Everzol Yellow 3RS Boyar Maddesinin Gidya Üzerine Adsorpsiyonu: Kinetik ve İzoterm Çalışmaları

Year 2024, Volume: 14 Issue: 1, 194 - 210, 15.03.2024

Fulya Aydın Temel

https://doi.org/10.31466/kfbd.1374988

Abstract

Bu çalışmada, Gidya kullanılarak Everzol Yellow 3RS boyar maddesinin adsorpsiyon prosesi ile giderimi araştırılmıştır. Adsorpsiyon sürecine pH’ın (3–11), temas süresinin (5–300 dakika), adsorban dozunun (2–16 g/L), başlangıç konsantrasyonunun (10-50 mg/L) ve sıcaklığın (25-60°C) etkisi incelenmiştir. Adsorpsiyon prosesinde 10 g/L adsorbent dozu, orijinal pH değeri, 90 dakika temas süresi, 10 mg/L boyar madde konsantrasyonu ve ortam sıcaklığı optimum maksimum giderim veriminin (%90.96) sağlandığı koşullar olarak belirlenmiştir. Gidya üzerindeki adsorpsiyon sürecinin mekanizmasını anlamak için kinetik ve denge modelleri uygulanmıştır. Kinetik ve izoterm deneylerinden elde edilen sonuçlara göre, Everzol Yellow 3RS boyar maddesinin Gidya üzerine adsorpsiyonu için adsorpsiyon kinetiği ikinci derece reaksiyon modeli modeli ile adsorpsiyon dengesi ise Freundlich izoterm modeli ile iyi bir şekilde tanımlanmıştır. Bu, hız sınırlayıcı adımın difüzyondan ziyade kemisorpsiyon olabileceği ve hem film difüzyonu hem de parçacık içi difüzyon süreçlerinin kayda değer olduğu anlamına gelmektedir. Ayrıca, adsorpsiyon mekanizmasının düzgün bir dağılım göstermediğini ve tek bir katmanla sınırlı olmadığını göstermiştir. Sonuç olarak, Gidya’nın potansiyel bir adsorbent olarak boyar madde gideriminde kullanılabilir olduğu görülmüştür.

Keywords

Everzol Yellow 3RS, Gidya, Adsorpsiyon, Kinetik, İzoterm, Arıtım.

Ethical Statement

Yapılan çalışmada araştırma ve yayın etiğine uyulmuştur.

Supporting Institution

Giresun Üniversitesi - Bilimsel Araştırma Projeleri Koordinasyon Birimi

Project Number

FEN-BAP-A-250620-63

Thanks

Bu çalışma, Giresun Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi (Proje FEN-BAP-A-250620-63) tarafından finanse edilmiştir. Araştırma olanağını sağladığı için Giresun Üniversitesi’ne teşekkür ediyorum.

Adsorption of Everzol Yellow 3RS dyestuff onto Gyttja: Kinetic and Isotherm Studies

Abstract

In this study, the removal of Everzol Yellow 3RS dye by adsorption process was investigated by using Gyttja. The effects of pH (3–11), contact time (5–300 min), adsorbent dose (2–16 g/L), initial concentration (10–50 mg/L), and temperature (25–60°C) on the adsorption process were investigated. In the adsorption process, 10 g/L adsorbent dose, original pH value, 90 minutes contact time, 10 mg/L dye concentration, and ambient temperature were determined as the conditions where the maximum removal efficiency (90.96%) was achieved. To understand the mechanism of the adsorption process on Gyttja, kinetic and equilibrium models were applied. According to the results obtained from the kinetic and isotherm experiments, the adsorption kinetics for the adsorption of Everzol Yellow 3RS dye onto Gyttja were well described by the pseudo-second-order reaction model and the adsorption equilibrium by the Freundlich isotherm model. This means that the rate-limiting step may be chemisorption rather than diffusion, and both film diffusion and intra-particle diffusion processes are significant. It also showed that the adsorption mechanism is not uniformly distributed and is not limited to a single layer. As a result, it was observed that Gyttja can be used as a potential adsorbent in dyestuff removal.

Keywords

Everzol Yellow 3RS, Gyttja, Adsorption, Kinetic, Isotherm, Treatment

Project Number

FEN-BAP-A-250620-63

References

• Abbou, B., Lebkiri, I., Ouaddari, H., El Amri, A., Achibat, F.E., Kadiri, L., Ouass, A., Lebkiri, A., Rifi, E.H., (2023). Improved removal of methyl orange dye by adsorption using modified clay: Combined experimental study using surface response methodology. Inorg. Chem. Commun. 155, 111127. https://doi.org/10.1016/j.inoche.2023.111127
• Acemioglu, B., (2004). Adsorption of Congo red from aqueous solution onto calcium-rich fly ash. J. Colloid Interface Sci., 274, 371-379.
• Akbal, F., Kuleyin, A., (2011). Decolorization of levafix brilliant blue E-B by electrocoagulation method. Environ. Prog. Sustain. Energy, 30, 29–36. https://doi.org/10.1002/ep.10437
• Ameri, Atefeh, Faramarzi, M.A., Tarighi, S., Shakibaie, M., Ameri, Alieh, Ramezani-Sarbandi, A., Forootanfar, H., (2023). Removal of dyes by Trametes versicolor laccase immobilized on NaY-zeolite. Chem. Eng. Res. Des. 197, 240–253. https://doi.org/10.1016/j.cherd.2023.07.014
• Armağan, B., Turan, M., Çelik, M.S., (2004). Equilibrium studies on the adsorption of reactive azo dyes into zeolite. Desalination, 170, 33-39.
• Aydın Temel, F., (2018). Endüstriyel Sızıntı Suyundan Pb(II) Giderimi İçin Genleştirilmiş Perlit Kullanımı: Kinetik Çalışmalar. Türk Tarım – Gıda Bilim ve Teknol. Derg.. 6, 360–364.
• Aydın Temel, F., (2017). Kinetics and thermodynamics of the Ni(II) ions sorption from industrial wastewater by gyttja. Int. J. Exergy, 23, 279–297. https://doi.org/10.1504/IJEX.2017.086168
• Aydın Temel, F., Avci, E., Turan, N.G., (2022). Investigation of Copper(Ii), Zinc(Ii) and Lead(Ii) Removal Onto Expanded Perlite By Adsorption From the Wastes of Metal Casting Industry: Statistical Modeling and Optimization. Environ. Eng. Manag. J. 21, 757–767. https://doi.org/10.30638/eemj.2022.070
• Aydın Temel, F., Avcı, E., Turan, N.G., (2018a). Full factorial experimental design of Ni(II) removal from industrial wastewater by adsorption. Int. J. Glob. Warm. 16, 299–319. https://doi.org/10.1504/IJGW.2018.095388
• Aydın Temel, F., Kuleyin, A., (2016). Ammonium removal from landfill leachate using natural zeolite: kinetic, equilibrium, and thermodynamic studies. Desalin. Water Treat. 57, 23873–23892. https://doi.org/10.1080/19443994.2015.1136964
• Aydın Temel, F., Turan, N.G., Ozgonenel, O., Ardali, Y., (2018b). The use of response surface methodology for modelling of lead (II) removal from industrial waste by pumice and vermiculite. Int. J. Glob. Warm. 15, 175–189. https://doi.org/10.1504/IJGW.2018.092895
• Aydın Temel, F., Turan, N.G., Ozgonenel, O., Ardalı, Y., (2018c). Heavy metal removal with pure and biochar rice husks: Modelling and optimisation using Box-Behnken design. Int. J. Glob. Warm. 16, 1–17. https://doi.org/10.1504/IJGW.2018.094307
• Balcik-Canbolat, C., Olmez-Hanci, T., Sengezer, C., Sakar, H., Karagunduz, A., Keskinler, B., (2019). A combined treatment approach for dye and sulfate rich textile nanofiltration membrane concentrate. J. Water Process Eng. 32, 100919. https://doi.org/10.1016/j.jwpe.2019.100919
• Barredo-Damas, S., Iborra-Clar, M.I., Bes-Pia, A., Alcaina-Miranda, M.I., Mendoza-Roca, J.A., Iborra-Clar, A., (2005). Study of preozonation influence on the physical-chemical treatment of textile wastewater. Desalination, 182, 267–274. https://doi.org/10.1016/j.desal.2005.04.017
• Bharath Balji, G., Surya, A., Govindaraj, P., Monisha Ponsakthi, G., (2022). Utilization of fly ash for the effective removal of hazardous dyes from textile effluent. Inorg. Chem. Commun. 143, 109708. https://doi.org/10.1016/j.inoche.2022.109708
• Buscio, V., López-Grimau, V., Álvarez, M.D., Gutiérrez-Bouzán, C., (2019). Reducing the environmental impact of textile industry by reusing residual salts and water: ECUVal system. Chem. Eng. J. 373, 161–170. https://doi.org/10.1016/j.cej.2019.04.146
• Capar, G., Yetis, U., Yilmaz, L., (2006). Membrane based strategies for the pre-treatment of acid dye bath wastewaters. J. Hazard. Mater. 135, 423–430. https://doi.org/10.1016/j.jhazmat.2005.12.008
• Chen, Y., Zhang, D., (2014). Adsorption kinetics, isotherm and thermodynamics studies of flavones from Vaccinium Bracteatum Thunb leaves on NKA-2 resin. Chem. Eng. J. 254, 579–585. https://doi.org/10.1016/j.cej.2014.05.120
• Cüce, H., Aydın Temel, F., (2021). Reuse of agro-wastes to treat wastewater containing dyestuff: Sorption process with potato and pumpkin seed wastes. Int. J. Glob. Warm. 24, 14–37. https://doi.org/10.1504/ijgw.2021.115108
• de Oliveira Neto, G.C., Ferreira Correia, J.M., Silva, P.C., de Oliveira Sanches, A.G., Lucato, W.C., (2019). Cleaner Production in the textile industry and its relationship to sustainable development goals. J. Clean. Prod. 228, 1514–1525. https://doi.org/10.1016/j.jclepro.2019.04.334
• Dikici, H., Saltali, K., Bingölbalı, S. (2010). Equilibrium and Kinetics Characteristics of Copper (II) Sorption onto Gyttja. Bull Environ Contam Toxicol 84, 147–151. https://doi.org/10.1007/s00128-009-9899-x
• Elver, O., Aydın Temel, F., Cagcag Yolcu, O., Akbal, F., Kuleyin, A., (2023). Modeling of Cu(II) adsorption on the activated Phragmites australis waste by fuzzy-based and neural network-based inference systems. J. Ind. Eng. Chem. https://doi.org/10.1016/j.jiec.2023.08.031
• GilPavas, E., Dobrosz-Gómez, I., Gómez-García, M.Á., (2012). Decolorization and mineralization of Diarylide Yellow 12 (PY12) by photo-Fenton process: The Response Surface Methodology as the optimization tool. Water Sci. Technol. 65, 1795–1800. https://doi.org/10.2166/wst.2012.078
• Ihaddaden, S., Aberkane, D., Boukerroui, A., Robert, D., (2022). Removal of methylene blue (basic dye) by coagulation-flocculation with biomaterials (bentonite and Opuntia ficus indica). J. Water Process Eng. 49, 102952. https://doi.org/10.1016/j.jwpe.2022.102952
• Khandegar, V., Saroha, A.K., (2013). Electrocoagulation for the treatment of textile industry effluent - A review. J. Environ. Manage. 128, 949–963. https://doi.org/10.1016/j.jenvman.2013.06.043
• Kim, T.H., Park, C., Kim, S., (2005). Water recycling from desalination and purification process of reactive dye manufacturing industry by combined membrane filtration. J. Clean. Prod. 13, 779–786. https://doi.org/10.1016/j.jclepro.2004.02.044
• Kuleyin, A., Aydın, F., (2011). Removal of Reactive Textile Dyes (Remazol Brillant Blue R and Remazol Yellow) by Surfactant-Modified Natural Zeolite. Environ. Prog. Sustain. Energy, 30, 141–151. https://doi.org/10.1002/ep
• Kuleyin, A., Gök, A., Akbal, F., (2021). Treatment of textile industry wastewater by electro-Fenton process using graphite electrodes in batch and continuous mode. J. Environ. Chem. Eng. 9. https://doi.org/10.1016/j.jece.2020.104782
• Liu, Y., Tan, Y., Cheng, Z., Liu, S., Ren, Y., Chen, X., Fan, M., Shen, Z., (2022). Quantitative structure-activity relationship (QSAR) guides the development of dye removal by coagulation. J. Hazard. Mater. 438, 129448. https://doi.org/10.1016/j.jhazmat.2022.129448
• Mallakpour, S., Sirous, F., Dinari, M., (2023). Comparative study for removal of cationic and anionic dyes using alginate-based hydrogels filled with citric acid-sawdust/UiO-66-NH2 hybrid. Int. J. Biol. Macromol. 238, 124034. https://doi.org/10.1016/j.ijbiomac.2023.124034
• Olgun, A., Atar, N., (2012). Equilibrium, thermodynamic and kinetic studies for the adsorption of lead (II) and nickel (II) onto clay mixture containing boron impurity. J. Ind. Eng. Chem. 18, 1751–1757. https://doi.org/10.1016/j.jiec.2012.03.020
• Ozdemir, O., Armagan, B., Turan, M., Çelik, M. S. (2004). Comparison of the adsorption characteristics of azo-reactive dyes on mezoporous minerals. Dyes and Pigments, 62(1), 49–60. doi:10.1016/j.dyepig.2003.11.007
• Öden, M.K., Şahinkaya, S., Küçükçongar, S. (2017). Pirina kullanılarak adsorpsiyon prosesinde renk giderimi, Cumhuriyet Sci. J., 38-4, 215-219.
• Sala, M., Gutiérrez-Bouzán, M.C., (2014). Electrochemical treatment of industrial wastewater and effluent reuse at laboratory and semi-industrial scale. J. Clean. Prod. 65, 458–464. https://doi.org/10.1016/j.jclepro.2013.08.006
• Salazar, R., Gallardo-Arriaza, J., Vidal, J., Rivera-Vera, C., Toledo-Neira, C., Sandoval, M.A., Cornejo-Ponce, L., Thiam, A., (2019). Treatment of industrial textile wastewater by the solar photoelectro-Fenton process: Influence of solar radiation and applied current. Sol. Energy, 190, 82–91. https://doi.org/10.1016/j.solener.2019.07.072
• Salman, T., Aydın Temel, F., Turan, G., Ardalı, Y., (2014). Removal of lead (II) from aqueous solution by batch adsorption on various inexpensive adsorbents using experimental design. Desalin. Water Treat. 56, 1566–1575. https://doi.org/10.1080/19443994.2014.951073
• Salman, T., Aydın Temel, F., Turan, N.G., Ardali, Y., (2016). Adsorption of lead (II) ions onto diatomite from aqueous solutions: Mechanism, isotherm and kinetic studies. Glob. Nest J. 18, 1–10.
• Saltalı, K., Alhashemi, M. (2022). Gidya,Leonardit ve Kompost’un Çinko Sorpsiyon Özelliklerinin Belirlenmesi, Turkish Journal of Agriculture-Food Science and Technology, 10, 2751-2757. https://doi.org/10.24925/turjaf.v10isp1.2751-2757.5720
• Shen, Y., Han, S., Xu, Q., Wang, Y., Xu, Z., Zhao, B., Zhang, R., (2016). Optimizing degradation of Reactive Yellow 176 by dielectric barrier discharge plasma combined with TiO2 nano-particles prepared using response surface methodology. Journal of the Taiwan Institute of Chemical Engineers, 60, 302–312.
• Soliman, N.K., Moustafa, A.F., Aboud, A.A., Halim, K.S.A., (2019). Effective utilization of Moringa seeds waste as a new green environmental adsorbent for removal of industrial toxic dyes. J. Mater. Res. Technol. 8, 1798–1808. https://doi.org/10.1016/j.jmrt.2018.12.010
• Stavrinou, A., Aggelopoulos, C.A., Tsakiroglou, C.D., (2018). Exploring the adsorption mechanisms of cationic and anionic dyes onto agricultural waste peels of banana, cucumber and potato: Adsorption kinetics and equilibrium isotherms as a tool. J. Environ. Chem. Eng. 6, 6958–6970. https://doi.org/10.1016/j.jece.2018.10.063
• Sumanjit, K., Rani, S., Mahajan, R.K., (2016). Equilibrium, kinetics and thermodynamic parameters for adsorptive removal of dye Basic Blue 9 by ground nut shells and Eichhornia. Arab. J. Chem. 9, S1464–S1477. https://doi.org/10.1016/j.arabjc.2012.03.013
• Tsai, W. T., Chang, Y. M., Lai, C. W., Lo, C. C., (2005). Adsorption of ethyl violet dye in aqueous solution by regenerated spent bleaching earth. J. Colloid Interface Sci. 289, 333-338.
• Vargas, A.M.M., Cazetta, A.L., Kunita, M.H., Silva, T.L., Almeida, V.C., (2011). Adsorption of methylene blue on activated carbon produced from flamboyant pods (Delonix regia): Study of adsorption isotherms and kinetic models. Chem. Eng. J. 168, 722–730. https://doi.org/10.1016/j.cej.2011.01.067
• Yadav, M., Thakore, S., Jadeja, R., (2022). Removal of organic dyes using Fucus vesiculosus seaweed bioadsorbent an ecofriendly approach: Equilibrium, kinetics and thermodynamic studies. Environ. Chem. Ecotoxicol. 4, 67–77. https://doi.org/10.1016/j.enceco.2021.12.003
• Zazou, H., Afanga, H., Akhouairi, S., Ouchtak, H., Addi, A.A., Akbour, R.A., Assabbane, A., Douch, J., Elmchaouri, A., Duplay, J., Jada, A., Hamdani, M., (2019). Treatment of textile industry wastewater by electrocoagulation coupled with electrochemical advanced oxidation process. J. Water Process Eng. 28, 214–221. https://doi.org/10.1016/j.jwpe.2019.02.006
• Zazycki, M.A., Godinho, M., Perondi, D., Foletto, E.L., Collazzo, G.C., Dotto, G.L., (2018). New biochar from pecan nutshells as an alternative adsorbent for removing reactive red 141 from aqueous solutions. J. Clean. Prod. 171, 57–65. https://doi.org/10.1016/j.jclepro.2017.10.007