Fabrication and Characterization of Mullite Reinforced Y2O3 Added ZrO2 Ceramics

Mehmet Akif Hafızoğlu; Tahsin Boyraz; Ahmet Akkuş

EN TR

Fabrication and Characterization of Mullite Reinforced Y2O3 Added ZrO2 Ceramics

Abstract

Mullite (3Al2O3.2SiO2) and 3 mol% yttria added zirconia (3 mol% Y2O3 - 97 mol% ZrO2) ceramic powders were synthesized by conventional ceramic processing route. All mixtures were prepared by mechanical alloying method in acetone environment with zirconia ball mill. Mullite and yttria added zirconia ceramic powders were synthesized by reaction sintering in air at 1600oC for 3h and 1300oC for 2h, respectively. The ceramic phases formed were made ready to form ceramic - ceramic composites by crushing, grinding and sieving processes. Then, 0 and 10% by weight mullite added yttria doped zirconia mixtures were prepared by powder metallurgy method. After drying, the powders were compacted by uniaxial pressing. The green compacts were sintered at 1500-1600oC for 1-5 h in air conditions in a high temperature furnace. Then, microstructure (SEM), phase analysis (XRD), mechanical (hardness, 3-point bending and wear) and physical properties (%shrinkage, water absorption, porosity and density) tests were performed on the composites. In this study, whether there is a phase change in the ZrO2-Y2O3 mixture at high sintering temperatures and the effect of mullite additive on the properties of this mixture was investigated. The data obtained were presented in graphs and tables and their comments were made.

Keywords

Zirconia, Yttria, Mullite, Characterization, Wear.

Mullit Takviyeli Y2O3 Katkılı ZrO2 Seramiklerinin İmalatı ve Karakterizasyonu

Abstract

Bu çalışmada, mullit (3Al2O3.2SiO2) ve %3 mol itriya katkılı zirkonya (%3 mol Y2O3 - %97 mol ZrO2) seramik tozları geleneksel seramik üretim yöntemi ile sentezlenmiştir. Tüm karışımlar, zirkonya bilyalı değirmende aseton ortamında mekanik alaşımlama yöntemiyle hazırlanmıştır. Mullit ve itriya katkılı zirkonya seramik tozları sırasıyla 1600 oC'de 3 saat ve 1300 oC'de 2 saat sentezlenmiştir. Seramik fazlar kırma, öğütme ve eleme işlemleri ile seramik - seramik kompozitleri oluşturmaya hazır hale getirilmiştir. Daha sonra ağırlıkça %0 ve %10 mullit takviyeli itriya katkılı zirkonya karışımları toz metalurjisi yöntemiyle hazırlanmıştır. Kurutulduktan sonra, tozlar tek eksenli presleme ile sıkıştırılmıştır. Devamında, yüksek sıcaklıklı bir fırında hava koşullarında 1500-1600 oC'de 1-5 saat sinterlenmiştir. Daha sonra kompozitler üzerinde mikroyapı (SEM), faz analizi (XRD), mekanik (sertlik, 3 nokta eğme ve aşınma) ve fiziksel özellikler (% küçülme, su emme, gözeneklilik ve yoğunluk) testleri yapılmıştır. Bu çalışmada, yüksek sinterleme sıcaklıklarında ZrO2 - Y2O3 karışımında faz değişimi olup olmadığı ve mullit katkı maddesinin bu karışımın özelliklerine etkisi araştırılmıştır. Elde edilen veriler grafik ve tablolar halinde sunulmuş ve yorumları yapılmıştır.

Keywords

Zirkonya, İtriya, Mullit, Karakterizasyon, Aşınma.

Supporting Institution

Sivas Cumhuriyet Üniversitesi Bilimsel Araştırma Projeleri Destek Fonu

Project Number

M-767

Thanks

Yazarlar, Sivas Cumhuriyet Üniversitesi Bilimsel Araştırma Projeleri Destek Fonu'na teşekkür eder.

References

[1] Boyraz, T., 2008. “An investigation on physical and electrical properties of CaO/MgO-stabilized zirconia ceramics formed with different methods,” Ph.D. dissertation, Metallurg. Eng., Istanbul Technical Univ., Istanbul.
[2] Pekdemir, A. D., 2018. “Preparation and characterization of boron carbide at low-temperature from boric acid and polyols,” Ph.D. dissertation, Dept. Chem., Ankara Univ., Ankara.
[3] Ceylan, A., 2006. “The production of functionally graded SiAlON ceramics by tape casting method,” Ph.D. dissertation, Dept. Cer. Eng., Anadolu Univ., Eskişehir.
[4] Abi, C. B., 2009. “An investigation on fracture toughness of traditional and technical ceramics,” Ph.D. dissertation, Dept. Metallurg. Eng., Afyon Kocatepe Univ., Afyon.
[5] Hafızoğlu, M. A., Boyraz , T. and Akkuş, A., 2021. “Fabrication, characterization and wear properties of mullite reinforced silica-doped zirconia ceramic composites,” in Proc. IMSMATEC'21, p. 175 – 180.
[6] Hafızoğlu, M. A., Akkuş, A. and Boyraz, T., 2021. “Fabrication, characterization and wear properties of mullite reinforced Al2O3-doped ZrO2 ceramic composites,” in Proc. GLOBCER’21, p. 673 – 686.
[7] Hafızoğlu, M. A., Boyraz , T. and Akkuş, A., 2021. “Fabrication and characterization of mullite reinforced TiO2 added ZrO2 ceramics,” International Joint Science Congress of Materials and Polymers (ISCMP’21).
[8] Cutler, R. A., Reynolds, J. R. and Jones, A., 1992. “Sintering and characterization of polycrystalline monoclinic, tetragonal, and cubic zirconia,” Journal of the American Ceramic Society, 75(8), pp. 2173-2183.
[9] Boyacıoğlu, T., 2007. “Improvement of room temperature mechanical properties of various amount of metal oxide doping cubic zirconia (c-ZrO2) used as electrolyte material for solid oxide fuel cells,” Master thesis, Dept. Metallurg. Eng., Gazi Univ., Ankara.
[10] Boyraz, T., 1998. “Dental porcelain powders,” Master thesis, Dept. Metallurg. Eng., Sakarya Univ., Sakarya.

[11] Liu, P. F., Li, Z., Xiao, P., Luo, H. and Jiang, T. H., 2018. “Microstructure and mechanical properties of in-situ grown mullite toughened 3Y-TZP zirconia ceramics fabricated by gelcasting,” Ceramics International, 44(2), pp. 1394-1403.
[12] Eichler, J., Rödel, J., Eisele, U. and Hoffman, M., 2007. “Effect of grain size on mechanical properties of submicrometer 3Y‐TZP: fracture strength and hydrothermal degradation,” Journal of the American Ceramic Society, 90(9), pp. 2830-2836.
[13] Sun, J., Gao, L., Iwasa, M., Nakayama, T. and Niihara, K., 2005. “Failure investigation of carbon nanotube/3Y-TZP nanocomposites,” Ceramics International, 31(8), pp. 1131-1134.
[14] El Ouatib, R., Guillemet, S., Durand, B., Samdi, A., Rakho, L. E. and Moussa, R., 2005. “Reactivity of aluminum sulfate and silica in molten alkali-metal sulfates in order to prepare mullite,” Journal of the European Ceramic Society, 25(1), pp. 73-80.
[15] Kucuk, I. and Boyraz, T., 2019. “Structural and mechanical characterization of mullite and aluminium titanate reinforced yttria stabilized zirconia ceramic composites,” Journal of Ceramic Processing Research, 20(1), pp. 73-79.
[16] Kumar, P., Nath, M., Ghosh, A. and Tripathi, H. S., 2015. “Enhancement of thermal shock resistance of reaction sintered mullite–zirconia composites in the presence of lanthanum oxide,” Materials Characterization, 101, pp. 34-39.
[17] Roy, J., Das, S. and Maitra, S., 2015. “Solgel‐processed mullite coating—a review. International Journal of Applied Ceramic Technology, 12, pp. E71-E77.
[18] Denry, I. and Kelly, J. R., 2008. “State of the art of zirconia for dental applications,” Dental materials, 24(3), pp. 299-307.
[19] Çitak, E. and Boyraz, T., 2014. “Microstructural characterization and thermal properties of aluminium titanate/YSZ Ceramics,” Acta Physica Polonica A, 125(2), pp. 465-468.
[20] Önen, U. and Boyraz, T., 2014. “Microstructural characterization and thermal properties of aluminium titanate/spinel ceramic matrix composites,” Acta Phys. Pol. A, 125(2), pp. 488-490.
[21] Sacli, M., Onen, U. and Boyraz, T., 2015. “Microstructural characterization and thermal properties of aluminium titanate/porcelain ceramic matrix composites,” Acta Physica Polonica A, 127(4), pp. 1133-1135.
[22] Boyraz, T. and Akkuş, A., 2021. “Investigation of wear properties of mullite and aluminium titanate added porcelain ceramics,” Journal of Ceramic Processing Research. Vol. 22, No. 2, pp. 226-231.
[23] Akkus, A. and Boyraz, T., 2018. “Investigation of wear properties of CaO, MgO added stabilized zirconia ceramics produced by different pressing methods,” J. Ceram. Proc. Res., Vol. 19, pp. 249-252.
[24] Kucuk, I., Boyraz, T., Gökçe, H. and Öveçoğlu, M. L., 2018. “Thermomechanical properties of aluminium titanate (Al2TiO5)-reinforced forsterite (Mg2SiO4) ceramic composites,” Ceramics International, 44(7), pp. 8277-8282.
[25] Stawarczyk, B., Özcan, M., Hallmann, L., Ender, A., Mehl, A. and Hämmerlet, C. H., 2013. “The effect of zirconia sintering temperature on flexural strength, grain size, and contrast ratio,” Clinical oral investigations, 17(1), 269-274.
[26] Talay Çevlik, E., 2015. “Low thermal degradation of three yttria-stabilized tetragonal zirconia polycrystalline and effect of low thermal degradation on flexural strength,” Ph.D. dissertation, Dept. Dent., Selçuk Univ., Konya.
[27] Huang, Y. Q., Liu, P. F., Li, Z. and Xiao, P., 2018. “Effects of the content of insitu grown mullite on the microstructure and mechanical properties of 3Y-TZP ceramics fabricated by gel-casting,” Ceramics International, 44(17), pp. 21882- 21892.
[28] Liu, P. F., Li, Z., Xiao, P., Luo, H. and Jiang, T. H., 2018. “Microstructure and mechanical properties of in-situ grown mullite toughened 3Y-TZP zirconia ceramics fabricated by gelcasting,” Ceramics International, 44(2), pp. 1394-1403.

Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Mehmet Akif Hafızoğlu ^*
0000-0002-9689-3004
Türkiye

Tahsin Boyraz
0000-0003-4404-6388
Türkiye

Ahmet Akkuş
0000-0002-6881-9333
Türkiye

Publication Date

December 31, 2021

Submission Date

December 1, 2021

Acceptance Date

December 25, 2021

Published in Issue

Year 2021 Volume: 6 Number: 2

IZ

https://izlik.org/JA73WC76EA

APA

Hafızoğlu, M. A., Boyraz, T., & Akkuş, A. (2021). Fabrication and Characterization of Mullite Reinforced Y2O3 Added ZrO2 Ceramics. Open Journal of Nano, 6(2), 28-40. https://izlik.org/JA73WC76EA

AMA

1.Hafızoğlu MA, Boyraz T, Akkuş A. Fabrication and Characterization of Mullite Reinforced Y2O3 Added ZrO2 Ceramics. Open J. Nano. 2021;6(2):28-40. https://izlik.org/JA73WC76EA

Chicago

Hafızoğlu, Mehmet Akif, Tahsin Boyraz, and Ahmet Akkuş. 2021. “Fabrication and Characterization of Mullite Reinforced Y2O3 Added ZrO2 Ceramics”. Open Journal of Nano 6 (2): 28-40. https://izlik.org/JA73WC76EA.

EndNote

Hafızoğlu MA, Boyraz T, Akkuş A (December 1, 2021) Fabrication and Characterization of Mullite Reinforced Y2O3 Added ZrO2 Ceramics. Open Journal of Nano 6 2 28–40.

IEEE

[1]M. A. Hafızoğlu, T. Boyraz, and A. Akkuş, “Fabrication and Characterization of Mullite Reinforced Y2O3 Added ZrO2 Ceramics”, Open J. Nano, vol. 6, no. 2, pp. 28–40, Dec. 2021, [Online]. Available: https://izlik.org/JA73WC76EA

ISNAD

Hafızoğlu, Mehmet Akif - Boyraz, Tahsin - Akkuş, Ahmet. “Fabrication and Characterization of Mullite Reinforced Y2O3 Added ZrO2 Ceramics”. Open Journal of Nano 6/2 (December 1, 2021): 28-40. https://izlik.org/JA73WC76EA.

JAMA

1.Hafızoğlu MA, Boyraz T, Akkuş A. Fabrication and Characterization of Mullite Reinforced Y2O3 Added ZrO2 Ceramics. Open J. Nano. 2021;6:28–40.

MLA

Hafızoğlu, Mehmet Akif, et al. “Fabrication and Characterization of Mullite Reinforced Y2O3 Added ZrO2 Ceramics”. Open Journal of Nano, vol. 6, no. 2, Dec. 2021, pp. 28-40, https://izlik.org/JA73WC76EA.

Vancouver

1.Mehmet Akif Hafızoğlu, Tahsin Boyraz, Ahmet Akkuş. Fabrication and Characterization of Mullite Reinforced Y2O3 Added ZrO2 Ceramics. Open J. Nano [Internet]. 2021 Dec. 1;6(2):28-40. Available from: https://izlik.org/JA73WC76EA

The Open Journal of Nano(OJN) deals with information related to (but not limited to) physical, chemical and biological phenomena and processes ranging from molecular to microscale structures.

All publications in The Open Journal of Nano are licensed under the Attribution-NonCommercial 4.0 International (CC BY-NC 4.0) license.

Fabrication and Characterization of Mullite Reinforced Y2O3 Added ZrO2 Ceramics

Abstract

Keywords

Mullit Takviyeli Y2O3 Katkılı ZrO2 Seramiklerinin İmalatı ve Karakterizasyonu

Abstract

Keywords

Supporting Institution

Project Number

Thanks

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

IZ

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