Yumuşak Çeliğin Asidik Korozyonuna Bir Salisilaaldemin Schiff Bazının İnhibitör Etkisi

Aysel Yurt; Arzu Pınarbaşı

EN TR

The Effect Of A Salisilaldimine Schiff Base On The Acidic Corrosion Of Mild Steel

Abstract

The effect of a salicylaldimine Schiff base (1,4-Bis[2-(2-hydroxybenzyliden amino) phenoxy]butane) on the corrosion behaviour of mild steel in 0.1M HCl media were investigated by using potentiodynamic polarisation, linear polarisation, electrochemical impedance spectroscopy, electrochemical quartz crystal microbalance and SEM methods. Potentiodynamic polarisation measurements indicate that studied Schiff base was acting as cathodic type inhibitor. All electrochemical measurements show that inhibition efficiencies increase with increase in inhibitor concentration. This reveals that inhibitive action of inhibitor was mainly due to adsorption on mild steel surfaces. It was found that adsorption of these inhibitors follows Temkin adsorption isotherm. The results of SEM and EQCM measurements indicate that Schiff base is adsorbed on metal surface and metal is protected against corrosion.

Keywords

EQCM,EIS,Schiff base,inhibitor

References

[1] G.Y. Elewady, “Pyrimidine Derivatives as Corrosion Inhibitors for Carbon-Steel in 2M Hydrochloric Acid Solution”, Int.J.Electrochem. Sci., Vol.3, No.10, pp.1149, 2008.
[2] S.H. Sanad, A.A. Ismail, A.A El-Meligi, “Indole and its derivatives as corrosion inhibitors for C-steel during pickling”, J. Mater. Sci. Technol.,Vol.16, No.3, pp.291-296, 2000.
[3] A. Yurt, A. Balaban, S. Üstün Kandemir, G. Bereket, B. Erk,, “Investigation on some Schiff bases as HCl corrosion inhibitors for carbon steel”, Mater. Chem. and Phys., Vol.85, No.2-3, pp. 420–426 , 2004.
[4] M. Ajmal, A. S. Mideen, M. A. Quraishi, “2-hydrazino-6-methyl-benzothiazole as an effective inhibitor for the corrosion of mild steel in acidic solutions”, Corros. Sci., Vol.36, No.1, pp.79-84, 1994.
[5] G.K., Gomma, M.H.,Wahdan, “Schiff bases as corrosion inhibitors for aluminium in hydrochloric acid solution”, Mater. Chem. And Phys., Vol.39, No.3, pp. 209-21, 1995.
[6] G. Hahner, C. Woll, M. Buck, M. Grunze, “Investigation of intermediate steps in the self-assembly of N-Alkanethiols on gold surfaces by soft-X-Ray spectroscopy”, Langmuir, Vol.9, No.8, pp. 1955-1958, 1993.
[7] F. Zucchi, G. Trabenelli, G. Brunoro, “Iron corrosion inhibition in hot 4M HCl solution by t-cinnamaldehyde and its structure-related compounds”, Corros. Sci., Vol.33, No.7, pp.1135- 1139, 1992.
[8] H. Baba,T. Kodama, “Corrosion inhibition and characteristics of the triazinedithiol surface film on copper under potentiostatic anodisation”, Corros.Sci., Vol.41, No. 1, pp. 1987-2000, 1999.
[9] C.D. Bain, E.B. Throughton, Y.T. Tao, J. Evall, G.M. Whiteside, J.G. Nuzzo, “Formation of monolayer films by the spontaneous assembly of organic thiols from solution onto gold”, J. Am. Soc., Vol. 111, No. 1, pp. 321-335, 1989.
[10] K.C. Emregul, R. Kurtaran, O. Atakol, “An investigation of chloride-substituted Schiff bases as corrosion inhibitors for steel”, Corros. Sci., Vol 45, No. 12, pp. 2803-2817 ,2003.

[11] J. Teledgi, A. Shaban, E. , Kalman, “EQCM study of copper and iron in presence of organic inhibitors and biocides”, Electrochim. Acta, Vol. 45, pp. 3639-3647, 2000.
[12] E.M. Sherif, S.M. Park, “Effect of 1,4-naphtaquinone on aluminum corrosion in 0.50M sodium chloride solutions”, Electrochim. Acta, Vol. 51, pp. 1313-1321, 2006.
[13] G. Saurbery, “The use of quartz oscillators for weighing thin layers and for micraweighing”, J. Phys., Vol. 155, pp. 206-222, 1959.
[14] A. Yurt, S. Ulutas, H. Dal, “Electrochemical and theoretical investigation on the corrosion of aluminium in acidic solution containing some Schiff bases”, Appl. Surf. Sci., Vol. 253, No. 2, pp. 919-925, 2006.
[15] A. El-Sayed, “A study of the inhibiting action of some polymers on the corrosion of iron in acidic media”, Corros. Prev. Control, Vol. 43, pp. 23-29, 1996.
[16] M.R. Saleh, A.M. Shams El Din, “Efficiency of organic acids and their anions in retarding the dissolution of aluminium”, Corros. Sci. Vol. 12, pp. 688-697, 1972.
[17] A.K. Maayta, N.A.F. Al-Rawashdeh, “Inhibition of acidic corrosion of pure aluminum by some organic compounds”, Corros. Sci. Vol. 46, pp. 1129-1138, 2004.
[18] Z. Szlarska-Smialowska, Proceedings of Advanced Study Institute on Electrochemical and Optical Techniques for the Study and Monitoring of Metallic Corrosion (edited by M.G.S. Ferreira and C.A. Melenderes), NATO ASI Series E: Applied Sciences, , Kluwer Academic Publishers, Netherlands, 203, 285, 1991.
[19] P.W. Atkins, “Physical Chemistry”, 6th edition, Oxford University Press, 857, 1999.
[20] M. Morad, J. Morvan, J. Pagetti, Proceedings of the 8th European Symposium on Corrosion Inhibitors (8SEIC), Ann. Univ. Ferrara, N.S., Sez V, Suppl. N. 10, 159, 1995.
[21] H. Shorky, M. Yuasa, I. Sekine, R.M. Issa, El-Baradie, H.Y., Gomma, G.K., “Corrosion inhibition of mild steel by Schiff base compounds in various aqueous solutions: part 1”, Corros. Sci., Vol. 40, No. 12, pp. 2173-2186, 1998.
[22] S.S. Abd-El-Rehim, H.H. Hassan, M.A.Amin, Mater. Chem. Phys., Vol. 70, pp. 64,2004.
[23] F. Bentiss, M.Langnee, M. Traisnel, J.C. Hornez, Corros. Sci., Vol.41, pp. 789, 1999.
[24] E. Khamis, M.A. Ameer, N.M. Alandis, G. Al-Senani, “Effect of thiosemi carbazones on corrosion of steel in phosphoric acid produced by wet process ”, Corrosion, Vol. 56, No. 2, pp. 127-138, 2000.
[25] J. Teledgi, A. Shaban, E. , Kalman, “EQCM study of copper and iron in presence of organic inhibitors and biocides” Electrochim. Acta, Vol. 45, pp. 3639-3647, 2000.
[26] H. Akrout, L. Bousselmi, E. Triki, S. Maximovitch and F. Dalard, “Adsorption mechanism of non-toxic organic inhibitors on steel in solutions at pH 8 determined by electrochemical quartz crystal microbalance measurements” Materials and Corrosion, 56, No. 3,2005

Details

Primary Language

Turkish

Subjects

Chemical Engineering

Journal Section

Research Article

Authors

Aysel Yurt This is me

Arzu Pınarbaşı This is me

Publication Date

December 31, 2010

Submission Date

July 1, 2017

Acceptance Date

December 20, 2010

Published in Issue

Year 1970 Volume: 23 Number: 2

IZ

https://izlik.org/JA63WX96EA

APA

Yurt, A., & Pınarbaşı, A. (2010). Yumuşak Çeliğin Asidik Korozyonuna Bir Salisilaaldemin Schiff Bazının İnhibitör Etkisi. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, 23(2), 95-114. https://izlik.org/JA63WX96EA

AMA

1.Yurt A, Pınarbaşı A. Yumuşak Çeliğin Asidik Korozyonuna Bir Salisilaaldemin Schiff Bazının İnhibitör Etkisi. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi. 2010;23(2):95-114. https://izlik.org/JA63WX96EA

Chicago

Yurt, Aysel, and Arzu Pınarbaşı. 2010. “Yumuşak Çeliğin Asidik Korozyonuna Bir Salisilaaldemin Schiff Bazının İnhibitör Etkisi”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi 23 (2): 95-114. https://izlik.org/JA63WX96EA.

EndNote

Yurt A, Pınarbaşı A (December 1, 2010) Yumuşak Çeliğin Asidik Korozyonuna Bir Salisilaaldemin Schiff Bazının İnhibitör Etkisi. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 23 2 95–114.

IEEE

[1]A. Yurt and A. Pınarbaşı, “Yumuşak Çeliğin Asidik Korozyonuna Bir Salisilaaldemin Schiff Bazının İnhibitör Etkisi”, Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi, vol. 23, no. 2, pp. 95–114, Dec. 2010, [Online]. Available: https://izlik.org/JA63WX96EA

ISNAD

Yurt, Aysel - Pınarbaşı, Arzu. “Yumuşak Çeliğin Asidik Korozyonuna Bir Salisilaaldemin Schiff Bazının İnhibitör Etkisi”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 23/2 (December 1, 2010): 95-114. https://izlik.org/JA63WX96EA.

JAMA

1.Yurt A, Pınarbaşı A. Yumuşak Çeliğin Asidik Korozyonuna Bir Salisilaaldemin Schiff Bazının İnhibitör Etkisi. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi. 2010;23:95–114.

MLA

Yurt, Aysel, and Arzu Pınarbaşı. “Yumuşak Çeliğin Asidik Korozyonuna Bir Salisilaaldemin Schiff Bazının İnhibitör Etkisi”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, vol. 23, no. 2, Dec. 2010, pp. 95-114, https://izlik.org/JA63WX96EA.

Vancouver

1.Aysel Yurt, Arzu Pınarbaşı. Yumuşak Çeliğin Asidik Korozyonuna Bir Salisilaaldemin Schiff Bazının İnhibitör Etkisi. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi [Internet]. 2010 Dec. 1;23(2):95-114. Available from: https://izlik.org/JA63WX96EA

The Effect Of A Salisilaldimine Schiff Base On The Acidic Corrosion Of Mild Steel

The Effect Of A Salisilaldimine Schiff Base On The Acidic Corrosion Of Mild Steel

Abstract

Keywords