STOKİYOMETRİK OLMAYAN NBT-ST SERAMİKLERİNİN ELEKTRİKSEL ÖZELLİKLERİNE SİNTERLEME YARDIMCISI CuO KATKISI ETKİSİNİN İNCELENMESİ

Gülbeniz Yaldiz İnce; Mustafa Yunus Kaya

doi:10.31796/ogummf.1542806

Research Article

INVESTIGATION OF THE EFFECT OF CuO SINTERING AID ON THE ELECTRICAL PROPERTIES OF NON-STOICHIOMETRIC NBT-ST CERAMICS

Year 2024, Volume: 32 Issue: 3, 1526 - 1536

Gülbeniz Yaldiz İnce , Mustafa Yunus Kaya

https://doi.org/10.31796/ogummf.1542806

Abstract

In the last two decades, extensive research has been conducted on lead-free piezoceramics to find alternatives to lead-zirconate-titanate (PZT) and its derivatives, which are widely utilized in electromechanical devices, including actuators, transducers, sensors, energy harvesting, and energy storage applications. Among these studies, sodium bismuth titanate (Na0.5Bi0.5TiO3-NBT) based ceramics and compositions near the morphotropic phase boundary (MPB) are notable for their electrical properties. A recent study modified the NBT ceramic composition with strontium titanate (SrTiO3-ST). The non-stoichiometric ceramic composition [Na0,5Bi0,5TiO3]0,75[Sr1-yTiO3-x]0,25-NBT-SnT (where x=0.25) was synthesized via solid-state calcination, and the effect of CuO additives on sintering performance and properties was investigated. The synthesis process achieved a significant proportion of the NBT-SnT phase in pseudo cubic symmetry. Secondary phase formation during sintering was observed to increase with CuO sintering aid. The highest density was achieved with ceramics containing 0.5% CuO sintered at 1200°C for 3 hours. For these ceramics, the dielectric constant (K) ranged from 570 to 1300 at a frequency of 10 kHz, with dielectric loss (tan δ) values ranging from 0.04 to 0.11, indicative of relaxor ferroelectric behavior with a degree of diffuse phase transition (γ) ranging from 1.84 to 1.99.

Keywords

Lead-free Ceramic, Sodium Bismuth Titanate, Ferroelectric, CuO doped, Electrical Properties

Thanks

The authors acknowledge Gebze Technical University, the Department of Materials Science and Engineering, and the Piezodevices research group for their support in the structural and electrical characterizations of this study.

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STOKİYOMETRİK OLMAYAN NBT-ST SERAMİKLERİNİN ELEKTRİKSEL ÖZELLİKLERİNE SİNTERLEME YARDIMCISI CuO KATKISI ETKİSİNİN İNCELENMESİ

Year 2024, Volume: 32 Issue: 3, 1526 - 1536

Gülbeniz Yaldiz İnce , Mustafa Yunus Kaya

https://doi.org/10.31796/ogummf.1542806

Abstract

Son yirmi yıllık süreçte, elektromekanik cihazlarda, enerji hasadı ve enerji depolama uygulamalarında yaygın kullanıma sahip kurşun zirkonat titanat ve türevi seramiklere alternatif olarak kurşun içermeyen piezoseramiklerin araştırılması ve geliştirilmesi üzerine çok sayıda çalışma yapılmıştır. Bu araştırmalar içerisinde sodyum bizmut titanat (Na0.5Bi0.5TiO3-NBT) esaslı seramikler ve morfotropik faz sınırı (MFS) kompozisyonları sergiledikleri elektriksel özellikler ile öne çıkmaktadır. Bu çalışmada, NBT seramik bileşimi stronsiyum titanat (SrTiO3-ST) ile modifiye edilmiştir. [Na0,5Bi0,5TiO3]0,75[Sr1-xTiO3-x]0,25-NBT-SnT (x=0,25) kimyasal formülünce stokiyometrik olmayan seramik kompozisyonu katı hal kalsinasyon yöntemiyle sentezlenmiş ve CuO katkısının sinterleme performansı ve özellikleri üzerine etkisi incelenmiştir. Sentezleme işlemi sonrasında psedokübik simetride NBT-SnT fazının yüksek oranda oluştuğu görülmüştür. Sinterleme yardımcısı CuO katkısı miktarına bağlı olarak sinterleme işleminde ikincil faz oluşumu gözlenmiştir. En yüksek yoğunlaşma oranı %0,5 CuO katkılı seramiklerde 1200 °C’de 3 saat sinterleme ile elde edilmiştir. Bu seramikler için 10 kHz frekansında dielektrik sabiti (K) 570 ila 1300 arasında, dielektrik kayıp (tan ) değerleri 0,04 ila 0,11 arasında, relaksör ferroelektrik davranışa işaret eden yayınımsallık derecesi () ise 1, 84 ila 1,99 arasında değişmektedir.

Keywords

Kurşunsuz Seramik, Sodyum Bizmut Titatanat, Ferroelektrik, CuO Katkı

Thanks

Bu çalışmadaki yapısal ve elektriksel karakterizasyonlara destek sağlayan Gebze Teknik Üniversitesi, Malzeme Bilimi ve Mühendisliği Bölümüne ve Piezoaygıtlar araştırma grubuna teşekkür ederiz.

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Primary Language	Turkish
Subjects	Materials Engineering (Other)
Journal Section	Research Articles
Authors	Gülbeniz Yaldiz İnce 0000-0003-2161-8283 Mustafa Yunus Kaya 0000-0002-4518-3184
Early Pub Date	December 12, 2024
Publication Date
Submission Date	September 3, 2024
Acceptance Date	November 14, 2024
Published in Issue	Year 2024 Volume: 32 Issue: 3

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APA	Yaldiz İnce, G., & Kaya, M. Y. (2024). STOKİYOMETRİK OLMAYAN NBT-ST SERAMİKLERİNİN ELEKTRİKSEL ÖZELLİKLERİNE SİNTERLEME YARDIMCISI CuO KATKISI ETKİSİNİN İNCELENMESİ. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, 32(3), 1526-1536. https://doi.org/10.31796/ogummf.1542806
AMA	Yaldiz İnce G, Kaya MY. STOKİYOMETRİK OLMAYAN NBT-ST SERAMİKLERİNİN ELEKTRİKSEL ÖZELLİKLERİNE SİNTERLEME YARDIMCISI CuO KATKISI ETKİSİNİN İNCELENMESİ. ESOGÜ Müh Mim Fak Derg. December 2024;32(3):1526-1536. doi:10.31796/ogummf.1542806
Chicago	Yaldiz İnce, Gülbeniz, and Mustafa Yunus Kaya. “STOKİYOMETRİK OLMAYAN NBT-ST SERAMİKLERİNİN ELEKTRİKSEL ÖZELLİKLERİNE SİNTERLEME YARDIMCISI CuO KATKISI ETKİSİNİN İNCELENMESİ”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi 32, no. 3 (December 2024): 1526-36. https://doi.org/10.31796/ogummf.1542806.
EndNote	Yaldiz İnce G, Kaya MY (December 1, 2024) STOKİYOMETRİK OLMAYAN NBT-ST SERAMİKLERİNİN ELEKTRİKSEL ÖZELLİKLERİNE SİNTERLEME YARDIMCISI CuO KATKISI ETKİSİNİN İNCELENMESİ. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 32 3 1526–1536.
IEEE	G. Yaldiz İnce and M. Y. Kaya, “STOKİYOMETRİK OLMAYAN NBT-ST SERAMİKLERİNİN ELEKTRİKSEL ÖZELLİKLERİNE SİNTERLEME YARDIMCISI CuO KATKISI ETKİSİNİN İNCELENMESİ”, ESOGÜ Müh Mim Fak Derg, vol. 32, no. 3, pp. 1526–1536, 2024, doi: 10.31796/ogummf.1542806.
ISNAD	Yaldiz İnce, Gülbeniz - Kaya, Mustafa Yunus. “STOKİYOMETRİK OLMAYAN NBT-ST SERAMİKLERİNİN ELEKTRİKSEL ÖZELLİKLERİNE SİNTERLEME YARDIMCISI CuO KATKISI ETKİSİNİN İNCELENMESİ”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 32/3 (December 2024), 1526-1536. https://doi.org/10.31796/ogummf.1542806.
JAMA	Yaldiz İnce G, Kaya MY. STOKİYOMETRİK OLMAYAN NBT-ST SERAMİKLERİNİN ELEKTRİKSEL ÖZELLİKLERİNE SİNTERLEME YARDIMCISI CuO KATKISI ETKİSİNİN İNCELENMESİ. ESOGÜ Müh Mim Fak Derg. 2024;32:1526–1536.
MLA	Yaldiz İnce, Gülbeniz and Mustafa Yunus Kaya. “STOKİYOMETRİK OLMAYAN NBT-ST SERAMİKLERİNİN ELEKTRİKSEL ÖZELLİKLERİNE SİNTERLEME YARDIMCISI CuO KATKISI ETKİSİNİN İNCELENMESİ”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, vol. 32, no. 3, 2024, pp. 1526-3, doi:10.31796/ogummf.1542806.
Vancouver	Yaldiz İnce G, Kaya MY. STOKİYOMETRİK OLMAYAN NBT-ST SERAMİKLERİNİN ELEKTRİKSEL ÖZELLİKLERİNE SİNTERLEME YARDIMCISI CuO KATKISI ETKİSİNİN İNCELENMESİ. ESOGÜ Müh Mim Fak Derg. 2024;32(3):1526-3.

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