ÖZGÜN Ho(5-SSA), (5-SSA = 5-SÜLFOSALİSİLİK ASİT) KAFES YAPISININ SENTEZLENMESİ VE OPTİKSEL ÖZELLİKLERİ

Year 2018, , 116 - 122, 27.06.2018

Adem Dönmez

https://doi.org/10.22531/muglajsci.423816

Cited By: 2

Abstract

Birleştirici olarak
adlandırılan organik yapıdaki ligandlar ile bağlayıcı olarak sınıflandırılan
metal merkezlerin oluşturdukları mükemmel özgün mimariye sahip olan süngerimsi
yapılar diğer bir deyişle Metal organik çerçeveler (MOÇ) üzerinde son yıllarda
oldukça yoğun çalışmalar yapılmaktadır. Bu yoğunlaşmanın başlıca nedeni bu tür
malzemelerin sensörler, gaz depolama, foto-katalizörler, organik ışık yayan
diyotlar (OLED), güneş hücreleri (SC) ve lüminesans yayabilen aygıtlar gibi
birçok teknolojik uygulama alanlarında kullanılabilme potansiyelinin yüksek
olmasından ötürüdür. Metal organik çerçevelerin özellikleri, seçilen organik
ligandlara ve metal iyonlarına bağlıdır. Dolayısıyla özgün olarak
sentezlenebilen bu kristal malzemeler ile yeni araştırma ve teknoloji
geliştirme (Ar-Te-Ge) alanları keşfedilebilmektedir. Bu çalışmada,
Ho(III)-tabanlı metal-organik çerçevesi (Ho-MOÇ; [Ho(5-SSA)], 5-SSA =
5-Sülfosalisilik asit) hidrotermal metot ile sentezlenmiştir. Toz kristal
X-ışını kırınımı, oda sıcaklığında katı-hal UV ve FT-IR spektroskopisi
teknikleri yardımıyla yapısal karakterizasyonu yapılmıştır. Buna ek olarak, oda
sıcaklığında görünür ve yakın kızıl ötesi (NIR) bölgede katı hal fotolüminesans
ölçümleri alınmış ve 5-SSA ligandından Ho+3 iyonuna olan enerji transfer
mekanizması detaylı bir şekilde incelenmiştir. 
UV ışınım altında
(349 nm’de), 5-SSA ligandı geniş bir lacivert renginde yayılım sergilerken,
Ho-MOÇ kompleksi UV-Görünür ve NIR bölgesinde Ho+3 iyonunun çeşitli
karakteristik emisyonlarını sergilemiştir. Mükemmel ışıldama performansları, bu
bileşiği yüksek verimli ışınım veren malzemeler için çok iyi bir aday haline
getirmektedir. 

Keywords

Lüminesans, Metal-Organik Çerçeveler, Holmiyum

SYNTHESIS AND OPTICAL PROPERTIES OF THE NOVEL Ho(5-SSA), (5-SSA = 5-SULFOSALICYLIC ACID) CAGE STRUCTURE

Abstract

In recent years,
intensive studies have been made on metal-organic
frameworks (MOFs) which is kind of spongy structures having excellent original
architectures formed by ligands in organic forms and metal centers classified
as binders. The main reason for this condensation is due to the great huge potential for such materials to be
used in many technological application areas such as sensors, gas storage,
photo-catalysis, organic light emitting diodes (OLEDs), solar cells (SCs) and
luminescent emitting devices. The properties of the metal-organic frameworks
depend on the selected organic ligands and metal ions. Therefore, new research
and technology development (R-T-G) fields can be discovered with these
materials that can be originally synthesized. In this work, Ho(III)-based metal-organic framework (Ho-MOF; [Ho(5-SSA)],
5-SSA = 5-sulfosalicylic acid) was synthesized by hydrothermal method. The
structural characterization has been made
by powder X-ray diffraction, a room
temperature solid-state UV and FT-IR spectroscopy.
In addition, the solid-state
photoluminescence measurements have been taken at room temperature in the UV-visible and near-infrared
region (NIR) and the energy transfer mechanism from 5-SSA ligand to the Ho+3
ion is investigated in detail. Under the excitation of UV light (at 349 nm), 5-SSA ligand exhibited a
broad navy-blue emission while its Ho-MOF complex exhibited several
characteristic emissions of the Ho+3 ion in the UV-Visible and NIR
region. The excellent luminescent performances make this compound very good
candidate for efficient luminescence materials.

Keywords

Luminescence, Metal-Organic Frameworks, Holmium

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