikan Bitümlü Şeylinin Termal Analiz Kinetiği ve Reaksiyon Mekanizması

Year 2023, Volume: 13 Issue: 4, 1648 - 1660, 15.12.2023

Yeliz Toptaş , Aydan Aksoğan Korkmaz

https://doi.org/10.31466/kfbd.1329907

Cited By: 1

Abstract

Bu çalışma, termogravimetrik analiz kullanılarak Arguvan-Parçikan bitümlü şeylindeki organik maddenin yanma kinetiğini araştırmayı amaçlamıştır. Bu amaçla bitümlü şeyle ait kinetik parametreler Arrhenius, Coats-Redfern, Ingraham-Marrier, Horowitz-Metzger olmak üzere 4 farklı kinetik model kullanılarak TGA verilerinden belirlenmiştir. Farklı modeller kullanılarak elde edilen bu kinetik parametreler birbirleriyle karşılaştırmalı olarak sunulmuştur. Elde edilen sonuçlara göre en yüksek aktivasyon enerjisi değerleri 277,27 - 1984,53 kj/mol olarak Arrhenius modeli ile hesaplanmıştır.

Keywords

Bitümlü şeyl, Termal analiz, Kinetik, Aktivasyon enerjisi

Thermal Analysis Kinetics and Reaction Mechanism of Parçikan Bituminous Shale

Abstract

This study aimed to investigate the combustion kinetics of organic material in the thermogravimetric analysis Arguvan-Parçikan bituminous shale. Arrhenius, Coats-Redfern, Ingraham-Marrier, Horowitz-Metzger are 4 different kinetic models from TGA data. These kinetic parameters obtained using different models are presented in comparison with each other. The highest activation values were calculated with the Arrhenius model as 277.27 - 1984.53 kj/mol.

Keywords

Bituminous shale, Thermal analysis, Kinetic, Activation energy

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