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ALTIN CEVHERLERİNİN KARAKTERİZASYONUNDA KULLANILAN MİKRO ANALİTİK YÖNTEMLER

Year 2018, Volume: 57 Issue: 4, 281 - 298, 01.12.2018
https://doi.org/10.30797/madencilik.479520

Abstract

Mikro analitik teknikler, cevher karakterizasyon çalışmalarında yaygın bir şekilde kullanılmaktadır.
Altın cevherlerinin, özellikle refrakter altın cevherlerinin karakterizasyonunda da etkin bir şekilde
kullanılan bu teknikler, doğruluk ve hassasiyeti yüksek oldukça faydalı bilgiler sunmaktadır. Cevher
hakkındaki bu bilgiler doğru proses seçiminin yapılmasına ya da mevcut prosesin etkin bir şekilde
kontrol edilmesine olanak sağlamaktadır. Bu çalışmada, altın cevherlerinin karakterizasyonunda,
mikroskobik (visible) altının belirlenmesinde kullanılan (QEMSCAN) (Quantitative Evaluation
of Mineralogy by Scanning Electron Microscope), MLA (Mineral Liberation Analyzer) gibi SEM
(Scanning Electron Microscopy) temelli geliştirilmiş modern otomatik analiz yöntemlerinin yanı
sıra refrakter altın cevherlerinde mikroskop altında kolayca görülemeyen, çok ince ‘invisible’
altının belirlenmesinde kullanılan EPMA (Electron-Probe Micro-Analysis), μ-PIXE (Microparticle-
induced X-ray emission) ve SIMS (Secondary-Ion Mass Spectrometry) gibi yaygın
olarak kullanılan mikro analitik yöntemler tanıtılmakta ve yapılan güncel çalışmalardan örnekler
sunulmaktadır.

References

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  • Adams, M.D., Burger, A.M., 1998b. Characterization and Blinding of Carbonaceous Preg- robbers in Gold Ores. Miner. Eng. 11 (10), 919-927.
  • Adams, M.D., Swaney, S.J., Friedl, J., Wagner, F.E., 1996. Preg-robbing Minerals in Gold Ore and Residues. In: Hidden Wealth. SAIMM, Johannesburg, 163-172.
  • Agangi, A., Przybyłowicz, W., Hofmann, A., 2015. Trace Element Mapping of Pyrite from Archean Gold Deposits – A Comparison between PIXE and EPMA. Nuclear Instruments and Methods in Physics Research B, 348, 302–306.
  • Andersen, J.C.Ø., Rollinson, G.K., Snook, B., Herrington, R.,Fairhurst, R.J., 2009. Use of QEMSCAN for the Characterization of Nirich and Ni-poor Goethite in Laterite Ores. Minerals Engineering, 22, 1119-1129.
  • Andrews, L., 2007. The Use of Electron Microbeam Techniques in Metallurgical Analysis, SAIMM, 107, 79-82.
  • Ashley, P.M., Creagh, C.,J., Ryan, C., 2000. Invisible Gold in Ore and Mineral Concentrates from the Hillgrove Gold-Antimony Deposits, NSW, Australia. Mineralium Deposita. 35, 285-301.
  • Boyle, R.W., 1979. The Geochemistry of Gold and Its Deposits.Geological Survey of Canada Bulletin, 280.
  • Cabri, L.J., 1987. The Mineralogy of Precious Metals: New Development sand Metallurgical Implication, Canadian Mineralogist, 25, 1-7.
  • Cabri, L.J., Campbell, J.L., 1998. The Proton Microprobe in Ore Mineralogy (Micro-PIXE Technique), In Modern Approaches to Ore and Environmental Mineralogy, Eds. L.J. Cabri, And D.J. Vaughan, Mineral. Assoc. Can., Short Course, 27, 181-198.
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  • Cabri, L.J., Jackson, S.E., 2011. New Developments in Characerization of Sulphide Refractory Gold Ores. In Proceedings of World Gold 2011, Organized By Metsoc, 51- 62.
  • Cabri, L.J., Mcmahon, G., 1995. SIMS Analysis of Sulfide Minerals for Pt and Au: Methodology and Relative Sensitivity Factors (RSF). The Canadian Mineralogist, 33, 349- 359.
  • Cabri, L.J., Newville, M., Gordon, R.A., Crozier, E.D., Sutton, S.R., Mcmahon, G., Jiang, D-T., 2000. Chemical Speciation of Gold in Arsenopyrite. The Canadian Mineralogist, 38, 1265-1281.
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  • Celep, O., 2011. Refakter Cevherlerden Siyanür Liçiyle Altın ve Gümüş Kazanımında Alkali Ön İşlemlerin Uygulanması, Doktora Tezi, KTU Fen Bilimleri Enstitüsü, Trabzon, S.167.
  • Celep, O., 2015. Altın Cevherlerinin Zenginleştirilmesi (Processing of Gold Ores), Türkiye Alim Kitapları, IstEin Imprint Der, Deutschland/Almanya, ISBN 13 9783639672138, P.221.
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  • Celep, O., Alp, İ., Deveci, H., Vıcıl, M., 2008. The Effect of Mineralogical Structure on the Cyanidation of Gold Ores, Geosound, 52, 43-53.
  • Celep, O., Alp, İ., Deveci, H., Vıcıl, M., 2009. Characterization of Refractory Behaviour of a Complex Gold/Silver Ore by Diagnostic Leaching, Transactions of Nonferrous Metals Society of China, 19, 707-713.
  • Celep, O., Alp, İ., Paktunç, D., Thibault, Y., 2011. Implementation of Sodium Hydroxide Pretreatment for Refractory Antimonial Gold and Silver Ores, Hydrometallurgy, 108, (1-2), 109-114.
  • Celep, O., Serbest, V., 2015. Characterization of an Iron Oxy/Hydroxide (Gossan Type) Bearing Refractory Gold and Silver Ore by Diagnostic Leaching. Transactions of Nonferrous Metals Society of China, 25 (4), 1286-1297.
  • Chen, T.T., Cabri, L.J., Dutrizac, J.E., 2002. Characterizing Gold in Refractory Sulfide Gold Ores and Residues, JOM, 54, 12, 20- 22.
  • Chryssoulis, S., Dunne, R., Coetzee, A., 2004. Diagnostic Microbeam Technology In Gold Ore Processing, JOM, 56, 7, 53-57.
  • Chryssoulis, S.L., 1997. Gold “Pregrobbing” by Pyrite: Natural and Process Induced. In: Austin, J. (Ed.), Proceedings of 29th CMP, Ottawa. CIM, Montreal, 1-12.
  • Chryssoulis, S.L., Cabri, L.J., 1990. Significance of Gold Mineralogical Balances in Mineral Processing. Trans. Instn. Min. Metall, Sec. C: Mineral Process. Extr. Metall., 99, C1-C10.
  • Chryssoulis, S.L., Cabri, L.J., Salter, R.S., 1987. Direct Determination of Invisible Gold in Refractory Sulfide Ores. In Proceedings of the International Symposium on Gold Metallurgy, New York: Pergamon Press. 235-244.
  • Chryssoulis, S.L., Grammatikopoulos, T.A., 2003. Forms of Gold. In: Eliopoulos D.G. et al., Mineral exploration and sustainable development, Millpress, 961-964.
  • Chryssoulis, S.L., Mcmullen, J., 2016. Mineralogical Investigation of Gold Ores, Chapter 5, In Gold Ore Processing-Project Development and Operations, Ed. Mike Adams, Elsevier, 57-93.
  • Coetzee, L.L., Theron, S.J., Martin, G.J., Van Der Merwe, J.D., Stanek, T.A., 2011. Modern Gold Deportments and Its Application to Industry Minerals Engineering, 24, 565–575.
  • Cook, N.J., Chryssoulis, S.L., 1990. Concentrations of ‘Invisible’ Gold in Common Sulfides. The Canadian Mineralogist, 28 (1), 1-16.
  • Cousens, D.R., Rasch, R., Ryan, C.G., 1997. Detection Limits and Accuracy of the Electron and Proton Microprobe. Micron, 28, 231-239.
  • Fandrich, R., Gu, Y., Burrows, D., Moeller, K., 2007. Modern SEM-Based Mineral Liberation Analysis. International Journal of Mineral Processing, 84, 310-320.
  • Fleming, C.A., 1992. Hydrometallurgy of Precious Metals Recovery. Hydrometallurgy, 30, 1-3, 127-162.
  • Foya, S.N., Reimold, W.U., Przybylowicz, W.J., Gibson, R.L., 1999. PIXE Microanalysis of Gold-Pyrite Associations from the Kimberley Reefs, Witwatersrand Basin, South Africa, Nuclear Instruments and Methods In Physics Research B, 158, 588-592
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  • Goodall, W.R, Scales, P.J, Ryan, C.G., 2005a. Applications of PIXE and Diagnostic Leaching In The Characterisation of Complex Gold Ores, Minerals Engineering, 18, 1010- 1019.
  • Goodall, W.R, Scales, P.J., Butcher, A.R., 2005b. The Use of QEMSCAN and Diagnostic Leaching In the Characterisation of Visible Gold in Complex Ores, Minerals Engineering, 18, 877-886.
  • Goodall, W.R., 2005. The Economic Recovery of Gold from Complex Ores, Doktora Tezi, Melboure Üniversitesi, Avustralya, p.288.
  • Goodall, W.R., Butcher, A.R., 2012. The Use of QEMSCAN in Practical Gold Deportment Studies”, Mineral Processing and Extractive Metallurgy (Trans. Inst. Min. Metall. C), 121, 199-204.
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Year 2018, Volume: 57 Issue: 4, 281 - 298, 01.12.2018
https://doi.org/10.30797/madencilik.479520

Abstract

References

  • Adams, M., 2016. Gold Ore Processing: Project Development and Operations. 2nd Ed. Elsevier.
  • Adams, M.D., Burger, A.M., 1998a. Characterization of Carbonaceous Pregrobbers and Abraded Carbon in Gold Residues. In: CIM Montréal’98. Canadian Institute of Mining, Metallurgy and Petroleum, Montreal, pp 8.
  • Adams, M.D., Burger, A.M., 1998b. Characterization and Blinding of Carbonaceous Preg- robbers in Gold Ores. Miner. Eng. 11 (10), 919-927.
  • Adams, M.D., Swaney, S.J., Friedl, J., Wagner, F.E., 1996. Preg-robbing Minerals in Gold Ore and Residues. In: Hidden Wealth. SAIMM, Johannesburg, 163-172.
  • Agangi, A., Przybyłowicz, W., Hofmann, A., 2015. Trace Element Mapping of Pyrite from Archean Gold Deposits – A Comparison between PIXE and EPMA. Nuclear Instruments and Methods in Physics Research B, 348, 302–306.
  • Andersen, J.C.Ø., Rollinson, G.K., Snook, B., Herrington, R.,Fairhurst, R.J., 2009. Use of QEMSCAN for the Characterization of Nirich and Ni-poor Goethite in Laterite Ores. Minerals Engineering, 22, 1119-1129.
  • Andrews, L., 2007. The Use of Electron Microbeam Techniques in Metallurgical Analysis, SAIMM, 107, 79-82.
  • Ashley, P.M., Creagh, C.,J., Ryan, C., 2000. Invisible Gold in Ore and Mineral Concentrates from the Hillgrove Gold-Antimony Deposits, NSW, Australia. Mineralium Deposita. 35, 285-301.
  • Boyle, R.W., 1979. The Geochemistry of Gold and Its Deposits.Geological Survey of Canada Bulletin, 280.
  • Cabri, L.J., 1987. The Mineralogy of Precious Metals: New Development sand Metallurgical Implication, Canadian Mineralogist, 25, 1-7.
  • Cabri, L.J., Campbell, J.L., 1998. The Proton Microprobe in Ore Mineralogy (Micro-PIXE Technique), In Modern Approaches to Ore and Environmental Mineralogy, Eds. L.J. Cabri, And D.J. Vaughan, Mineral. Assoc. Can., Short Course, 27, 181-198.
  • Cabri, L.J., Chryssoulis, S.L., Campbell, J.L., Teesdale, W.J., 1991. Comparison of in-situ Gold Analyses in Arsenian Pyrite. Applied Geochemistry, 6, 225-230.
  • Cabri, L.J., Chryssoulis, S.L., De Villiers, J.P.R., Gilles Laflamme, J.H., Buseck, P.R. 1989. The Nature of “Invisible” Gold in Arsenopyrite, Canadian Mineralogist, 27, 353-362.
  • Cabri, L.J., Jackson, S.E., 2011. New Developments in Characerization of Sulphide Refractory Gold Ores. In Proceedings of World Gold 2011, Organized By Metsoc, 51- 62.
  • Cabri, L.J., Mcmahon, G., 1995. SIMS Analysis of Sulfide Minerals for Pt and Au: Methodology and Relative Sensitivity Factors (RSF). The Canadian Mineralogist, 33, 349- 359.
  • Cabri, L.J., Newville, M., Gordon, R.A., Crozier, E.D., Sutton, S.R., Mcmahon, G., Jiang, D-T., 2000. Chemical Speciation of Gold in Arsenopyrite. The Canadian Mineralogist, 38, 1265-1281.
  • Can, N.M., Çelik, İ.B., 2009. Proses Mineralojisi: Cevher Hazırlamadaki Önemi, Ölçüm Yöntem ve Araçları-Bölüm 1, Madencilik Dergisi, 48, 43-53.
  • Celep, O., 2011. Refakter Cevherlerden Siyanür Liçiyle Altın ve Gümüş Kazanımında Alkali Ön İşlemlerin Uygulanması, Doktora Tezi, KTU Fen Bilimleri Enstitüsü, Trabzon, S.167.
  • Celep, O., 2015. Altın Cevherlerinin Zenginleştirilmesi (Processing of Gold Ores), Türkiye Alim Kitapları, IstEin Imprint Der, Deutschland/Almanya, ISBN 13 9783639672138, P.221.
  • Celep, O., Alp İ., Deveci, H., 2011. Improved Gold and Silver Extraction from a Refractory Antimony Ore by Pre-treatment with Alkaline Sulphide Leach, Hydrometallurgy, 105, 3-4, 234-239.
  • Celep, O., Alp, İ., Deveci, H., Vıcıl, M., 2008. The Effect of Mineralogical Structure on the Cyanidation of Gold Ores, Geosound, 52, 43-53.
  • Celep, O., Alp, İ., Deveci, H., Vıcıl, M., 2009. Characterization of Refractory Behaviour of a Complex Gold/Silver Ore by Diagnostic Leaching, Transactions of Nonferrous Metals Society of China, 19, 707-713.
  • Celep, O., Alp, İ., Paktunç, D., Thibault, Y., 2011. Implementation of Sodium Hydroxide Pretreatment for Refractory Antimonial Gold and Silver Ores, Hydrometallurgy, 108, (1-2), 109-114.
  • Celep, O., Serbest, V., 2015. Characterization of an Iron Oxy/Hydroxide (Gossan Type) Bearing Refractory Gold and Silver Ore by Diagnostic Leaching. Transactions of Nonferrous Metals Society of China, 25 (4), 1286-1297.
  • Chen, T.T., Cabri, L.J., Dutrizac, J.E., 2002. Characterizing Gold in Refractory Sulfide Gold Ores and Residues, JOM, 54, 12, 20- 22.
  • Chryssoulis, S., Dunne, R., Coetzee, A., 2004. Diagnostic Microbeam Technology In Gold Ore Processing, JOM, 56, 7, 53-57.
  • Chryssoulis, S.L., 1997. Gold “Pregrobbing” by Pyrite: Natural and Process Induced. In: Austin, J. (Ed.), Proceedings of 29th CMP, Ottawa. CIM, Montreal, 1-12.
  • Chryssoulis, S.L., Cabri, L.J., 1990. Significance of Gold Mineralogical Balances in Mineral Processing. Trans. Instn. Min. Metall, Sec. C: Mineral Process. Extr. Metall., 99, C1-C10.
  • Chryssoulis, S.L., Cabri, L.J., Salter, R.S., 1987. Direct Determination of Invisible Gold in Refractory Sulfide Ores. In Proceedings of the International Symposium on Gold Metallurgy, New York: Pergamon Press. 235-244.
  • Chryssoulis, S.L., Grammatikopoulos, T.A., 2003. Forms of Gold. In: Eliopoulos D.G. et al., Mineral exploration and sustainable development, Millpress, 961-964.
  • Chryssoulis, S.L., Mcmullen, J., 2016. Mineralogical Investigation of Gold Ores, Chapter 5, In Gold Ore Processing-Project Development and Operations, Ed. Mike Adams, Elsevier, 57-93.
  • Coetzee, L.L., Theron, S.J., Martin, G.J., Van Der Merwe, J.D., Stanek, T.A., 2011. Modern Gold Deportments and Its Application to Industry Minerals Engineering, 24, 565–575.
  • Cook, N.J., Chryssoulis, S.L., 1990. Concentrations of ‘Invisible’ Gold in Common Sulfides. The Canadian Mineralogist, 28 (1), 1-16.
  • Cousens, D.R., Rasch, R., Ryan, C.G., 1997. Detection Limits and Accuracy of the Electron and Proton Microprobe. Micron, 28, 231-239.
  • Fandrich, R., Gu, Y., Burrows, D., Moeller, K., 2007. Modern SEM-Based Mineral Liberation Analysis. International Journal of Mineral Processing, 84, 310-320.
  • Fleming, C.A., 1992. Hydrometallurgy of Precious Metals Recovery. Hydrometallurgy, 30, 1-3, 127-162.
  • Foya, S.N., Reimold, W.U., Przybylowicz, W.J., Gibson, R.L., 1999. PIXE Microanalysis of Gold-Pyrite Associations from the Kimberley Reefs, Witwatersrand Basin, South Africa, Nuclear Instruments and Methods In Physics Research B, 158, 588-592
  • Gasparrini, C., 1983. The Mineralogy of Gold and Its Significance in Metal Extraction. Canadian Mining & Metallurgical Bulletin, 76, 144-153.
  • Genkin, A.D., Bortnikov, N.S., Cabri, L.J., Wagner, F.E., Stanley, C.J., Safonov, Y.G., Mcmahon, G., Friedl, J., Kerzin, A.L., Gamyanin, G.N., 1998. A Multidisciplinary Study of Invisible Gold In Arsenopyrite From Four Mesothermal Gold Deposits In Siberia, Russian Federation, Economic Geology, 93, 463-487.
  • Goodall, W. R., 2008. Characterisation of Mineralogy and Gold Deportment for Complex Tailings Deposits Using QEMSCAN, Minerals Engineering, 21, 518–523
  • Goodall, W.R, Scales, P.J, Ryan, C.G., 2005a. Applications of PIXE and Diagnostic Leaching In The Characterisation of Complex Gold Ores, Minerals Engineering, 18, 1010- 1019.
  • Goodall, W.R, Scales, P.J., Butcher, A.R., 2005b. The Use of QEMSCAN and Diagnostic Leaching In the Characterisation of Visible Gold in Complex Ores, Minerals Engineering, 18, 877-886.
  • Goodall, W.R., 2005. The Economic Recovery of Gold from Complex Ores, Doktora Tezi, Melboure Üniversitesi, Avustralya, p.288.
  • Goodall, W.R., Butcher, A.R., 2012. The Use of QEMSCAN in Practical Gold Deportment Studies”, Mineral Processing and Extractive Metallurgy (Trans. Inst. Min. Metall. C), 121, 199-204.
  • Goodall, W.R., Scales, P.J., 2007. An Overview of the Advantages and Disadvantages of the Determination of Gold Mineralogy by Automated Mineralogy, Minerals Engineering, 20 (5), 506-517.
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There are 82 citations in total.

Details

Primary Language Turkish
Journal Section Collection
Authors

Oktay Celep This is me 0000-0001-9024-4196

Ahmet Deniz Baş This is me 0000-0003-4633-9053

Ersin Yener Yazıcı 0000-0002-8711-0784

Hacı Deveci 0000-0003-4105-0912

Publication Date December 1, 2018
Submission Date February 8, 2018
Published in Issue Year 2018 Volume: 57 Issue: 4

Cite

APA Celep, O., Baş, A. D., Yazıcı, E. Y., Deveci, H. (2018). ALTIN CEVHERLERİNİN KARAKTERİZASYONUNDA KULLANILAN MİKRO ANALİTİK YÖNTEMLER. Scientific Mining Journal, 57(4), 281-298. https://doi.org/10.30797/madencilik.479520
AMA Celep O, Baş AD, Yazıcı EY, Deveci H. ALTIN CEVHERLERİNİN KARAKTERİZASYONUNDA KULLANILAN MİKRO ANALİTİK YÖNTEMLER. Mining. December 2018;57(4):281-298. doi:10.30797/madencilik.479520
Chicago Celep, Oktay, Ahmet Deniz Baş, Ersin Yener Yazıcı, and Hacı Deveci. “ALTIN CEVHERLERİNİN KARAKTERİZASYONUNDA KULLANILAN MİKRO ANALİTİK YÖNTEMLER”. Scientific Mining Journal 57, no. 4 (December 2018): 281-98. https://doi.org/10.30797/madencilik.479520.
EndNote Celep O, Baş AD, Yazıcı EY, Deveci H (December 1, 2018) ALTIN CEVHERLERİNİN KARAKTERİZASYONUNDA KULLANILAN MİKRO ANALİTİK YÖNTEMLER. Scientific Mining Journal 57 4 281–298.
IEEE O. Celep, A. D. Baş, E. Y. Yazıcı, and H. Deveci, “ALTIN CEVHERLERİNİN KARAKTERİZASYONUNDA KULLANILAN MİKRO ANALİTİK YÖNTEMLER”, Mining, vol. 57, no. 4, pp. 281–298, 2018, doi: 10.30797/madencilik.479520.
ISNAD Celep, Oktay et al. “ALTIN CEVHERLERİNİN KARAKTERİZASYONUNDA KULLANILAN MİKRO ANALİTİK YÖNTEMLER”. Scientific Mining Journal 57/4 (December 2018), 281-298. https://doi.org/10.30797/madencilik.479520.
JAMA Celep O, Baş AD, Yazıcı EY, Deveci H. ALTIN CEVHERLERİNİN KARAKTERİZASYONUNDA KULLANILAN MİKRO ANALİTİK YÖNTEMLER. Mining. 2018;57:281–298.
MLA Celep, Oktay et al. “ALTIN CEVHERLERİNİN KARAKTERİZASYONUNDA KULLANILAN MİKRO ANALİTİK YÖNTEMLER”. Scientific Mining Journal, vol. 57, no. 4, 2018, pp. 281-98, doi:10.30797/madencilik.479520.
Vancouver Celep O, Baş AD, Yazıcı EY, Deveci H. ALTIN CEVHERLERİNİN KARAKTERİZASYONUNDA KULLANILAN MİKRO ANALİTİK YÖNTEMLER. Mining. 2018;57(4):281-98.

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