INVESTIGATION OF THE AMENABILITY OF A COPPER-RICH REFRACTORY GOLD ORE TO CYANIDE LEACHING
Year 2020,
, 225 - 234, 01.12.2020
Deus Albert Msumange
Ersin Yener Yazıcı
,
Oktay Celep
,
Hacı Deveci
Abstract
The production of gold from refractory gold ores has been increasing due to the exhaustion of free
milling gold ores. The presence of cyanicides (e.g., copper minerals) and encapsulation of gold
in minerals such as pyrite and arsenopyrite are common reasons for refractoriness of gold ores.
In this study, the amenability of a copper-rich gold ore (108 g/t Au, 1.60% Cu) to cyanide leaching
was investigated. Direct cyanide leaching of the ore showed that the gold extraction was very low
by 18.4% over 24 h., indicating that the ore is highly refractory. Sulphuric acid pretreatment for
the removal of acid-soluble copper was found to be not effective to achieve high gold extractions
at the subsequent cyanide leaching. Leaching at high NaCN concentrations (1-8 g/L) yielded
limited Au extractions of ≤47.2%. Ultra-fine grinding (UFG) (d80: 8-73 μm) as a pretreatment route
followed by cyanide leaching also could provide Au recoveries of just below 54.1%. The findings
showed that the ore is double-refractory and needs the employment of more effective pretreatment
process(es) to achieve acceptable gold extractions (>90%) in subsequent cyanidation stage.
References
- Akçay, M., Gündüz, Ö., 2004. Porphyry Cu–Au
Mineralisation Associated with a Multi-Phase Intrusion
and Related Replacement Fronts in Limestones in an
Island Arc Setting Near the Gümüşhane Village (Artvin)
In The Eastern Black Sea Province (Turkey). Chemie
Der Erde - Geochemistry, 64, 359-383.
- Aylmore, M.G., Muir, D.M., 2001. Thiosulphate
Leaching of Gold- A Review. Minerals Engineering, 14,
135-174.
- Bas, A. D., Koç, E., Yazici, E. Y., Deveci, H., 2015.
Treatment of Copper-Rich Gold Ore by Cyanide
Leaching. Leaching. Trans Nonferrous Met. Soc.
China, 25 (2), 597-607.
- Bas, A. D., Yazici, E. Y., Deveci, H., 2012. Treatment of
Copper Rich Gold Ores by Ammonia Assisted Cyanide
Leaching. Proceedings of the XXVI International
Mineral Processing Congress (IMPC), New Delhi,
India, 356−365.
- Bascombe, L., Mach, L., Altman, K.A., 2013. Technical
Report on the Çöpler Mineral Resource Update
Erzincan Province. Turkey, No. Canadian National
Instrument, 43-101, Alacer Gold.
- Celep, O., 2011. Application of Alkaline Pretreatments
for Gold and Silver Recovery from Refractory Ores. PhD
Thesis, Karadeniz Technical University. The Graduate
School of Natural and Applied Sciences, Department of
Mining Engineering, Trabzon, May, 157 pp.
- Celep, O., 2015. Processing of Gold Ores. Türkiye Alim
Kitapları, 220 pp (in Turkish).
- Celep, O., Altınkaya, P., Yazıcı, E.Y., Deveci, H., 2016.
Effect of Ultra-fine Grinding on Cyanide Leaching of
Copper Bearing Pyritic Gold Concentrate. Proceedings
of XV. International Mineral Processing Symposium
and Exhibition (IMPS), Istanbul-Turkey, 1255-1269.
- Celep, O., Altinkaya, P., Yazıcı, E.Y., Deveci, H., 2018.
Nitric Acid Leaching for Pre-Treatment of a Copper
Bearing Auroferrous Pyritic Concentrate. XXIX.
International Mineral Processing Congress (IMPC),
Paper no: 184, 17-21.
- Chryssoulis, S.L., Mcmullen, J., 2016. Mineralogical
Investigation of Gold Ores. Gold Ore Processing-
Project Development and Operations. Editor Mike
Adams, Elsevier, 57-93.
Deveci, H., Yazici, E.Y., Celep, O., 2018. An Overview
of Pre-treatment and Leaching Options for Gold
Extraction from Refractory Copper-Gold Ores. 16th
International Mineral Processing Symposium and
Exhibition (IMPS), Antalya, 439-451.
- Ellis, S., Gao, M., 2002. The Development of Ultra-fine
Grinding at KCGM. SME Annual Conference, Preprint
02-072.
- Fleming, C.A., Mezei, A., Bourricaudy, E., Canizares,
M., Ashbury, M., 2011. Factors Influencing the Rate of
Gold Cyanide Leaching and Adsorption on Activated
Carbon, and their Impact on the Design of CIL and CIP
Circuits. Minerals Engineering, 24, 6, 484-494.
- Fleming, C.A., 2011. Dealing with Cyanide-Soluble
Copper in the Gold Mining Industry. Fray International
Symposium on Metals and Materials Processing in a
Clean Environment. Mexico, 173-190.
- Habashi, F., 1999. A Textbook of Hydrometallurgy.
Metallurgie Extractive Quebec Publications, Canada,
220-223.
- Hayes, G. A., Corrans, I. J., 1992. Leaching of Gold-
Copper Ores Using Ammoniacal Cyanide. Proceedings
of International Conference on Extractive Metallurgy of
Gold and Base Metals, Melbourne, Australasian Inst
Min Metall, 349-353.
- Hedley, N., Tabachnick, H., 1958. Chemistry of
Cyanidation. Mineral Dressing Notes No. 23, American
Cyanamid Company, New Jersey.
- Kesler, S.E., Chryssoulis, S.L., Simon, G., 2002. Gold
in Porphyry Copper Deposits: Its Abundance and Fate.
Ore Geology Review, 21 (1-2), 103-124.
- Marsden, J., House, I., 2006. The Chemistry of
Gold Extraction. 2nd Edition, The Society for Mining
Metallurgy and Exploration Inc., USA, 318-392.
- Medusa, 2009. Software for Chemical Equilibrium
Diagrams. 32 bit version, Royal Institute of Technology,
Sweden.
- Muir, D.M., 2011. A Review of the Selective Leaching of
Gold from Oxidized Copper-Gold Ores with Ammonia-
Cyanide and New Insights for Plant Control and
Operation. Minerals Engineering, 24, 576-582.
- Sceresini, B., Breuer, P., 2016. Gold-copper Ores.
Gold Ore Processing, 2nd Edition, Chapter 43, Editor:
Adams, M. D., Elsevier.
- Sinclair, W.D., 2007. Porphyry Deposits. Geological
Association of Canada, Mineral Deposits Division,
Special Publication, Canada, 223-243.
- URL-1,http://kozaaltin.com.tr/operasyonlar-ve-projeler/
kaymaz-altin-madeni, 02 August 2013.
- URL-2,https://www.alacergold.com/operations/
resources-and-reserves, 29 July 2020.
- URL-3,http://marianaresources.com/projects/hotmaden/
24 March 2016.
- Yazici, E. Y., Deveci, H., Alp, I., 2009. Treatment of
Cyanide Effluents by Oxidation and Adsorption in Batch
and Column Studies. Journal of Hazardous Materials,
166 (2-3), 1362-1366.
- Yazici, E.Y., Ahlatci, F., Koc, E., Celep, O., Deveci,
H., 2015. Pre-treatment of a Copper-rich Gold Ore
for Elimination of Copper Interference. 8th European
Metallurgical Conference (EMC), Dusseldorf, Vol. 2,
601-613.
- Yılmaz, E., Yazıcı, E.Y., Celep, O., Deveci, H., 2019.
Recovery of Cyanide from Effluents: SART Process.
Gumushane University Journal of Science and
Technology Institute, 9 (3), 600-615 (in Turkish).
- Yigit, O., 2006. Gold in Turkey- A Missing Link in
Tethyan Metallogeny. Ore Geology Reviews, 28, 147-
179.
BAKIR İÇERİĞİ YÜKSEK REFRAKTER BİR ALTIN CEVHERİNİN SİYANÜR LİÇİNE UYGUNLUĞUNUN ARAŞTIRILMASI
Year 2020,
, 225 - 234, 01.12.2020
Deus Albert Msumange
Ersin Yener Yazıcı
,
Oktay Celep
,
Hacı Deveci
Abstract
Serbest altın içeren cevherlerin giderek tükenmesi nedeniyle refrakter altın cevherlerinden altın
üretimi artmaktadır. Siyanür tüketen minerallerin (bakır mineralleri gibi) varlığı ve altının pirit ve
arsenopirit gibi mineraller içerisinde kapanım halinde bulunması altın cevherlerindeki refrakterliğin
yaygın nedenleri arasında yer almaktadır. Bu çalışmada, bakırca zengin bir altın cevherinin
(108 g/t Au, %1,60 Cu) siyanür liçine uygunluğu araştırılmıştır. Siyanür liçinde elde edilen düşük
(%18,4) altın kazanımı, cevherin yüksek derecede refrakter bir cevher olduğunu göstermektedir.
Sülfürik asit ön işlemi ile asitte çözünen bakırın uzaklaştırılması, takip eden siyanür liçinde
yüksek altın kazanımlarına ulaşılmasında etkili olmamıştır. Yüksek NaCN konsantrasyonlarında
(1-8 g/L) yapılan testlerde, sınırlı altın kazanımları (≤%47,2) elde edilmiştir. Siyanür liçinden önce
ön işlem olarak uygulanan çok ince öğütme (d80: 8-73 μm) sonrası altın kazanımları %54,1’in
altında kalmıştır. Elde edilen sonuçlar cevherin çift yönlü refrakter bir cevher olduğunu ve siyanür
liçi aşamasında kabul edilebilir (>%90) altın kazanımlarına ulaşmak için daha etkili ön işlem(ler)in
uygulanmasının gerekli olduğunu göstermiştir.
References
- Akçay, M., Gündüz, Ö., 2004. Porphyry Cu–Au
Mineralisation Associated with a Multi-Phase Intrusion
and Related Replacement Fronts in Limestones in an
Island Arc Setting Near the Gümüşhane Village (Artvin)
In The Eastern Black Sea Province (Turkey). Chemie
Der Erde - Geochemistry, 64, 359-383.
- Aylmore, M.G., Muir, D.M., 2001. Thiosulphate
Leaching of Gold- A Review. Minerals Engineering, 14,
135-174.
- Bas, A. D., Koç, E., Yazici, E. Y., Deveci, H., 2015.
Treatment of Copper-Rich Gold Ore by Cyanide
Leaching. Leaching. Trans Nonferrous Met. Soc.
China, 25 (2), 597-607.
- Bas, A. D., Yazici, E. Y., Deveci, H., 2012. Treatment of
Copper Rich Gold Ores by Ammonia Assisted Cyanide
Leaching. Proceedings of the XXVI International
Mineral Processing Congress (IMPC), New Delhi,
India, 356−365.
- Bascombe, L., Mach, L., Altman, K.A., 2013. Technical
Report on the Çöpler Mineral Resource Update
Erzincan Province. Turkey, No. Canadian National
Instrument, 43-101, Alacer Gold.
- Celep, O., 2011. Application of Alkaline Pretreatments
for Gold and Silver Recovery from Refractory Ores. PhD
Thesis, Karadeniz Technical University. The Graduate
School of Natural and Applied Sciences, Department of
Mining Engineering, Trabzon, May, 157 pp.
- Celep, O., 2015. Processing of Gold Ores. Türkiye Alim
Kitapları, 220 pp (in Turkish).
- Celep, O., Altınkaya, P., Yazıcı, E.Y., Deveci, H., 2016.
Effect of Ultra-fine Grinding on Cyanide Leaching of
Copper Bearing Pyritic Gold Concentrate. Proceedings
of XV. International Mineral Processing Symposium
and Exhibition (IMPS), Istanbul-Turkey, 1255-1269.
- Celep, O., Altinkaya, P., Yazıcı, E.Y., Deveci, H., 2018.
Nitric Acid Leaching for Pre-Treatment of a Copper
Bearing Auroferrous Pyritic Concentrate. XXIX.
International Mineral Processing Congress (IMPC),
Paper no: 184, 17-21.
- Chryssoulis, S.L., Mcmullen, J., 2016. Mineralogical
Investigation of Gold Ores. Gold Ore Processing-
Project Development and Operations. Editor Mike
Adams, Elsevier, 57-93.
Deveci, H., Yazici, E.Y., Celep, O., 2018. An Overview
of Pre-treatment and Leaching Options for Gold
Extraction from Refractory Copper-Gold Ores. 16th
International Mineral Processing Symposium and
Exhibition (IMPS), Antalya, 439-451.
- Ellis, S., Gao, M., 2002. The Development of Ultra-fine
Grinding at KCGM. SME Annual Conference, Preprint
02-072.
- Fleming, C.A., Mezei, A., Bourricaudy, E., Canizares,
M., Ashbury, M., 2011. Factors Influencing the Rate of
Gold Cyanide Leaching and Adsorption on Activated
Carbon, and their Impact on the Design of CIL and CIP
Circuits. Minerals Engineering, 24, 6, 484-494.
- Fleming, C.A., 2011. Dealing with Cyanide-Soluble
Copper in the Gold Mining Industry. Fray International
Symposium on Metals and Materials Processing in a
Clean Environment. Mexico, 173-190.
- Habashi, F., 1999. A Textbook of Hydrometallurgy.
Metallurgie Extractive Quebec Publications, Canada,
220-223.
- Hayes, G. A., Corrans, I. J., 1992. Leaching of Gold-
Copper Ores Using Ammoniacal Cyanide. Proceedings
of International Conference on Extractive Metallurgy of
Gold and Base Metals, Melbourne, Australasian Inst
Min Metall, 349-353.
- Hedley, N., Tabachnick, H., 1958. Chemistry of
Cyanidation. Mineral Dressing Notes No. 23, American
Cyanamid Company, New Jersey.
- Kesler, S.E., Chryssoulis, S.L., Simon, G., 2002. Gold
in Porphyry Copper Deposits: Its Abundance and Fate.
Ore Geology Review, 21 (1-2), 103-124.
- Marsden, J., House, I., 2006. The Chemistry of
Gold Extraction. 2nd Edition, The Society for Mining
Metallurgy and Exploration Inc., USA, 318-392.
- Medusa, 2009. Software for Chemical Equilibrium
Diagrams. 32 bit version, Royal Institute of Technology,
Sweden.
- Muir, D.M., 2011. A Review of the Selective Leaching of
Gold from Oxidized Copper-Gold Ores with Ammonia-
Cyanide and New Insights for Plant Control and
Operation. Minerals Engineering, 24, 576-582.
- Sceresini, B., Breuer, P., 2016. Gold-copper Ores.
Gold Ore Processing, 2nd Edition, Chapter 43, Editor:
Adams, M. D., Elsevier.
- Sinclair, W.D., 2007. Porphyry Deposits. Geological
Association of Canada, Mineral Deposits Division,
Special Publication, Canada, 223-243.
- URL-1,http://kozaaltin.com.tr/operasyonlar-ve-projeler/
kaymaz-altin-madeni, 02 August 2013.
- URL-2,https://www.alacergold.com/operations/
resources-and-reserves, 29 July 2020.
- URL-3,http://marianaresources.com/projects/hotmaden/
24 March 2016.
- Yazici, E. Y., Deveci, H., Alp, I., 2009. Treatment of
Cyanide Effluents by Oxidation and Adsorption in Batch
and Column Studies. Journal of Hazardous Materials,
166 (2-3), 1362-1366.
- Yazici, E.Y., Ahlatci, F., Koc, E., Celep, O., Deveci,
H., 2015. Pre-treatment of a Copper-rich Gold Ore
for Elimination of Copper Interference. 8th European
Metallurgical Conference (EMC), Dusseldorf, Vol. 2,
601-613.
- Yılmaz, E., Yazıcı, E.Y., Celep, O., Deveci, H., 2019.
Recovery of Cyanide from Effluents: SART Process.
Gumushane University Journal of Science and
Technology Institute, 9 (3), 600-615 (in Turkish).
- Yigit, O., 2006. Gold in Turkey- A Missing Link in
Tethyan Metallogeny. Ore Geology Reviews, 28, 147-
179.