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Fe-Cr Siyah Seramik Pigment Üretiminde Ferrokrom Kullanımı

Year 2010, Volume: 23 Issue: 2, 53 - 65, 31.12.2010

Abstract


Bu çalışmada, saf oksitlere göre daha ucuz hammaddeler kullanarak porselen karo bünyeleri için siyah Fe-Cr hematit pigmentlerin üretimi ve karakterizasyonu amaçlanmıştır. Hematit ve ferrokrom ile üretilen pigmentlerin L*a*b* renk değerlerine; başlangıç hammaddelerinin tane boyutu, mineralleştirici ilavesi ve kademeli kalsinasyonun etkisi incelenmiştir. Üretilen pigmentlerin renkleri spektrofotometre ile ölçülerek L*a*b* olarak ifade edilmiştir. İnce tane boyutuna sahip başlangıç hammaddeleri ve mineralleştirici ilavesi ile kademeli olarak kalsine edilerek üretilen pigmentlerin renk parametrelerinin, ticari olarak kullanılan siyah pigmentlerle oldukça benzer olduğu tespit edilmiştir.

References

  • [1] T. Manfredini and F. Bondioli, “Inorganic pigments”, Ceramic Industry, Vol.150, No.2, pp.53-58, 2000.
  • [2] R.A. Eppler and D.R. Eppler, “Glazes and Glass Coatings”, First Edn, American Ceramic Society, Westerville, 2000.
  • [3] J. Calbo, S. Sorli, M. Llusar, M.A. Tena and G. Monros, “Minimisation of toxicity in nickel ferrite black pigment”, British Ceramic Transactions, Vol.103, pp.3-9, 2004.
  • [4] J. Calbo, M.A. Tena, G. Monros, M. Llusar, R. Galindo and J.A. Badenes, “Flux agent effect on nickel ferrite black pigment”, Am. Ceram. Soc. Bull., Vol.84, No.12, pp.10–14, 2005.
  • [5] A. Escardino, S. Mestre, A. Barba, V. Beltran and A. Blasco, “Synthesis mechanism of an iron-chromium ceramic pigment”, J. Am. Ceram. Soc., Vol.83, No.1, pp.29–32, 2000.
  • [6] A. Escardino, S. Mestre, A. Barba, C. Feliu, A. Blasco and V. Beltran, “Kinetic study of black (Fe,Cr)2O3 pigment synthesis reaction: influence of composition and particle size”, British Ceramic Transactions, Vol.102, No.6, pp.251-256, 2003.
  • [7] A. Escardino, S. Mestre, A. Barba and V. Beltran, “Kinetic study of black Fe2O3-Cr2O3 pigment synthesis: influence of synthesis time and temperature”, J. Am. Ceram. Soc., Vol.86, No.6, pp.945-950, 2003.
  • [8] A. Escardino, S. Mestre, A. Barba, M. Monzo, A. Blasco and V. Beltran, “Colorimetric study of black (Fe,Cr)2O3 pigment synthesis reaction: relation between chromatic coordinates and synthesis conditions, British Ceramic Transactions, Vol.102, No.6, pp. 247-250, 2003.
  • [9] W.G. Loucka, M.E. Gall and J.D. Thomas, Blue shade Fe-Cr black pigment, US. Patent No: 6235106, 2001.
  • [10] H. Weber, Black Fe-Cr oxide pigment composition, US. Patent No: 3561989, 1971.
  • [11] B.Tanisan and S. Turan, “Development of black ceramic pigments from chromite and hematite mixtures”, I. International Ceramic, Glass, Porcelain Enamel, Glaze and Pigment Congress, 12-14 October 2009, Eskisehir, Proceeding Books, pp.1127-1134.
  • [12] E. Ozel, I. Kücük and S. Turan, “Synthesis of an iron-chromium ceramic pigment by using limonite and chromite mixtures”, Key Eng. Mater., Vol.206-213, pp.1227-1235, 2002.
  • [13] S. Turan, Y. Inceefe and E. Ozel, “Production and characterisation of pigments produced using grinding waste from cast iron foundry”, Key Eng. Mater., Vol.264-268, pp.2473-2476, 2004.
  • [14] E. Ozel, S. Turan, S. Çoruh and O.N. Ergun,“Production of brown and black pigments by using flotation waste from copper slag”, Waste Manage. Res., Vol. 24, pp.125–133, 2006.
  • [15] G. Costa, V.P. Della, M.J. Ribeiro, A.P.N. Oliveria, G. Monros and J.A. Labrincha, “Synthesis of black ceramic pigments from secondary raw materials”, Dyes and Pigments, Vol.77, pp.137–144, 2008.
  • [16] G. Costa, V.P. Della, M.J. Ribeiro and J.A. Labrincha, “Forming black spinel pigment from industrial sludge”, Am. Ceram. Soc. Bull., Vol.87, No.7, pp.9101–9107, 2008.
  • [17] S. Geng and J. Zhu, “Promising alloys for intermediate-temperature solid oxide fuel cell interconnect aplication”, Journal of Power Sources, Vol.160, No.2, pp.1009-1016, 2006.

Use Of Ferrochrome In Fe-Cr Black Ceramic Pigment Production

Year 2010, Volume: 23 Issue: 2, 53 - 65, 31.12.2010

Abstract


In this study, production and charecrarization of Fe-Cr hematite black pigments for porcelain tile bodies were attempted by using cheaper raw materials as compared to pure oxides. Effect of raw material particle size, mineralizers and stepwise calcination on pigments L*a*b* values that produced with hematite and ferrochrome were investigated. The obtained colour values were reported as L*a*b values, measured by a spectrophotometer. When fine particle size raw materials with mineralizers were used and calcined in a stepwise manner, black ceramic pigment with very similar colour parameters to commercial black pigments was produced.


References

  • [1] T. Manfredini and F. Bondioli, “Inorganic pigments”, Ceramic Industry, Vol.150, No.2, pp.53-58, 2000.
  • [2] R.A. Eppler and D.R. Eppler, “Glazes and Glass Coatings”, First Edn, American Ceramic Society, Westerville, 2000.
  • [3] J. Calbo, S. Sorli, M. Llusar, M.A. Tena and G. Monros, “Minimisation of toxicity in nickel ferrite black pigment”, British Ceramic Transactions, Vol.103, pp.3-9, 2004.
  • [4] J. Calbo, M.A. Tena, G. Monros, M. Llusar, R. Galindo and J.A. Badenes, “Flux agent effect on nickel ferrite black pigment”, Am. Ceram. Soc. Bull., Vol.84, No.12, pp.10–14, 2005.
  • [5] A. Escardino, S. Mestre, A. Barba, V. Beltran and A. Blasco, “Synthesis mechanism of an iron-chromium ceramic pigment”, J. Am. Ceram. Soc., Vol.83, No.1, pp.29–32, 2000.
  • [6] A. Escardino, S. Mestre, A. Barba, C. Feliu, A. Blasco and V. Beltran, “Kinetic study of black (Fe,Cr)2O3 pigment synthesis reaction: influence of composition and particle size”, British Ceramic Transactions, Vol.102, No.6, pp.251-256, 2003.
  • [7] A. Escardino, S. Mestre, A. Barba and V. Beltran, “Kinetic study of black Fe2O3-Cr2O3 pigment synthesis: influence of synthesis time and temperature”, J. Am. Ceram. Soc., Vol.86, No.6, pp.945-950, 2003.
  • [8] A. Escardino, S. Mestre, A. Barba, M. Monzo, A. Blasco and V. Beltran, “Colorimetric study of black (Fe,Cr)2O3 pigment synthesis reaction: relation between chromatic coordinates and synthesis conditions, British Ceramic Transactions, Vol.102, No.6, pp. 247-250, 2003.
  • [9] W.G. Loucka, M.E. Gall and J.D. Thomas, Blue shade Fe-Cr black pigment, US. Patent No: 6235106, 2001.
  • [10] H. Weber, Black Fe-Cr oxide pigment composition, US. Patent No: 3561989, 1971.
  • [11] B.Tanisan and S. Turan, “Development of black ceramic pigments from chromite and hematite mixtures”, I. International Ceramic, Glass, Porcelain Enamel, Glaze and Pigment Congress, 12-14 October 2009, Eskisehir, Proceeding Books, pp.1127-1134.
  • [12] E. Ozel, I. Kücük and S. Turan, “Synthesis of an iron-chromium ceramic pigment by using limonite and chromite mixtures”, Key Eng. Mater., Vol.206-213, pp.1227-1235, 2002.
  • [13] S. Turan, Y. Inceefe and E. Ozel, “Production and characterisation of pigments produced using grinding waste from cast iron foundry”, Key Eng. Mater., Vol.264-268, pp.2473-2476, 2004.
  • [14] E. Ozel, S. Turan, S. Çoruh and O.N. Ergun,“Production of brown and black pigments by using flotation waste from copper slag”, Waste Manage. Res., Vol. 24, pp.125–133, 2006.
  • [15] G. Costa, V.P. Della, M.J. Ribeiro, A.P.N. Oliveria, G. Monros and J.A. Labrincha, “Synthesis of black ceramic pigments from secondary raw materials”, Dyes and Pigments, Vol.77, pp.137–144, 2008.
  • [16] G. Costa, V.P. Della, M.J. Ribeiro and J.A. Labrincha, “Forming black spinel pigment from industrial sludge”, Am. Ceram. Soc. Bull., Vol.87, No.7, pp.9101–9107, 2008.
  • [17] S. Geng and J. Zhu, “Promising alloys for intermediate-temperature solid oxide fuel cell interconnect aplication”, Journal of Power Sources, Vol.160, No.2, pp.1009-1016, 2006.
There are 17 citations in total.

Details

Subjects Material Production Technologies
Journal Section Research Articles
Authors

Belgin Tanışan

Servet Turan

Publication Date December 31, 2010
Acceptance Date August 20, 2010
Published in Issue Year 2010 Volume: 23 Issue: 2

Cite

APA Tanışan, B., & Turan, S. (2010). Fe-Cr Siyah Seramik Pigment Üretiminde Ferrokrom Kullanımı. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, 23(2), 53-65.
AMA Tanışan B, Turan S. Fe-Cr Siyah Seramik Pigment Üretiminde Ferrokrom Kullanımı. ESOGÜ Müh Mim Fak Derg. December 2010;23(2):53-65.
Chicago Tanışan, Belgin, and Servet Turan. “Fe-Cr Siyah Seramik Pigment Üretiminde Ferrokrom Kullanımı”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi 23, no. 2 (December 2010): 53-65.
EndNote Tanışan B, Turan S (December 1, 2010) Fe-Cr Siyah Seramik Pigment Üretiminde Ferrokrom Kullanımı. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 23 2 53–65.
IEEE B. Tanışan and S. Turan, “Fe-Cr Siyah Seramik Pigment Üretiminde Ferrokrom Kullanımı”, ESOGÜ Müh Mim Fak Derg, vol. 23, no. 2, pp. 53–65, 2010.
ISNAD Tanışan, Belgin - Turan, Servet. “Fe-Cr Siyah Seramik Pigment Üretiminde Ferrokrom Kullanımı”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 23/2 (December 2010), 53-65.
JAMA Tanışan B, Turan S. Fe-Cr Siyah Seramik Pigment Üretiminde Ferrokrom Kullanımı. ESOGÜ Müh Mim Fak Derg. 2010;23:53–65.
MLA Tanışan, Belgin and Servet Turan. “Fe-Cr Siyah Seramik Pigment Üretiminde Ferrokrom Kullanımı”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, vol. 23, no. 2, 2010, pp. 53-65.
Vancouver Tanışan B, Turan S. Fe-Cr Siyah Seramik Pigment Üretiminde Ferrokrom Kullanımı. ESOGÜ Müh Mim Fak Derg. 2010;23(2):53-65.

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