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Antique Lavender Essential Oil from 1945, its chemical composition and enantiomeric distribution

Year 2016, Volume: 3 Issue: 2, 20 - 25, 01.08.2016

Abstract

Properly stored lavender from 1945 was collected in French market and Gas Chromatography and Mass Spectrometry (GCMS) analysis was carried out to see possible chemical transformation and chemical composition. Total of 102 peaks (100% components) were identified, out of them 10 were oxidized minor components (total 0.41%). The lavender essential oil was dominated by the linalool (40.8%), terpinen-4-ol (9.9%), α-terpineol (3.5%), linalyl acetate (16.4%), lavandulyl acetate (3.8%), and trans-caryophyllene (2.2%). Enantiomeric distribution of major monoterpenoids were also measured.

References

  • Adams, R. P. (2007). Identification of Essential Oil Components by Gas Chromatography. Illinois: Allured.
  • Baser, K. H., Özek, T., & Konakchiev, A. (2005). Enantiomeric Distribution of Linalool, Linalyl Acetate and Camphor in Bulgarian Lavender Oil. Journal of Essential Oil Research, 17(2), 135-136.
  • Chemat, F., Lucchesi, M., Smadja, J., Favretto, L., Colnaghi, G., & Visinoni, F. (2006). Microwave accelerated steam distillation of essential oil from lavender: A rapid, clean and environmentally friendly approach. Analytica Chimica Acta, 555(1), 157-160.
  • Guenther, E. (1948). The essential oils Vol. I: History origin in plants production analysis. Newyork: Van Nostrand.
  • Hagvall, L., Sköld, M., Bråred-Christensson, J., Börje, A., & Karlberg, A. (2008). Lavender oil lacks natural protection against autoxidation, forming strong contact allergens on air exposure. Contact Dermatitis, 59(3), 143-150.
  • Hădărugă, D. I., Hădărugă, N. G., Costescu, C. I., David, I., & Gruia, A. T. (2014). Thermal and oxidative stability of the Ocimum basilicum L. essential oil/β-cyclodextrin supramolecular system. Beilstein Journal of Organic Chemistry Beilstein J. Org. Chem., 10, 2809-2820.
  • International Standard ISO 3515 (2002), Oil of lavender (Lavendula angustifolia Mill.)
  • Lawrence, B. M. (2012). Essential Oils 2008-2011. Carol Stream, IL: Allured.
  • Letizia, C., Cocchiara, J., Lalko, J., & Api, A. (2003). Fragrance material review on linalyl acetate. Food and Chemical Toxicology, 41(7), 965-976.
  • Letizia, C., Cocchiara, J., Lalko, J., & Api, A. (2003). Fragrance material review on linalool. Food and Chemical Toxicology, 41(7), 943-964.
  • Misharina, T., Polshkov, A. N., Ruchkina, E. L., & Medvedeva, I. B. (2003). Changes in the composition of the essential oil of Marjoram during storage. Applied Biochemistry and Microbiology, 39(3), 311-316.
  • Nilsson, J., Carlberg, J., Abrahamsson, P., Hulthe, G., Persson, B., & Karlberg, A. (2008). Evaluation of ionization techniques for mass spectrometric detection of contact allergenic hydroperoxides formed by autoxidation of fragrance terpenes. Rapid Communications in Mass Spectrometry Rapid Commun. Mass Spectrom., 22(22), 3593-3598.
  • Pavela, R. (2006). Insecticidal Activity of Essential Oils Against Cabbage Aphid Brevicoryne brassicae. Journal of Essential Oil Bearing Plants, 9(2), 99-106.
  • Satyal, P., & Pappas, R. S. (2016). First Reporting on the Chemistry and Biological Activity of a Novel Boswellia Chemotype: The Methoxy Alkane Frankincense. Global Journal of Frontier Science Research B, 16, 1-9.
  • Sköld, M., Borje, A., Matura, M., & Karlberg, A. (2002). Studies on the autoxidation and sensitizing capacity of the fragrance chemical linalool, identifying a linalool hydroperoxide. Contact Dermatitis, 46(5), 267-272.
  • Sköld, M., Börje, A., Harambasic, E., & Karlberg, A. (2004). Contact Allergens Formed on Air Exposure of Linalool. Identification and Quantification of Primary and Secondary Oxidation Products and the Effect on Skin Sensitization. Chemical Research in Toxicology, 17(12), 1697-1705.
  • Sköld, M., Karlberg, A., Matura, M., & Börje, A. (2006). The fragrance chemical β-caryophyllene—air oxidation and skin sensitization. Food and Chemical Toxicology, 44(4), 538-545.
  • Sköld, M., Hagvall, L., & Karlberg, A. (2007). Autoxidation of linalyl acetate, the main component of lavender oil, creates potent contact allergens. Contact Dermatitis, 58(1), 9-14.
  • Tranchida, P. Q., Shellie, R. A., Purcaro, G., Conte, L. S., Dugo, P., Dugo, G., & Mondello, L. (2010). Analysis of Fresh and Aged Tea Tree Essential Oils By Using GCxGC-qMS. Journal of Chromatographic Science, 48(4), 262-266.
  • Turek, C., & Stintzing, F. C. (2013). Stability of essential oils: a review.Comprehensive Reviews in Food Science and Food Safety, 12(1), 40-5
Year 2016, Volume: 3 Issue: 2, 20 - 25, 01.08.2016

Abstract

References

  • Adams, R. P. (2007). Identification of Essential Oil Components by Gas Chromatography. Illinois: Allured.
  • Baser, K. H., Özek, T., & Konakchiev, A. (2005). Enantiomeric Distribution of Linalool, Linalyl Acetate and Camphor in Bulgarian Lavender Oil. Journal of Essential Oil Research, 17(2), 135-136.
  • Chemat, F., Lucchesi, M., Smadja, J., Favretto, L., Colnaghi, G., & Visinoni, F. (2006). Microwave accelerated steam distillation of essential oil from lavender: A rapid, clean and environmentally friendly approach. Analytica Chimica Acta, 555(1), 157-160.
  • Guenther, E. (1948). The essential oils Vol. I: History origin in plants production analysis. Newyork: Van Nostrand.
  • Hagvall, L., Sköld, M., Bråred-Christensson, J., Börje, A., & Karlberg, A. (2008). Lavender oil lacks natural protection against autoxidation, forming strong contact allergens on air exposure. Contact Dermatitis, 59(3), 143-150.
  • Hădărugă, D. I., Hădărugă, N. G., Costescu, C. I., David, I., & Gruia, A. T. (2014). Thermal and oxidative stability of the Ocimum basilicum L. essential oil/β-cyclodextrin supramolecular system. Beilstein Journal of Organic Chemistry Beilstein J. Org. Chem., 10, 2809-2820.
  • International Standard ISO 3515 (2002), Oil of lavender (Lavendula angustifolia Mill.)
  • Lawrence, B. M. (2012). Essential Oils 2008-2011. Carol Stream, IL: Allured.
  • Letizia, C., Cocchiara, J., Lalko, J., & Api, A. (2003). Fragrance material review on linalyl acetate. Food and Chemical Toxicology, 41(7), 965-976.
  • Letizia, C., Cocchiara, J., Lalko, J., & Api, A. (2003). Fragrance material review on linalool. Food and Chemical Toxicology, 41(7), 943-964.
  • Misharina, T., Polshkov, A. N., Ruchkina, E. L., & Medvedeva, I. B. (2003). Changes in the composition of the essential oil of Marjoram during storage. Applied Biochemistry and Microbiology, 39(3), 311-316.
  • Nilsson, J., Carlberg, J., Abrahamsson, P., Hulthe, G., Persson, B., & Karlberg, A. (2008). Evaluation of ionization techniques for mass spectrometric detection of contact allergenic hydroperoxides formed by autoxidation of fragrance terpenes. Rapid Communications in Mass Spectrometry Rapid Commun. Mass Spectrom., 22(22), 3593-3598.
  • Pavela, R. (2006). Insecticidal Activity of Essential Oils Against Cabbage Aphid Brevicoryne brassicae. Journal of Essential Oil Bearing Plants, 9(2), 99-106.
  • Satyal, P., & Pappas, R. S. (2016). First Reporting on the Chemistry and Biological Activity of a Novel Boswellia Chemotype: The Methoxy Alkane Frankincense. Global Journal of Frontier Science Research B, 16, 1-9.
  • Sköld, M., Borje, A., Matura, M., & Karlberg, A. (2002). Studies on the autoxidation and sensitizing capacity of the fragrance chemical linalool, identifying a linalool hydroperoxide. Contact Dermatitis, 46(5), 267-272.
  • Sköld, M., Börje, A., Harambasic, E., & Karlberg, A. (2004). Contact Allergens Formed on Air Exposure of Linalool. Identification and Quantification of Primary and Secondary Oxidation Products and the Effect on Skin Sensitization. Chemical Research in Toxicology, 17(12), 1697-1705.
  • Sköld, M., Karlberg, A., Matura, M., & Börje, A. (2006). The fragrance chemical β-caryophyllene—air oxidation and skin sensitization. Food and Chemical Toxicology, 44(4), 538-545.
  • Sköld, M., Hagvall, L., & Karlberg, A. (2007). Autoxidation of linalyl acetate, the main component of lavender oil, creates potent contact allergens. Contact Dermatitis, 58(1), 9-14.
  • Tranchida, P. Q., Shellie, R. A., Purcaro, G., Conte, L. S., Dugo, P., Dugo, G., & Mondello, L. (2010). Analysis of Fresh and Aged Tea Tree Essential Oils By Using GCxGC-qMS. Journal of Chromatographic Science, 48(4), 262-266.
  • Turek, C., & Stintzing, F. C. (2013). Stability of essential oils: a review.Comprehensive Reviews in Food Science and Food Safety, 12(1), 40-5
There are 20 citations in total.

Details

Journal Section Articles
Authors

Prabodh Satyal This is me

Robert S. Pappas This is me

Publication Date August 1, 2016
Published in Issue Year 2016 Volume: 3 Issue: 2

Cite

APA Satyal, P., & Pappas, R. S. (2016). Antique Lavender Essential Oil from 1945, its chemical composition and enantiomeric distribution. Natural Volatiles and Essential Oils, 3(2), 20-25.