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Conducting Polymer Films on Zn Deposited Carbon Electrode

Year 2023, , 129 - 139, 07.08.2023
https://doi.org/10.28978/nesciences.1342013

Abstract

Zn plating on carbon steel (CS) was achieved applying current of 4 mA with galvanostatic technique in acidic medium. Zn particles had homogenous, smooth with spherical structure. It was shown that the Zn particles exhibited active behavior on CS substrate. Poly(aniline), poly(pyrrole), poly(N-methylpyrrole) and poly(o-anisidine) homopolymer films were obtained on CS/Zn electrode. Evaluation of anticorrosion performance of these homopolymer coatings in 3.5 % NaCl solution was investigated by using AC impedance spectroscopy (EIS) technique, anodic polarization and the Eocp-time curves. Homopolymer films exhibited significant physical barrier behavior on Zn plated carbon steel, in longer exposure time.

References

  • Bagherzadeh, M., Haddadi H., Iranpour M. (2016) Electrochemical evaluation and surface study of magnetite/PANI nanocomposite for carbon steel protection in 3.5 % NaCl. Progress in Organic Coatings, 101, 149-160. https://doi.org/10.1016/j.porgcoat.2016.08.011.
  • Bajat, J.B., Maksimovic, M.D., Miskovic-Stankovic, V.B., Zec, S. (2001). Electrodeposition and characterization of Zn-Ni alloys as sublayers for epoxy coating deposition. Journal of Applied Electrochemistry, 31, 355-361. https://doi.org/10.1023/A:1017580019551.
  • Camalet, J. L., Lacroix, J. C., Aeiyach, S., Chane-Ching, K., & Lacaze, P. C. (1998). Electrosynthesis of adherent polyaniline films on iron and mild steel in aqueous oxalic acid medium. Synthetic Metals, 93(2), 133-142. https://doi.org/10.1016/S0379-6779(97)04099-X.
  • Guenbour, A., Kacemi A., Benbachir, A. (2000). Corrosion protection of copper by polyaminophenol films. Progress in Organic Coatings, 39, 151-155. https://doi.org/10.1016/S0300-9440(00)00141-7.
  • Kilinççeker, G., & Galip, H. (2008). The effects of acetate ions (CH3COO−) on electrochemical behavior of copper in chloride solutions. Materials Chemistry and Physics, 110(2-3), 380-386. https://doi.org/10.1016/j.matchemphys.2008.02.026
  • Kilinççeker, G., & Demir, H. (2013). The inhibition effects of methionine on corrosion behavior of copper in 3.5% NaCl solution at pH= 8.5. Protection of Metals and Physical Chemistry of Surfaces, 49, 788-797. https://doi.org/10.1134/S2070205113060221.
  • Kim, Y., Teshima, K., & Kobayashi, N. (2000). Improvement of reversible photoelectrochromic reaction of polyaniline in polyelectrolyte composite film with the dichloroethane solution system. Electrochimica Acta, 45(8-9), 1549-1553. https://doi.org/10.1016/S0013-4686(99)00373-4.
  • Mansfeld, F. (1995). Use of electrochemical impedance spectroscopy for the study of corrosion protection by polymer coatings. Journal of Applied Electrochemistry, 25(3), 187-202. https://doi.org/10.1007/BF00262955.
  • Martins, J. I., Reis, T. C., Bazzaoui, M., Bazzaoui, E. A., & Martins, L. (2004). Polypyrrole coatings as a treatment for zinc-coated steel surfaces against corrosion. Corrosion Science, 46(10), 2361-2381. https://doi.org/10.1016/j.corsci.2004.02.006.
  • Ozyılmaz, A. T., Kardaş, G., & Erbil, M. (2005). The corrosion performance of polyaniline on nickel plated mild steel. Applied Surface Science, 242(1-2), 97-106. https://doi.org/10.1016/j.apsusc.2004.08.002.
  • Ozyilmaz, A.T. (2006). The corrosion performance of polyaniline film modified on nickel plated copper in aqueous p-toluenesulfonic acid solution. Surface & Coatings Technology, 200, 3918-3925. https://doi.org/10.1016/j.surfcoat.2005.01.058.
  • Ozyilmaz, A.T., Akdag, A. (2011). Polyaniline, poly (N-methylaniline) and poly (aniline-co-N-methylaniline) coatings on stainless steel. Transactions of the IMF, 89(4), 215-224. https://doi.org/10.1179/174591911X13077162170188.
  • Ozyilmaz, A.T., Akdag, A. (2013a). Corrosion protection provided by homo- and copolymer films synthesized in various oxalic and sulphamic acid electrolyte mixtures. Transactions of the IMF., 91 (1), 44-51. https://doi.org/10.1179/0020296712Z.00000000063.
  • Ozyilmaz, A. T., Akdag, A., Karahan, I. H., & Ozyilmaz, G. (2013). The influence of polyaniline (PANI) coating on corrosion behaviour of zinc–cobalt coated carbon steel electrode. Progress in Organic Coatings, 76(6), 993-997. https://doi.org/10.1016/j.porgcoat.2012.10.020.
  • Ozyilmaz, G., Özyılmaz, A.T., Ağçam, S. (2018). Using Response Surface Methodology for Amperometric Glucose Biosensor Construction. Natural and Engineering Sciences, 3 (1), 1-15. https://doi.org/10.28978/nesciences.379311.
  • Shah, K., & Iroh, J. (2002). Electrochemical synthesis and corrosion behavior of poly (N-ethyl aniline) coatings on Al-2024 alloy. Synthetic Metals, 132(1), 35-41. https://doi.org/10.1016/S0379-6779(02)00213-8.
  • Sohi, M. H., & Jalali, M. (2003). Study of the corrosion properties of zinc–nickel alloy electrodeposits before and after chromating. Journal of Materials Processing Technology, 138(1-3), 63-66. https://doi.org/10.1016/S0924-0136(03)00050-5.
  • Yalçınkaya, S., & Çakmak, D. (2021). Immobilization of CoII‐(N, N′‐bis (salicylidene)‐2‐aminobenzylamine) on poly (pyrrole‐co‐o‐anisidine)/chitosan composite films: Application to electrocatalytic oxidation of catechol. Electroanalysis, 33(3), 755-765. https://doi.org/10.1002/elan.202060243.
  • Walter, G. W. (1986). A review of impedance plot methods used for corrosion performance analysis of painted metals. Corrosion Science, 26(9), 681-703. https://doi.org/10.1016/0010-938X(86)90033-8.
Year 2023, , 129 - 139, 07.08.2023
https://doi.org/10.28978/nesciences.1342013

Abstract

References

  • Bagherzadeh, M., Haddadi H., Iranpour M. (2016) Electrochemical evaluation and surface study of magnetite/PANI nanocomposite for carbon steel protection in 3.5 % NaCl. Progress in Organic Coatings, 101, 149-160. https://doi.org/10.1016/j.porgcoat.2016.08.011.
  • Bajat, J.B., Maksimovic, M.D., Miskovic-Stankovic, V.B., Zec, S. (2001). Electrodeposition and characterization of Zn-Ni alloys as sublayers for epoxy coating deposition. Journal of Applied Electrochemistry, 31, 355-361. https://doi.org/10.1023/A:1017580019551.
  • Camalet, J. L., Lacroix, J. C., Aeiyach, S., Chane-Ching, K., & Lacaze, P. C. (1998). Electrosynthesis of adherent polyaniline films on iron and mild steel in aqueous oxalic acid medium. Synthetic Metals, 93(2), 133-142. https://doi.org/10.1016/S0379-6779(97)04099-X.
  • Guenbour, A., Kacemi A., Benbachir, A. (2000). Corrosion protection of copper by polyaminophenol films. Progress in Organic Coatings, 39, 151-155. https://doi.org/10.1016/S0300-9440(00)00141-7.
  • Kilinççeker, G., & Galip, H. (2008). The effects of acetate ions (CH3COO−) on electrochemical behavior of copper in chloride solutions. Materials Chemistry and Physics, 110(2-3), 380-386. https://doi.org/10.1016/j.matchemphys.2008.02.026
  • Kilinççeker, G., & Demir, H. (2013). The inhibition effects of methionine on corrosion behavior of copper in 3.5% NaCl solution at pH= 8.5. Protection of Metals and Physical Chemistry of Surfaces, 49, 788-797. https://doi.org/10.1134/S2070205113060221.
  • Kim, Y., Teshima, K., & Kobayashi, N. (2000). Improvement of reversible photoelectrochromic reaction of polyaniline in polyelectrolyte composite film with the dichloroethane solution system. Electrochimica Acta, 45(8-9), 1549-1553. https://doi.org/10.1016/S0013-4686(99)00373-4.
  • Mansfeld, F. (1995). Use of electrochemical impedance spectroscopy for the study of corrosion protection by polymer coatings. Journal of Applied Electrochemistry, 25(3), 187-202. https://doi.org/10.1007/BF00262955.
  • Martins, J. I., Reis, T. C., Bazzaoui, M., Bazzaoui, E. A., & Martins, L. (2004). Polypyrrole coatings as a treatment for zinc-coated steel surfaces against corrosion. Corrosion Science, 46(10), 2361-2381. https://doi.org/10.1016/j.corsci.2004.02.006.
  • Ozyılmaz, A. T., Kardaş, G., & Erbil, M. (2005). The corrosion performance of polyaniline on nickel plated mild steel. Applied Surface Science, 242(1-2), 97-106. https://doi.org/10.1016/j.apsusc.2004.08.002.
  • Ozyilmaz, A.T. (2006). The corrosion performance of polyaniline film modified on nickel plated copper in aqueous p-toluenesulfonic acid solution. Surface & Coatings Technology, 200, 3918-3925. https://doi.org/10.1016/j.surfcoat.2005.01.058.
  • Ozyilmaz, A.T., Akdag, A. (2011). Polyaniline, poly (N-methylaniline) and poly (aniline-co-N-methylaniline) coatings on stainless steel. Transactions of the IMF, 89(4), 215-224. https://doi.org/10.1179/174591911X13077162170188.
  • Ozyilmaz, A.T., Akdag, A. (2013a). Corrosion protection provided by homo- and copolymer films synthesized in various oxalic and sulphamic acid electrolyte mixtures. Transactions of the IMF., 91 (1), 44-51. https://doi.org/10.1179/0020296712Z.00000000063.
  • Ozyilmaz, A. T., Akdag, A., Karahan, I. H., & Ozyilmaz, G. (2013). The influence of polyaniline (PANI) coating on corrosion behaviour of zinc–cobalt coated carbon steel electrode. Progress in Organic Coatings, 76(6), 993-997. https://doi.org/10.1016/j.porgcoat.2012.10.020.
  • Ozyilmaz, G., Özyılmaz, A.T., Ağçam, S. (2018). Using Response Surface Methodology for Amperometric Glucose Biosensor Construction. Natural and Engineering Sciences, 3 (1), 1-15. https://doi.org/10.28978/nesciences.379311.
  • Shah, K., & Iroh, J. (2002). Electrochemical synthesis and corrosion behavior of poly (N-ethyl aniline) coatings on Al-2024 alloy. Synthetic Metals, 132(1), 35-41. https://doi.org/10.1016/S0379-6779(02)00213-8.
  • Sohi, M. H., & Jalali, M. (2003). Study of the corrosion properties of zinc–nickel alloy electrodeposits before and after chromating. Journal of Materials Processing Technology, 138(1-3), 63-66. https://doi.org/10.1016/S0924-0136(03)00050-5.
  • Yalçınkaya, S., & Çakmak, D. (2021). Immobilization of CoII‐(N, N′‐bis (salicylidene)‐2‐aminobenzylamine) on poly (pyrrole‐co‐o‐anisidine)/chitosan composite films: Application to electrocatalytic oxidation of catechol. Electroanalysis, 33(3), 755-765. https://doi.org/10.1002/elan.202060243.
  • Walter, G. W. (1986). A review of impedance plot methods used for corrosion performance analysis of painted metals. Corrosion Science, 26(9), 681-703. https://doi.org/10.1016/0010-938X(86)90033-8.
There are 19 citations in total.

Details

Primary Language English
Subjects Classical Physics (Other), Material Production Technologies, Industrial Engineering
Journal Section Articles
Authors

Ali Tuncay Ozyilmaz This is me 0000-0002-3657-8117

Publication Date August 7, 2023
Submission Date January 5, 2023
Published in Issue Year 2023

Cite

APA Ozyilmaz, A. T. (2023). Conducting Polymer Films on Zn Deposited Carbon Electrode. Natural and Engineering Sciences, 8(2), 129-139. https://doi.org/10.28978/nesciences.1342013

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