Nano–Boyutta Alüminyum Partikülü ile Basic Blue 11’in Sonokatalitik Oksidasyonunun İncelenmesi

Abstract

Tekstil endüstrisinde yüksek konsantrasyonda organik madde ve boya içerikli renkli atıksu açığa çıkmaktadır. Bu tür atıksuların arıtılabilirliğinde yaygın olarak kimyasal veya ileri oksidasyon prosesleri kullanılmaktadır. Son zamanlarda sıfır yüklü partiküller (Al0, Cu0, Fe0, Mg0, Ni0, Zn0) kullanılarak suda bulunan kirleticilerin giderimi konusunda çalışmalar yer almaktadır. Çalışma kapsamında, kesikli reaktör düzeneğinde ultrases (US–40 kHz) ve nano–boyutta sıfır yüklü alüminyum (nZVAl) partikülünün tekli ve birleşik (US/nZVAl) proses uygulamalarının Basic Blue 11 (BB11) boya gideriminde pH, nZVAl dozu ve reaksiyon süresi parametrelerinin etkisi araştırılmıştır. Elde edilen sonuçlara göre, nZVAl partikülünün adsorpsiyon kapasitesinin pH 10 değerinde daha iyi olduğu tespit edilmiştir. Ultrases prosesinin tek başına etkisi az iken, nZVAl partikülü tek başına kullanıldığında 0.40 g nZVAl dozunda 60 dk’ da elde edilen benzer sonuç, birleşik US/nZVAl prosesi kullanıldığında 0.20 g dozda elde edilmiştir. Ultrases etkisi altında nZVAl partikül çap boyutu küçüldüğünden ve yüzey alanı arttığından daha düşük dozda ve kısa sürede BB11 giderimi elde edilmiştir. nZVAl partikülünün BB11 gideriminde geri kazanımı ve tekrar kullanılabilirliği araştırılmış ve nZVAl tek kullanıldığında 5 kez kullanılırken, birleşik US/nZVAl uygulandığında 8 kez tekrar kullanılabileceği ortaya konmuştur. nZVAl ve ultrases proses ile boya adsorpsiyonun Langmuir izotermine ve ikinci dereceden adsorpsiyon kinetiğine uygun olduğu tespit edilmiştir.

Keywords

• Basic Blue 11
• İleri Oksidasyon Prosesi
• Sıfır yüklü alüminyum
• İzoterm
• Kinetik
• Ultrases

Investigation of the Effect of Nano-Scale Aluminum Particle and Ultrasound Process on Basic Blue 11 Removal

Abstract

In the textile industry, colored wastewater containing high concentrations of organic matter and dyes is released. Chemical or advanced oxidation processes are commonly used in the treatment of such wastewaters. Recently, there have been studies on the removal of pollutants in water using zero–valent particles (Al0, Cu0, Fe0, Mg0, Ni0, Zn0). Within the scope of the study, the effects of the alone and combined (US/nZVAl) process applications of ultrasound (US–40 kHz) and nano-sized zero-charged aluminum (nZVAl) particles in batch reactor setup on pH, nZVAl dose, and reaction time parameters were investigated in terms of Basic Blue 11 (BB11) dye removal. According to the results obtained, it was determined that the adsorption capacity of the nZVAl particle was better at pH 10. When the effect of the ultrasound process alone was low, a similar result, which was obtained in 60 minutes at a dose of 0.40 g nZVAl when the nZVAl particle was used alone, was obtained at a dose of 0.20 g using the combined US/nZVAl process. Since the nZVAl particle diameter size decreased and the surface area increased under the effect of ultrasound, BB11 removal was obtained at a lower dose and in a short time. The recovery and reusability of the nZVAl particle in BB11 removal was investigated, and it was found out that while nZVAl was used 2 times when used alone, it could be reused 5 times when the combined US/nZVAl process was applied. It was also determined that dye adsorption with nZVAl and the ultrasound process was in accordance with the Langmuir isotherm and second order adsorption kinetics.

Keywords

• Basic Blue 11
• Advanced Oxidation Process
• Isotherm
• Kinetic
• Zero–valent aluminium
• Ultrasound

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