ÖZGÜN Ho(5-SSA), (5-SSA = 5-SÜLFOSALİSİLİK ASİT) KAFES YAPISININ SENTEZLENMESİ VE OPTİKSEL ÖZELLİKLERİ

Abstract

Birleştirici olarak adlandırılan organik yapıdaki ligandlar ile bağlayıcı olarak sınıflandırılan metal merkezlerin oluşturdukları mükemmel özgün mimariye sahip olan süngerimsi yapılar diğer bir deyişle Metal organik çerçeveler (MOÇ) üzerinde son yıllarda oldukça yoğun çalışmalar yapılmaktadır. Bu yoğunlaşmanın başlıca nedeni bu tür malzemelerin sensörler, gaz depolama, foto-katalizörler, organik ışık yayan diyotlar (OLED), güneş hücreleri (SC) ve lüminesans yayabilen aygıtlar gibi birçok teknolojik uygulama alanlarında kullanılabilme potansiyelinin yüksek olmasından ötürüdür. Metal organik çerçevelerin özellikleri, seçilen organik ligandlara ve metal iyonlarına bağlıdır. Dolayısıyla özgün olarak sentezlenebilen bu kristal malzemeler ile yeni araştırma ve teknoloji geliştirme (Ar-Te-Ge) alanları keşfedilebilmektedir. Bu çalışmada, Ho(III)-tabanlı metal-organik çerçevesi (Ho-MOÇ; [Ho(5-SSA)], 5-SSA = 5-Sülfosalisilik asit) hidrotermal metot ile sentezlenmiştir. Toz kristal X-ışını kırınımı, oda sıcaklığında katı-hal UV ve FT-IR spektroskopisi teknikleri yardımıyla yapısal karakterizasyonu yapılmıştır. Buna ek olarak, oda sıcaklığında görünür ve yakın kızıl ötesi (NIR) bölgede katı hal fotolüminesans ölçümleri alınmış ve 5-SSA ligandından Ho+3 iyonuna olan enerji transfer mekanizması detaylı bir şekilde incelenmiştir.  UV ışınım altında (349 nm’de), 5-SSA ligandı geniş bir lacivert renginde yayılım sergilerken, Ho-MOÇ kompleksi UV-Görünür ve NIR bölgesinde Ho+3 iyonunun çeşitli karakteristik emisyonlarını sergilemiştir. Mükemmel ışıldama performansları, bu bileşiği yüksek verimli ışınım veren malzemeler için çok iyi bir aday haline getirmektedir. 

Keywords

• Lüminesans,Metal-Organik Çerçeveler,Holmiyum

SYNTHESIS AND OPTICAL PROPERTIES OF THE NOVEL Ho(5-SSA), (5-SSA = 5-SULFOSALICYLIC ACID) CAGE STRUCTURE

Abstract

In recent years, intensive studies have been made on metal-organic frameworks (MOFs) which is kind of spongy structures having excellent original architectures formed by ligands in organic forms and metal centers classified as binders. The main reason for this condensation is due to the great huge potential for such materials to be used in many technological application areas such as sensors, gas storage, photo-catalysis, organic light emitting diodes (OLEDs), solar cells (SCs) and luminescent emitting devices. The properties of the metal-organic frameworks depend on the selected organic ligands and metal ions. Therefore, new research and technology development (R-T-G) fields can be discovered with these materials that can be originally synthesized. In this work, Ho(III)-based metal-organic framework (Ho-MOF; [Ho(5-SSA)], 5-SSA = 5-sulfosalicylic acid) was synthesized by hydrothermal method. The structural characterization has been made by powder X-ray diffraction, a room temperature solid-state UV and FT-IR spectroscopy. In addition, the solid-state photoluminescence measurements have been taken at room temperature in the UV-visible and near-infrared region (NIR) and the energy transfer mechanism from 5-SSA ligand to the Ho+3 ion is investigated in detail. Under the excitation of UV light (at 349 nm), 5-SSA ligand exhibited a broad navy-blue emission while its Ho-MOF complex exhibited several characteristic emissions of the Ho+3 ion in the UV-Visible and NIR region. The excellent luminescent performances make this compound very good candidate for efficient luminescence materials.

Keywords

• Luminescence,Metal-Organic Frameworks,Holmium

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