BibTex RIS Cite

Comparison of GC Profiles of Achillea crithmifolia and Origanum heracleoticum Essential Oils and Headspace Volatiles

Year 2014, Volume: 1 Issue: 1, 60 - 65, 03.12.2014

Abstract

In the analysis of the secondary metabolites of plants it would be preferable if the applied method is fast and  the  generation  of  artifacts  is  minimal. Obtaining  essential  oils  (EO)  by hydrodistillation  or  steam distillation is time-consuming (the duration of the distillation is usually two to three hours) and possibility of the formation of artifacts is more probable due relatively high temperature in aqueous solution. Also, the most volatile components could be lost during distillation, essential oil extraction and storage. Traditional head space (HS) method enables the analysis of volatile compounds obtained after the establishment of vapor-liquid equilibrium within a closed container.  Time of analysis is much shorter (10-

20 minutes) than for hydrodistillation, one can work at lower temperatures with or without solvent, and without loss of highly volatile components. Further, an advantage of HS technique is in the fact that it requires less of the plant material (masses lower than one gram in head space in comparison to usually more than 100 g for obtaining essential oil). Although head space GC is widely used (Buchbauer et al. 1993, Vuorela  et al. 1989, Rouseff & Cadwallader, 2001, Zhu et al.  2005, Serban et al.  2012) limited number of articles is focused on analysis of the head space volatile components obtained directly from the plant material under static conditions (Abu-Lafi et al. 2007, Simonovi? et al. 2014). Continuing a previous examination  (Simonovi?  et  al.  2014)  we  considered  that  it  is  of  interest  to  compare  EO  and  HSV composition for more samples in order to determine their compatibility. For this purpose, the analysis of essential oils and head space volatiles of Achillea crithmifolia Waldst. & Kit.   and  Origanum heracleoticum L. were done.

References

  • Adams, R. P. (2007). Identification of essential oil components by gas chromatography/mass spectroscopy. Allured Publishing Corporation: Illinois.
  • Buchbauer, G., Jirovetz, L., Wasicky, M., Nikiforov, A. (1993). Headspace and essential oil analysis of apple flowers, Journal of Agricultural and Food Chemistry, 41, 116–118.
  • National Institute of Standards and Technology, NIST Chemistry WebBook, Nist Standard Reference database Website. 2005. [http://webbook.nist.gov/chemistry/]; accesed December 2013.
  • Rouseff, R. L. & Cadwallader, K. (2001). Headspace Techniques for Food Aroma Volatiles: An Overview. In R. L. Rouseff. & Cadwallader K (Eds.), Headspace Analysis of Foods and Flavours: Theory and Practice, Vol. 488 (pp. 1-8). Kluwer Academic/Plenum Publishers, New York.
  • Serban, E., Socaci, S., Tofana, M., Maier, S., Bojita, M. (2012). Advantages of “headspace” technique for GC/MS analisys of essential oils. Farmacia, 60, 249-256.
  • Simonović, S., Stankov-Jovanović, V., Mitić, V., Ilić, M., Petrović, G., Stojanović, G. 82014). Chemical Composition of Angelica pancicii Essential Oil Determined by Liquid and Headspace GC-MS Techniques. Nat ural Product Communication, 9, 271-272.
  • Stein, S. E. National Institute of Standards and Technology (NIST) Mass Spectral Database and Software, Version 3.02. 1990.
  • Van Den Dool, H., & Kratz, P. D. (1963). A generalization of the retention index system including linear temperature programmed gas-liquid partition chromatography. Journal of Chromatography A, 11, 463– 471.
  • Vuorela, H., Pohjola, J., Krause, C., Hiltunen, R. (1989). Application of headspace gas chromatography in essential oil analysis. Part IX. Selective loss of terpene compounds during hydrodistillation. Flavour and Fragrance Journal, 4,117–120.
  • Zhu, J. Y. & Chai, X. S. (2005). Some Recent Developments in Headspace Gas Chromatography. Current Analytical Chemistry, 1, 79-83.
Year 2014, Volume: 1 Issue: 1, 60 - 65, 03.12.2014

Abstract

References

  • Adams, R. P. (2007). Identification of essential oil components by gas chromatography/mass spectroscopy. Allured Publishing Corporation: Illinois.
  • Buchbauer, G., Jirovetz, L., Wasicky, M., Nikiforov, A. (1993). Headspace and essential oil analysis of apple flowers, Journal of Agricultural and Food Chemistry, 41, 116–118.
  • National Institute of Standards and Technology, NIST Chemistry WebBook, Nist Standard Reference database Website. 2005. [http://webbook.nist.gov/chemistry/]; accesed December 2013.
  • Rouseff, R. L. & Cadwallader, K. (2001). Headspace Techniques for Food Aroma Volatiles: An Overview. In R. L. Rouseff. & Cadwallader K (Eds.), Headspace Analysis of Foods and Flavours: Theory and Practice, Vol. 488 (pp. 1-8). Kluwer Academic/Plenum Publishers, New York.
  • Serban, E., Socaci, S., Tofana, M., Maier, S., Bojita, M. (2012). Advantages of “headspace” technique for GC/MS analisys of essential oils. Farmacia, 60, 249-256.
  • Simonović, S., Stankov-Jovanović, V., Mitić, V., Ilić, M., Petrović, G., Stojanović, G. 82014). Chemical Composition of Angelica pancicii Essential Oil Determined by Liquid and Headspace GC-MS Techniques. Nat ural Product Communication, 9, 271-272.
  • Stein, S. E. National Institute of Standards and Technology (NIST) Mass Spectral Database and Software, Version 3.02. 1990.
  • Van Den Dool, H., & Kratz, P. D. (1963). A generalization of the retention index system including linear temperature programmed gas-liquid partition chromatography. Journal of Chromatography A, 11, 463– 471.
  • Vuorela, H., Pohjola, J., Krause, C., Hiltunen, R. (1989). Application of headspace gas chromatography in essential oil analysis. Part IX. Selective loss of terpene compounds during hydrodistillation. Flavour and Fragrance Journal, 4,117–120.
  • Zhu, J. Y. & Chai, X. S. (2005). Some Recent Developments in Headspace Gas Chromatography. Current Analytical Chemistry, 1, 79-83.
There are 10 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

Gordana Stojanovi? This is me

Olga Jovanovi? This is me

Goran Petrovi? This is me

Violeta Miti? This is me

Vesna Jovanovi? This is me

Publication Date December 3, 2014
Published in Issue Year 2014 Volume: 1 Issue: 1

Cite

APA Stojanovi?, G., Jovanovi?, O., Petrovi?, G., Miti?, V., et al. (2014). Comparison of GC Profiles of Achillea crithmifolia and Origanum heracleoticum Essential Oils and Headspace Volatiles. Natural Volatiles and Essential Oils, 1(1), 60-65.