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Bakır(II) 4-Klorofenilasetat İzonikotinamid Kompleksinin Sentezi, Spektroskopik, Termik ve Floresans Özellikleri

Year 2019, Volume: 12 Issue: 1, 9 - 14, 29.07.2019

Abstract

Bu
çalışmada [Cu(4-Cl-phenac)
2(ina)2] genel formüllü
(4-Cl-phenac=4-klorofenilasetat; ina=izonikotinamid)  kompleks sentezlenmiştir. Kompleksin yapısını
aydınlatmak için elementel analiz, FT-IR spektroskopisi yöntemleri kullanılmış
ve kompleksin termal kararlılığı TGA/DTA analizi ile incelenmiştir. Kompleksin
optik özellikleri ve floresans davranışları UV-Vis and Floresans Spektroskopisi
yöntemleri ile incelenmiştir. Bakır atomları çevresinde karboksilat oksijen
atomları üzerinden koordine olan 4-klorofenilasetik asit anyonları ve piridin
halkasında bulunan azot atomu üzerinden koordine olan izonikotinamid ligandları
ile hafif bozulmuş tetrahedral geometri oluşmaktadır. Susuz kompleks yaklaşık
200°C’den itibaren bozunmaya başlamaktadır. Organik ligandların da yapıdan
parçalanarak uzaklaşması neticesinde komplekslerden geriye CuO kaldığı
belirlenmiştir. Kompleks 225 nm dalga boyunda uyarıldığında yaklaşık 350 – 475
nm arasındaki bölgede ışıma yaptığı gözlemlenmiştir.

Supporting Institution

Kafkas Üniversitesi BAP

Project Number

2015-FM-22

Thanks

Teşekkür kısmında belirtilmiştir

References

  • Ahuja I.S. and Prasad I. (1976) Isonicotinamide complexes with some metal(II) halides and pseudohalides, Inorganic and Nuclear Chemistry Letters, 12(10), 777–784.
  • Chakrabarty P.P., Biswas D., García-Granda S.,. Jana A.D, Saha S. (2012) Sodium ion assisted molecular self-assembly in a class of Schiff-base copper(II) complexes. Polyhedron, 35(1), 108–115.
  • Deacon G., (1980) Relationships between the carbon-oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination. Coordination Chemistry Reviews, 33(3), 227–250
  • Desmonts L. B., Reinhoudlt D.N., Mercedes C.C. (2007) Design of fluorescent materials for chemical sensing, Chemical Society Reviews, 36, 993 – 1017.
  • Hökelek T., Dal H., Tercan B., Özbek F.E., Necefoğlu H. (2009) Tetraaquabis(nicotinamide-κ N 1 )nickel(II) bis(2-fluorobenzoate). Acta Crystallographica Section E Structure Reports Online, 65 (1), m1330–m1331.
  • Homzová K., Györyová K., Koman M., Melník M., Juhászová Ž. (2015) Synthesis, crystal structure, and spectroscopic and thermal properties of the polymeric compound catena -poly[[bis(2,4-dichlorobenzoato)zinc(II)]-μ-isonicotinamide]. Acta Crystallographica Section C Structural Chemistry, 71 (9) 814–819.
  • Huang X., Sun H., Dou J., Li D., Wang D. Liu G. (2007) A dimeric luminescent lanthanide complex [Eu(PAA) 2 (phen)(NO3)]2 : hydrothermal synthesis, crystal structure and fluorescence. Journal of Coordination Chemistry, 60 (19), 2045–2050.
  • Iqbal M., Ahmad I., Ali S., Muhammad N., Ahmed S., Sohail M. (2013) Dimeric “paddle-wheel” carboxylates of copper(II): Synthesis, crystal structure and electrochemical studies. Polyhedron, 50 (1), 524–531.
  • Iqbal M., Ali S., Tahir M.N., Shah N.A., (2017), Dihydroxo-bridged dimeric Cu(II) system containing sandwiched non-coordinating phenylacetate anion: Crystal structure, spectroscopic, anti-bacterial, anti-fungal and DNA-binding studies of [(phen)(H 2 O)Cu(OH) 2 Cu(H 2 O)(phen)]2L.6H 2 O: (HL = phenylacetic acid; phen = 1,10-phenanthroline). Journal of Molecular Structure, 1143, 23–30.
  • Lakowicz J. R., (2006). Principles of fluorescence spectroscopy, 3rded. Springer, New York, 530 – 566.
  • Mandal A., Patel B.K., (2017) Molecular structure and fluorescence property of Zn(II), Cd(II) complexes of 3-pyridyl-5-aryl-(1H)-1,2,4-triazoles. Polyhedron, 132, 112-122.
  • Nakamoto K. (2008) Infrared and Raman Spectra of Inorganic and Coordination Compounds: Hoboken, NJ, USA, John Wiley & Sons, Inc., doi:10.1002/9780470405840.
  • Pavia D. L., Lampman G.M., Kriz G.S. (2001) Introduction to spectroscopy: a guide for students of organic chemistry: South Melbourne, Brooks/Cole.
  • Sheng, G.H., Cheng X-S., You Z.L, Zhu H.L. (2015) Syntheses, Crystal Structures, and Characterization of Copper(II) and Zinc(II) Complexes Derived from N,N-Dimethylethane-1,2-diamine and Phenylacetic Acid Derivatives. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 45 (9) 1273–1277.
  • Wen L., Yin H., Li W., Wang D. (2010) New organoantimony complexes with the isomers of chlorophenylacetic acid: Syntheses, characterizations and crystal structures of 1D polymeric chain, 2D network structure and 3D framework. Inorganica Chimica Acta, 363 (4), 676–684.
  • Wu W.P., Wang J., Lu L., Wu Y. (2016) Syntheses and luminescence of four supramolecular coordination complexes with flexible ligand. Russian Journal of Coordination Chemistry, 42 (3),217–224.
  • Yüksek M., Elmali A., Durmuş M., Yaglioglu H.G., Ünver H., Nyokong T. (2010) Good optical limiting performance of indium and gallium phthalocyanines in a solution and co-polymer host. Journal of Optics, 12 (1), 015208.
  • Zhang, W.M., Li M.H, Sun J., Lv P.C, Zhu HL. (2014) Synthesis, characterization, and antibacterial evaluation of copper(II) complexes supported by phenylacetic acid derivatives, and diamine ligands. Journal of Coordination Chemistry, 67 (21) 3519–3531.

Synthesis, Spectroscopic, Thermal and Fluorescence Properties of Copper (II) 4-Chlorophenylacetate with Isonicotinamide

Year 2019, Volume: 12 Issue: 1, 9 - 14, 29.07.2019

Abstract

In this study, the complex of [Cu(4-Cl-phenac)2(ina)2] (4-Cl-phenac = 4 chlorophenylacetate; ina = isonicotinamide) with general formula was synthesized. Elemental analysis and FT-IR spectroscopy methods were used to determine the structure of the complex and thermal stability of the complex was examined by TGA/DTA analysis. Optical properties and fluorescence behavior of the complex were investigated by UV-Vis and Fluorescence Spectroscopy. In these complexes copper ions possess an tetrahedral geometry with two oxygen atoms of 4-chlorophenylacetate anions, two nitrogen atoms from two isonicotinamide. The anhydrous complex beganto decompose at about 200 °C. As a result of the remove of organic ligands from the structure, CuO was a final product of thermal decomposition. The anhydrous complex began to decompose at about 200 °C. When the complex was excited at a wavelength of 225 nm, the emission peaks were observed between 350-475 nm.

Project Number

2015-FM-22

References

  • Ahuja I.S. and Prasad I. (1976) Isonicotinamide complexes with some metal(II) halides and pseudohalides, Inorganic and Nuclear Chemistry Letters, 12(10), 777–784.
  • Chakrabarty P.P., Biswas D., García-Granda S.,. Jana A.D, Saha S. (2012) Sodium ion assisted molecular self-assembly in a class of Schiff-base copper(II) complexes. Polyhedron, 35(1), 108–115.
  • Deacon G., (1980) Relationships between the carbon-oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination. Coordination Chemistry Reviews, 33(3), 227–250
  • Desmonts L. B., Reinhoudlt D.N., Mercedes C.C. (2007) Design of fluorescent materials for chemical sensing, Chemical Society Reviews, 36, 993 – 1017.
  • Hökelek T., Dal H., Tercan B., Özbek F.E., Necefoğlu H. (2009) Tetraaquabis(nicotinamide-κ N 1 )nickel(II) bis(2-fluorobenzoate). Acta Crystallographica Section E Structure Reports Online, 65 (1), m1330–m1331.
  • Homzová K., Györyová K., Koman M., Melník M., Juhászová Ž. (2015) Synthesis, crystal structure, and spectroscopic and thermal properties of the polymeric compound catena -poly[[bis(2,4-dichlorobenzoato)zinc(II)]-μ-isonicotinamide]. Acta Crystallographica Section C Structural Chemistry, 71 (9) 814–819.
  • Huang X., Sun H., Dou J., Li D., Wang D. Liu G. (2007) A dimeric luminescent lanthanide complex [Eu(PAA) 2 (phen)(NO3)]2 : hydrothermal synthesis, crystal structure and fluorescence. Journal of Coordination Chemistry, 60 (19), 2045–2050.
  • Iqbal M., Ahmad I., Ali S., Muhammad N., Ahmed S., Sohail M. (2013) Dimeric “paddle-wheel” carboxylates of copper(II): Synthesis, crystal structure and electrochemical studies. Polyhedron, 50 (1), 524–531.
  • Iqbal M., Ali S., Tahir M.N., Shah N.A., (2017), Dihydroxo-bridged dimeric Cu(II) system containing sandwiched non-coordinating phenylacetate anion: Crystal structure, spectroscopic, anti-bacterial, anti-fungal and DNA-binding studies of [(phen)(H 2 O)Cu(OH) 2 Cu(H 2 O)(phen)]2L.6H 2 O: (HL = phenylacetic acid; phen = 1,10-phenanthroline). Journal of Molecular Structure, 1143, 23–30.
  • Lakowicz J. R., (2006). Principles of fluorescence spectroscopy, 3rded. Springer, New York, 530 – 566.
  • Mandal A., Patel B.K., (2017) Molecular structure and fluorescence property of Zn(II), Cd(II) complexes of 3-pyridyl-5-aryl-(1H)-1,2,4-triazoles. Polyhedron, 132, 112-122.
  • Nakamoto K. (2008) Infrared and Raman Spectra of Inorganic and Coordination Compounds: Hoboken, NJ, USA, John Wiley & Sons, Inc., doi:10.1002/9780470405840.
  • Pavia D. L., Lampman G.M., Kriz G.S. (2001) Introduction to spectroscopy: a guide for students of organic chemistry: South Melbourne, Brooks/Cole.
  • Sheng, G.H., Cheng X-S., You Z.L, Zhu H.L. (2015) Syntheses, Crystal Structures, and Characterization of Copper(II) and Zinc(II) Complexes Derived from N,N-Dimethylethane-1,2-diamine and Phenylacetic Acid Derivatives. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 45 (9) 1273–1277.
  • Wen L., Yin H., Li W., Wang D. (2010) New organoantimony complexes with the isomers of chlorophenylacetic acid: Syntheses, characterizations and crystal structures of 1D polymeric chain, 2D network structure and 3D framework. Inorganica Chimica Acta, 363 (4), 676–684.
  • Wu W.P., Wang J., Lu L., Wu Y. (2016) Syntheses and luminescence of four supramolecular coordination complexes with flexible ligand. Russian Journal of Coordination Chemistry, 42 (3),217–224.
  • Yüksek M., Elmali A., Durmuş M., Yaglioglu H.G., Ünver H., Nyokong T. (2010) Good optical limiting performance of indium and gallium phthalocyanines in a solution and co-polymer host. Journal of Optics, 12 (1), 015208.
  • Zhang, W.M., Li M.H, Sun J., Lv P.C, Zhu HL. (2014) Synthesis, characterization, and antibacterial evaluation of copper(II) complexes supported by phenylacetic acid derivatives, and diamine ligands. Journal of Coordination Chemistry, 67 (21) 3519–3531.
There are 18 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Articles
Authors

Füreya Elif Özbek This is me

Mustafa Sertçelik

Mustafa Yüksek

Ali Murat Tonbul This is me

Hacali Necefoğlu This is me

Project Number 2015-FM-22
Publication Date July 29, 2019
Submission Date June 26, 2019
Published in Issue Year 2019 Volume: 12 Issue: 1

Cite

APA Özbek, F. E., Sertçelik, M., Yüksek, M., Tonbul, A. M., et al. (2019). Bakır(II) 4-Klorofenilasetat İzonikotinamid Kompleksinin Sentezi, Spektroskopik, Termik ve Floresans Özellikleri. Kafkas Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 12(1), 9-14.