Arum rupicola Boiss. var. rupicola (Araceae)’dan distile edilen uçucu yağın GK/KS analizi

Abstract

Amaç: Arum rupicola Boiss. var. rupicola yöresel adıyla Dağ Sorsalının, halk ilacı olarak hemorroit, egzema, romatizma, ve özellikle kanser hastalıklarında kullanıldığı bilinmektedir. Bu nedenle aşırı toplanma sonucunda tehdit altındaki türler kategorisine dahil edilen bitkinin toprak üstü kısımlarının uçucu yağ bileşiminin incelenmesi amaçlanmıştır. Yöntem: Arum rupicola Boiss. var. rupicola’nın topraküstü kısımları Antalya (Kaş)’nın, Palamut köyünden toplanmış ve uçucu yağı Clevenger apareyi kullanılarak su distilasyonu yöntemi ile elde edilmiştir. Elde edilen uçucu yağın bileşimi eş zamanlı olarak gaz Kromatografisi (GK) ve gaz kromatografisi/ kütle spektrometresi (GK/KS) sistemleri ile tayin edildi. Bulgular: Ana bileşik (E)-geranil aseton (%15) olurken, hekzahidrofarnesil aseton (%9.2), nonanal (%6.8), heptakosan (%6.5), farnesil aseton (%5.0), trikosan (%4.9), ve 2-dodekanon (%3.8) diğer önemli bileşikler olarak tespit edilmiştir. Sonuç: A. rupicola var. rupicola’ nın uçucu yağ içeriğinde farnesil aseton (%5) ve hekzahidrofarnesil aseton (%9.2) varlığı yeni bir kayıttır. Taksonomik özellik olarak α-farnesen (%95) içeren tek tür Arum creticum dur. Bayraklı ve kokusuz bir tür olarak bilinen A. rupicola var. rupicola’da da farnesil aseton ve hekzahidrofarnesil aseton bulunmaktadır.

Keywords

• Arum rupicola var. rupicola
• Araceae
• Uçucu bileşikler
• (E)-geranil aseton
• GK/KS

GC/MS Analysis of Essential oil distilled from Arum rupicola Boiss. var. rupicola (Araceae)

Abstract

Aim: Arum rupicola Boiss. var. rupicola with a vernacular name of Dağ Sorsalı, are used etnobotanically for hemorroid, eczema, rheumatism, and cancer. Essential oil combination of A. rupicola var. rupicola, under the lower risk (lc) threatened category because of the excess gathering was investigated. Methods: The above ground samples of Arum rupicola Boiss. var. rupicola was collected from Palamut province of Antalya (Kaş) and essential oil was taken by hydrodistillation method with Clevenger apparatus. The essential oil composition was analysed by Gas chromatography (GC) and Gas chromatography/Mass Spectrometry (GC/MS) systems simultaneously. Results: As a result of, (E)-geranyl acetone (15%) was the main compound while hexahydrofarnesyl acetone (9.2%), nonanal (6.8%), heptacosan (6.5%), farnesyl acetone (5.0%), tricosan (4.9%), ve 2-dodecanone (3.8%) followed. Conclusion: Farnesyl acetone (5%) and hexahydrofarnesyl acetone (9.2%) sesquiterpenes were new records for A. rupicola var. rupicola volatile oil content. The only species is Arum creticum consisting α-farnesene (95%) as its taxonomical feature. A. rupicola var. rupicola has farnesyl acetone and hexahydrofarnesyl aceton being known a flagy and odourless species.

Keywords

• A. rupicola var. rupicola
• Araceae
• Essential oil
• (E)-geranyl aseton
• GC/MS

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