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ANOT CÜRUFLARINDAN BAKIRIN GERİ KAZANIMINDA DÜŞÜK ERİME NOKTALI ÇÖZÜCÜ KULLANIMININ ARAŞTIRILMASI

Year 2020, , 308 - 320, 31.12.2020

Mehmet Ali Topçu , Aydın Rüşen

https://doi.org/10.31796/ogummf.806311
Cited By: 1

Abstract

Bu çalışmada, ikincil kaynaklardan bakır tel üretimi yapan bir firmadan temin edilen bakır anot cürufundan bakır geri kazanımı için çevre ve insan sağlığına duyarlı düşük erime noktalı çözücü kullanımı araştırılmıştır. Bakır anot cürufunun fiziksel, kimyasal ve mineralojik karakterizasyonu öncesinde yapılan öğütme işleminde cüruf içindeki metalik bakırın bir kısmı fiziksel olarak ayrılmıştır. Liç deneylerinde son yıllarda hidrometalurjik süreçlerde kullanılan kolin klorür (ChCl) ve üre (1:2) ile hazırlanan düşük erime noktalı solvent çevre duyarlı çözücü olarak kullanılmıştır. Liç deneylerinin sonuçlarına göre fiziksel olarak anot cürufundan ayrılmayan bakır 72 saatlik reaksiyon süresi, 95 oC’lik liç sıcaklığı ve 1/20 katı/sıvı oranı şartlarındaki liç işlemi ile %90 üzerinde ekstrakte edilmiştir. Liç deneylerinden sonrasında çözeltideki demir çözünürlüğünün oldukça düşük seviyede kaldığı görülmüştür. Çalışmada elde edilen sonuçlara göre fiziksel olarak ayırma ve sonrasında ChCl-üre karışımıyla hazırlanan düşük erime noktalı çözücü kullanılarak yapılan liç işlemleri ile bakır anot cürufundan bakır geri kazanımı için çevreci bir çözücü adayı olabileceği ortaya konmuştur.

Keywords

Düşük Erime Noktalı Çözücü Anot Cürufu Geri Kazanım Hidrometalurji

Supporting Institution

Karamanoğlu Mehmetbey Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü

Project Number

17 - M - 18

Thanks

Bu çalışmanın yapılmasını 17-M-18 proje numarası ile destekleyen Karamanoğlu Mehmetbey Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü’ne teşekkür ederiz.

References

  • Referans 1 Abbott, A. P., Capper, G., Davies, D.L., Rasheed, R. K., &Tambyrajah, V. (2003).Novel solvent properties o choline chloride/urea mixtures.Chemical Communications, (1), 70–71. doi: https://doi.org/10.1039/B210714G
  • Referans 2 Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004). Deep eutectic solvents formed between choline chloride and carboxylic acids: versatile alternatives to ionic liquids. Journal of the American Chemical Society, 126(29), 9142-9147.doi: https://doi.org/10.1021/ja048266j
  • Referans 3 Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., &Shikotra, P. (2005). Selective extraction of metals from mixed oxide matrixes using choline-based ionic liquids. Inorganic Chemistry, 44(19), 6497-6499.doi: https://doi.org/10.1021/ic0505450
  • Referans 4 Abbott, A. P., Capper, G., Davies, D. L., &Shikotra, P. (2006).Processing metal oxides using ionic liquids. Mineral Processing and Extractive Metallurgy, 115(1), 15-18.doi: https://doi.org/10.1039/C0GC00716A
  • Referans 5 Abbott, A. P., Capper, G., Davies, D. L., McKenzie, K. J., & Obi, S. U. (2006).Solubility of metal oxides in deep eutectic solvents based on choline chloride. Journal of Chemical & Engineering Data, 51(4), 1280-1282.doi: https://doi.org/10.1021/je060038c
  • Referans 6 Abbott, A. P., Barron, J. C., Ryder, K. S., & Wilson, D. (2007).Eutectic‐based ionic liquids with metal‐containing anions and cations. Chemistry-A European Journal, 13(22), 6495-6501.doi: https://doi.org/10.1002/chem.200601738
  • Referans 7 Abbott, A. P., Collins, J., Dalrymple, I., Harris R. C., Mistry, R., Qiu, F., Scheirer, J., & Wise, R. W. (2009).Processing of electric arc furnace dust using deep eutectic solvents.Australian Journal of Chemistry, 62(4), 341 – 347.doi: https://doi.org/10.1071/CH08476
  • Referans 8 Agrawal, A., Kumari, S., &Sahu, K. K. (2009). Iron and copper recovery/removal from industrial wastes: A review. Industrial & Engineering Chemistry Research, 48(13), 6145-6161.doi: https://doi.org/10.1021/ie900135u
  • Referans 9 Arslan, C., &Arslan, F. (2002). Recovery of copper, cobalt, and zinc from copper smelter and converter slags. Hydrometallurgy, 67(1-3), 1-7.doi:https://doi.org/10.1016/S0304-386X(02)00139-1
  • Referans 10 Bakkar, A. (2014). Recycling of electric arc furnace dust through dissolution in deep eutectic ionic liquids and electrowinning. Journal of Hazardous Materials, 280, 191-199. doi: https://doi.org/10.1016/j.jhazmat.2014.07.066
  • Referans 11 Banza, A. N., Gock, E., & Kongolo, K. (2002). Base metals recovery from copper smelter slag by oxidising leaching and solvent extraction. Hydrometallurgy, 67(1-3), 63-69. doi: https://doi.org/10.1016/S0304-386X(02)00138-X
  • Referans 12 Boyrazli, M., Altundogan, H. S., &Tümen, F. (2006).Recovery of metals from copper converter slag by leaching with K2Cr2O7-H2SO4. Canadian Metallurgical Quarterly, 45(2), 145-152.doi: https://doi.org/10.1179/cmq.2006.45.2.145
  • Referans 13 Dai, Y., Van Spronsen, J., Witkamp, G. J., Verpoorte, R., & Choi, Y. H. (2013).Natural deep eutectic solvents as new potential media for green technology. AnalyticaChimicaActa, 766, 61-68.doi: https://doi.org/10.1016/j.aca.2012.12.019
  • Referans 14 Delgado-Mellada, N., Laribba, M., Navarro, P., Rigual, V.,Ayuso, M., Garcia, J., & Rodriguez, F., (2018). Thermal stability of choline chloride deep eutectic solvents by TGA/FTIR-ATR analysis.Journal of Molecular Liquids, 260, 37 – 43.doi: https://doi.org/10.1016/j.molliq.2018.03.076
  • Referans 15 Dong, T., Hua, Y., Zhang, Q., & Zhou, D. (2009).Leaching of chalcopyrite with Brønsted acidic ionic liquid. Hydrometallurgy, 99(1-2), 33-38.doi: https://doi.org/10.1016/j.hydromet.2009.06.001
  • Referans 16 Huang, J., Chen, M., Chen, H., Chen, S., & Sun, Q. (2014).Leaching behavior of copper from waste printed circuit boards with Brønsted acidic ionic liquid. Waste Management, 34(2), 483-488.doi: https://doi.org/10.1016/j.wasman.2013.10.027
  • Referans 17 Jalkanen, H., Vehviläinen, J., &Poijärvi, J. (2003).Copper in solidified copper smelter slags. Scandinavian Journal of Metallurgy, 32(2), 65-70.doi: https://doi.org/10.1034/j.16000692.2003.00536.x
  • Referans 18 Lee, J., Kim, S., & Shin, D. (2015). Electrolytic recovery of Fe from Cu smelter slag in nitric acid solution. Journal of Applied Electrochemistry, 45(3), 281-288. doi: https://10.1007/s10800-015-0797-0
  • Referans 19 Li, Y., Papangelakis, V. G., & Perederiy, I. (2009). High pressure oxidative acid leaching of nickel smelter slag: Characterization of feed and residue. Hydrometallurgy, 97(3-4), 185-193. doi: https://doi.org/10.1016/j.hydromet.2009.03.007
  • Referans 20 Liu, W., Rao, S., Wang, W., Yang, T., Yang, L., Chen, L., & Zhang, D. (2015). Selective leaching of cobalt and iron from cobalt white alloy in sulfuric acid solution with catalyst. International Journal of Mineral Processing, 141, 8-14.doi: https://doi.org/10.1016/j.minpro.2015.06.002
  • Referans 20 Mihailova, I., &Mehandjiev, D. (2010).Characterization of fayalite from copper slags. Journal of the University of Chemical Technology and Metallurgy, 45(3), 317-326.Erişim adresi: https://dl.uctm.edu/journal/node/j20103/12_Irena_Mihailova_317-326.pdf
  • Referans 21 Paiva, A., Craveiro, R., Aroso, I., Martins, M., Reis, R. L., & Duarte, A. R. C. (2014).Natural deep eutectic solvents–solvents for the 21st century. ACS Sustainable Chemistry & Engineering, 2(5), 1063-1071.doi:https://doi.org/10.1021/sc500096j
  • Referans 22 Rüşen, A., &Topcu, M. A. (2017).Optimization of gold recovery from copper anode slime by acidic ionic liquid. Korean Journal of Chemical Engineering, 34(11), 2958-2965.doi: https://doi.org/10.1007/s11814-017-0200-4
  • Referans 23 Rüşen, A., & Ali Topcu, M.A. (2017). Investigation of Various Metal Recoveries from Zinc Plant Leach Residue by Choline-Chloride Agent. Current Physical Chemistry, 7(4), 273-280. doi: https://doi.org/10.2174/1877946807666170808120341
  • Referans 24 Satlewal, A., Agrawal, R., Bhagia, S., Sangoro, J., &Ragauskas, A. J. (2018). Natural deep eutectic solvents for lignocellulosic biomass pretreatment: Recent developments, challenges and novel opportunities. Biotechnology Advances , 36 (8), 2032-2050. doi: https://doi.org/10.1016/j.biotechadv.2018.08.009
  • Referans 25 Topçu, M. A., Rüşen, A., &Derin, B. (2019). Minimizing of copper losses to converter slag by a boron compound addition. Journal of Materials Research and Technology, 8(6), 6244-6252.doi: https://doi.org/10.1016/j.jmrt.2019.10.018
  • Referans 26 Whitehead, J. A., Zhang, J., Pereira, N., McCluskey, A., &Lawrance, G. A. (2007).Application of 1-alkyl-3-methyl-imidazolium ionic liquids in the oxidative leaching of sulphidic copper, gold and silver ores. Hydrometallurgy, 88(1-4), 109-120.doi: https://doi.org/10.1016/j.hydromet.2007.03.009
  • Referans 27 Zhang, Q., Vigier, K. D., Royer, S., & Jerome, F. (2012). Deep eutectic solvents: syntheses, properties and applications. Chemical Society Reviews , 41, 7108-7146. doi: https://doi.org/10.1039/C2CS35178A
  • Referans 28 Xiang, J., Huang, Q., Lv, X., & Bai, C. (2017). Multistage utilization process for the gradient-recovery of V, Fe, and Ti from vanadium-bearing converter slag. Journal of Hazardous Materials, 336, 1-7. doi: https://doi.org/10.1016/j.jhazmat.2017.04.060
  • Referans 29 Xie, X., Zou, X., Lu, X., Zheng, K., Cheng, H., Xu, Q., & Zhou, Z. (2016).Voltammetric study and electrodeposition of Cu from CuO in deep eutectic solvents. Journal of The Electrochemical Society, 163(9),537 - 543. doi: https://doi.org/10.1149/2.1241609jes

INVESTIGATION OF USE OF DEEP EUTETIC SOLVENT ON COPPER RECOVERY FROM COPPER ANODE SLAG

Year 2020, , 308 - 320, 31.12.2020

Mehmet Ali Topçu , Aydın Rüşen

https://doi.org/10.31796/ogummf.806311
Cited By: 1

Abstract

Project Number

17 - M - 18

References

  • Referans 1 Abbott, A. P., Capper, G., Davies, D.L., Rasheed, R. K., &Tambyrajah, V. (2003).Novel solvent properties o choline chloride/urea mixtures.Chemical Communications, (1), 70–71. doi: https://doi.org/10.1039/B210714G
  • Referans 2 Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004). Deep eutectic solvents formed between choline chloride and carboxylic acids: versatile alternatives to ionic liquids. Journal of the American Chemical Society, 126(29), 9142-9147.doi: https://doi.org/10.1021/ja048266j
  • Referans 3 Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., &Shikotra, P. (2005). Selective extraction of metals from mixed oxide matrixes using choline-based ionic liquids. Inorganic Chemistry, 44(19), 6497-6499.doi: https://doi.org/10.1021/ic0505450
  • Referans 4 Abbott, A. P., Capper, G., Davies, D. L., &Shikotra, P. (2006).Processing metal oxides using ionic liquids. Mineral Processing and Extractive Metallurgy, 115(1), 15-18.doi: https://doi.org/10.1039/C0GC00716A
  • Referans 5 Abbott, A. P., Capper, G., Davies, D. L., McKenzie, K. J., & Obi, S. U. (2006).Solubility of metal oxides in deep eutectic solvents based on choline chloride. Journal of Chemical & Engineering Data, 51(4), 1280-1282.doi: https://doi.org/10.1021/je060038c
  • Referans 6 Abbott, A. P., Barron, J. C., Ryder, K. S., & Wilson, D. (2007).Eutectic‐based ionic liquids with metal‐containing anions and cations. Chemistry-A European Journal, 13(22), 6495-6501.doi: https://doi.org/10.1002/chem.200601738
  • Referans 7 Abbott, A. P., Collins, J., Dalrymple, I., Harris R. C., Mistry, R., Qiu, F., Scheirer, J., & Wise, R. W. (2009).Processing of electric arc furnace dust using deep eutectic solvents.Australian Journal of Chemistry, 62(4), 341 – 347.doi: https://doi.org/10.1071/CH08476
  • Referans 8 Agrawal, A., Kumari, S., &Sahu, K. K. (2009). Iron and copper recovery/removal from industrial wastes: A review. Industrial & Engineering Chemistry Research, 48(13), 6145-6161.doi: https://doi.org/10.1021/ie900135u
  • Referans 9 Arslan, C., &Arslan, F. (2002). Recovery of copper, cobalt, and zinc from copper smelter and converter slags. Hydrometallurgy, 67(1-3), 1-7.doi:https://doi.org/10.1016/S0304-386X(02)00139-1
  • Referans 10 Bakkar, A. (2014). Recycling of electric arc furnace dust through dissolution in deep eutectic ionic liquids and electrowinning. Journal of Hazardous Materials, 280, 191-199. doi: https://doi.org/10.1016/j.jhazmat.2014.07.066
  • Referans 11 Banza, A. N., Gock, E., & Kongolo, K. (2002). Base metals recovery from copper smelter slag by oxidising leaching and solvent extraction. Hydrometallurgy, 67(1-3), 63-69. doi: https://doi.org/10.1016/S0304-386X(02)00138-X
  • Referans 12 Boyrazli, M., Altundogan, H. S., &Tümen, F. (2006).Recovery of metals from copper converter slag by leaching with K2Cr2O7-H2SO4. Canadian Metallurgical Quarterly, 45(2), 145-152.doi: https://doi.org/10.1179/cmq.2006.45.2.145
  • Referans 13 Dai, Y., Van Spronsen, J., Witkamp, G. J., Verpoorte, R., & Choi, Y. H. (2013).Natural deep eutectic solvents as new potential media for green technology. AnalyticaChimicaActa, 766, 61-68.doi: https://doi.org/10.1016/j.aca.2012.12.019
  • Referans 14 Delgado-Mellada, N., Laribba, M., Navarro, P., Rigual, V.,Ayuso, M., Garcia, J., & Rodriguez, F., (2018). Thermal stability of choline chloride deep eutectic solvents by TGA/FTIR-ATR analysis.Journal of Molecular Liquids, 260, 37 – 43.doi: https://doi.org/10.1016/j.molliq.2018.03.076
  • Referans 15 Dong, T., Hua, Y., Zhang, Q., & Zhou, D. (2009).Leaching of chalcopyrite with Brønsted acidic ionic liquid. Hydrometallurgy, 99(1-2), 33-38.doi: https://doi.org/10.1016/j.hydromet.2009.06.001
  • Referans 16 Huang, J., Chen, M., Chen, H., Chen, S., & Sun, Q. (2014).Leaching behavior of copper from waste printed circuit boards with Brønsted acidic ionic liquid. Waste Management, 34(2), 483-488.doi: https://doi.org/10.1016/j.wasman.2013.10.027
  • Referans 17 Jalkanen, H., Vehviläinen, J., &Poijärvi, J. (2003).Copper in solidified copper smelter slags. Scandinavian Journal of Metallurgy, 32(2), 65-70.doi: https://doi.org/10.1034/j.16000692.2003.00536.x
  • Referans 18 Lee, J., Kim, S., & Shin, D. (2015). Electrolytic recovery of Fe from Cu smelter slag in nitric acid solution. Journal of Applied Electrochemistry, 45(3), 281-288. doi: https://10.1007/s10800-015-0797-0
  • Referans 19 Li, Y., Papangelakis, V. G., & Perederiy, I. (2009). High pressure oxidative acid leaching of nickel smelter slag: Characterization of feed and residue. Hydrometallurgy, 97(3-4), 185-193. doi: https://doi.org/10.1016/j.hydromet.2009.03.007
  • Referans 20 Liu, W., Rao, S., Wang, W., Yang, T., Yang, L., Chen, L., & Zhang, D. (2015). Selective leaching of cobalt and iron from cobalt white alloy in sulfuric acid solution with catalyst. International Journal of Mineral Processing, 141, 8-14.doi: https://doi.org/10.1016/j.minpro.2015.06.002
  • Referans 20 Mihailova, I., &Mehandjiev, D. (2010).Characterization of fayalite from copper slags. Journal of the University of Chemical Technology and Metallurgy, 45(3), 317-326.Erişim adresi: https://dl.uctm.edu/journal/node/j20103/12_Irena_Mihailova_317-326.pdf
  • Referans 21 Paiva, A., Craveiro, R., Aroso, I., Martins, M., Reis, R. L., & Duarte, A. R. C. (2014).Natural deep eutectic solvents–solvents for the 21st century. ACS Sustainable Chemistry & Engineering, 2(5), 1063-1071.doi:https://doi.org/10.1021/sc500096j
  • Referans 22 Rüşen, A., &Topcu, M. A. (2017).Optimization of gold recovery from copper anode slime by acidic ionic liquid. Korean Journal of Chemical Engineering, 34(11), 2958-2965.doi: https://doi.org/10.1007/s11814-017-0200-4
  • Referans 23 Rüşen, A., & Ali Topcu, M.A. (2017). Investigation of Various Metal Recoveries from Zinc Plant Leach Residue by Choline-Chloride Agent. Current Physical Chemistry, 7(4), 273-280. doi: https://doi.org/10.2174/1877946807666170808120341
  • Referans 24 Satlewal, A., Agrawal, R., Bhagia, S., Sangoro, J., &Ragauskas, A. J. (2018). Natural deep eutectic solvents for lignocellulosic biomass pretreatment: Recent developments, challenges and novel opportunities. Biotechnology Advances , 36 (8), 2032-2050. doi: https://doi.org/10.1016/j.biotechadv.2018.08.009
  • Referans 25 Topçu, M. A., Rüşen, A., &Derin, B. (2019). Minimizing of copper losses to converter slag by a boron compound addition. Journal of Materials Research and Technology, 8(6), 6244-6252.doi: https://doi.org/10.1016/j.jmrt.2019.10.018
  • Referans 26 Whitehead, J. A., Zhang, J., Pereira, N., McCluskey, A., &Lawrance, G. A. (2007).Application of 1-alkyl-3-methyl-imidazolium ionic liquids in the oxidative leaching of sulphidic copper, gold and silver ores. Hydrometallurgy, 88(1-4), 109-120.doi: https://doi.org/10.1016/j.hydromet.2007.03.009
  • Referans 27 Zhang, Q., Vigier, K. D., Royer, S., & Jerome, F. (2012). Deep eutectic solvents: syntheses, properties and applications. Chemical Society Reviews , 41, 7108-7146. doi: https://doi.org/10.1039/C2CS35178A
  • Referans 28 Xiang, J., Huang, Q., Lv, X., & Bai, C. (2017). Multistage utilization process for the gradient-recovery of V, Fe, and Ti from vanadium-bearing converter slag. Journal of Hazardous Materials, 336, 1-7. doi: https://doi.org/10.1016/j.jhazmat.2017.04.060
  • Referans 29 Xie, X., Zou, X., Lu, X., Zheng, K., Cheng, H., Xu, Q., & Zhou, Z. (2016).Voltammetric study and electrodeposition of Cu from CuO in deep eutectic solvents. Journal of The Electrochemical Society, 163(9),537 - 543. doi: https://doi.org/10.1149/2.1241609jes
There are 30 citations in total.

Details

Primary Language Turkish
Subjects Material Production Technologies
Journal Section Research Articles
Authors

Mehmet Ali Topçu 0000-0002-0007-5665

Aydın Rüşen 0000-0001-5592-1411

Project Number 17 - M - 18
Publication Date December 31, 2020
Acceptance Date November 25, 2020
Published in Issue Year 2020

Cite

APA Topçu, M. A., & Rüşen, A. (2020). ANOT CÜRUFLARINDAN BAKIRIN GERİ KAZANIMINDA DÜŞÜK ERİME NOKTALI ÇÖZÜCÜ KULLANIMININ ARAŞTIRILMASI. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, 28(3), 308-320. https://doi.org/10.31796/ogummf.806311
AMA Topçu MA, Rüşen A. ANOT CÜRUFLARINDAN BAKIRIN GERİ KAZANIMINDA DÜŞÜK ERİME NOKTALI ÇÖZÜCÜ KULLANIMININ ARAŞTIRILMASI. ESOGÜ Müh Mim Fak Derg. December 2020;28(3):308-320. doi:10.31796/ogummf.806311
Chicago Topçu, Mehmet Ali, and Aydın Rüşen. “ANOT CÜRUFLARINDAN BAKIRIN GERİ KAZANIMINDA DÜŞÜK ERİME NOKTALI ÇÖZÜCÜ KULLANIMININ ARAŞTIRILMASI”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi 28, no. 3 (December 2020): 308-20. https://doi.org/10.31796/ogummf.806311.
EndNote Topçu MA, Rüşen A (December 1, 2020) ANOT CÜRUFLARINDAN BAKIRIN GERİ KAZANIMINDA DÜŞÜK ERİME NOKTALI ÇÖZÜCÜ KULLANIMININ ARAŞTIRILMASI. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 28 3 308–320.
IEEE M. A. Topçu and A. Rüşen, “ANOT CÜRUFLARINDAN BAKIRIN GERİ KAZANIMINDA DÜŞÜK ERİME NOKTALI ÇÖZÜCÜ KULLANIMININ ARAŞTIRILMASI”, ESOGÜ Müh Mim Fak Derg, vol. 28, no. 3, pp. 308–320, 2020, doi: 10.31796/ogummf.806311.
ISNAD Topçu, Mehmet Ali - Rüşen, Aydın. “ANOT CÜRUFLARINDAN BAKIRIN GERİ KAZANIMINDA DÜŞÜK ERİME NOKTALI ÇÖZÜCÜ KULLANIMININ ARAŞTIRILMASI”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 28/3 (December 2020), 308-320. https://doi.org/10.31796/ogummf.806311.
JAMA Topçu MA, Rüşen A. ANOT CÜRUFLARINDAN BAKIRIN GERİ KAZANIMINDA DÜŞÜK ERİME NOKTALI ÇÖZÜCÜ KULLANIMININ ARAŞTIRILMASI. ESOGÜ Müh Mim Fak Derg. 2020;28:308–320.
MLA Topçu, Mehmet Ali and Aydın Rüşen. “ANOT CÜRUFLARINDAN BAKIRIN GERİ KAZANIMINDA DÜŞÜK ERİME NOKTALI ÇÖZÜCÜ KULLANIMININ ARAŞTIRILMASI”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, vol. 28, no. 3, 2020, pp. 308-20, doi:10.31796/ogummf.806311.
Vancouver Topçu MA, Rüşen A. ANOT CÜRUFLARINDAN BAKIRIN GERİ KAZANIMINDA DÜŞÜK ERİME NOKTALI ÇÖZÜCÜ KULLANIMININ ARAŞTIRILMASI. ESOGÜ Müh Mim Fak Derg. 2020;28(3):308-20.

Cited By

Processing of anode slime with deep eutectic solvents as a green leachant
Hydrometallurgy
Mehmet A. Topçu
https://doi.org/10.1016/j.hydromet.2021.105732

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