Tere Bitkisindeki Metallerin Atomik Absorpsiyon Spektrometre ile Tayini

Year 2016, Volume: 7 Issue: Ek (Suppl.) 1, 240 - 247, 09.10.2016

Burcu Kabak Diğdem Trak Yasin Arslan Yılmaz Erdem Erdal Kendüzler

Abstract

Bu çalışmada, Burdur şehir merkezinden geçen dere suyu kullanılarak yetiştirilen tere bitkisindeki (Lepidium sativum)  bazı metallerin (Na, K, Mg, Ca, Mn, Fe, Cu, Cd, Hg, Pb) tayini, atomik absorpsiyon spektrometre (AAS) ile gerçekleştirilmiştir. Tere bitkisi, dere suyuyla sulama yapılan dere kenarındaki bir tarladan alınan toprak kullanılarak yetiştirilmiştir. Tere tohumları, bu toprak örneklerini içeren polietilen saksılara ekilmiş ve sulama suyu olarak da dere ve yerel marketten temin edilen içme suyu kullanılmıştır. Belirli bir büyüklüğe erişen bitkiden yaprakları hasat edilmiştir. Tere yaprakları mikrodalga yöntemi kullanılarak çözülmüştür. Örneklerin kantitatif analizlerinde AAS tekniği ile kalibrasyon yöntemi kullanılmıştır.

Anahtar Kelimeler: Tere (Lepidium sativum), metal, atomik absorpsiyon spektrometre, su

References

• Akinyele, I.O., Shokunbi, O.S. (2015). Comparative analysis of dry ashing and wet digestion methods for the determination of trace and heavy metals in food samples. Food Chemistry 173: 682–684.
• Amalraj, A., Pius, A. (2015). Bioavailability of calcium and its absorption inhibitors in raw and cooked green leafy vegetables commonly consumed in India – An in vitro study. Food Chemistry 170:430–436.
• Aydın, M. (2011). Metallerle etkileştirilen tere bitkisinde (lepidium sativum) bazi enzim aktivitelerinin incelenmesi. Yüksek lisans tezi, Sakarya Üniversitesi Fen Bilimleri Enstitüsü, Sakarya.
• Bradberry, S.M. (2016). Metals (cobalt, copper, lead, mercury). Medicine 44: 182-184.
• Dannehl, D., Huyskens-Keil, S., Wendorf, D., Ulrichs, C., Schmidt, U. (2012). Influence of intermittent-direct-electric-current (IDC) on phytochemical compounds in garden cress during growth. Food Chemistry 131: 239–246.
• Gill, S.S., Khana, N.A., Tutejab, N. (2012). Cadmium at high dose perturbs growth, photosynthesis and nitrogen metabolism while at low dose it up regulates sulfur assimilation and antioxidant machinery in garden cress (Lepidium sativum L.). Plant Science 182: 112– 120.
• Gouda, A.A. (2014). Cloud point extraction, preconcentration and spectrophotometric determination of trace amount of manganese(II) in water and food samples. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 131:138–144.
• Hajar, E.W.I., Sulaiman, A.Z.B., Sakinah, A.M.M. (2014). Assessment of heavy metals tolerance in leaves, stems and flowers of Stevia rebaudiana plant. Procedia Environmental Sciences 20: 386 – 393.
• http://www.google.com.tr/maps, son erişim tarihi:19.07.2016.
• Jarczewska, M., Górski,L., Malinowska, E.(2016). Application of DNA aptamers as sensing layers for electrochemicaldetection of potassium ions. Sensors and Actuators B 226: 37–43.
• Khan, S., Aijun, L., Zhang, S., Huc, Q., Zhua, Y-G. (2008). Accumulation of polycyclic aromatic hydrocarbons and heavy metals in lettuce grown in the soils contaminated with long-term wastewater irrigation. Journal of Hazardous Materials 152: 506–515.
• Leao, D.J., Junior, M.M.S., Brandao, G.C., Ferreira, S.L.C. (2016). Simultaneous determination of cadmium, iron and tin in canned foods using high-resolution continuum source graphite furnace atomic absorption spectrometry. Talanta 153: 45–50.
• Maratta, A., Vázquez, S., López, A., Augusto, M., Pacheco, P.H. (2016). Lead preconcentration by solid phase extraction using oxidized carbon xerogel and spectrophotometric determination with dithizone. Microchemical Journal 128: 166–171.
• Sadeghi, O., Tavassoli, N., Amini, M.M., Ebrahimzadeh, H., Daei, N. (2011). Pyridine-functionalized mesoporous silica as an adsorbent material for the determination of nickel and lead in vegetables grown in close proximity by electrothermal atomic adsorption spectroscopy. Food Chemistry 127: 364–368.
• Santos, J., Oliva-Teles, M.T., Delerue-Matos, C., Oliveira, M.B.P.P. (2014). Multi-elemental analysis of ready-to-eat ‘baby leaf’ vegetables using microwave digestion and high-resolution continuum source atomic absorption spectrometry. Food Chemistry 151: 311–316.
• Shokrollahi, A., Hemmatidoust, K., Zarghampour, F. (2015). Determination of magnesium by the solution scanometric method ina coloured titan yellow magnesium hydroxide complex form. Journal of Taibah University for Science 10: 161–167.
• Tüzen, M., Sahiner, S., Hazer, B. (2016). Solid phase extraction of lead, cadmium and zinc on biodegradable polyhydroxybutyrate diethanol amine (PHB-DEA) polymer and their determination in water and food samples. Food Chemistry 210: 115–120.
• Umesha, S.S., Naidu, K.A. (2012). Vegetable oil blends with a-linolenic acid rich Garden cress oil modulate lipid metabolism in experimental rats. Food Chemistry 135: 2845–2851.
• Üzen, N. (2014). Fiziksel olarak aritilmiş evsel atik sularin pamuk (Gossypium Hirsutum l.) verim ve kalitesi ile toprak kirliliğine etkisi. Doktora tezi, Çukurova Üniversitesi Fen Bilimleri Enstitüsü, Adana.
• Zhang, J., Chen, S., Kim, J., Cheng, S. (2016). Mercury flow analysis and reduction pathways for fluorescent lamps in mainland China. Journal of Cleaner Production 133: 451-458.