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AN ADVANCED OXIDATION PROCESS : FENTON PROCESS

Year 2008, Volume: 14 Issue: 3, 229 - 236, 01.03.2008

Abstract

Biological wastewater treatment is not effective treatment method if raw wastewater contains toxic and refractory organics. Advanced oxidation processes are applied before or after biological treatment for the detoxification and reclamation of this kind of wastewaters. The advanced oxidation processes are based on the formation of powerful hydroxyl radicals. Among advanced oxidation processes Fenton process is one of the most promising methods. Because application of Fenton process is simple and cost effective and also reaction occurs in a short time period. Fenton process is applied for many different proposes. In this study, Fenton process was evaluated as an advanced oxidation process in wastewater treatment.

References

  • Alaton, İ. A. ve Gürses, F. 2004. Penisilin prokain G antibiyotik formülasyon atıksuyunun Fenton-benzeri ve Foto-fenton-benzeri ileri oksidasyon prosesleri ile arıtılabilirliğinin incelenmesi. Su Kirlenmesi ve Kontrolü Dergisi. (1), 11-16.
  • Anotai, J., Lu, M.C. and Chewpreecha, P. 2006. Kinetics of aniline degradation by Fenton and electro-fenton processes. Water Research. (9), 1841-1847.
  • Aydın, A.F. ve Sarıkaya, H.Z. 2002. Biyolojik proseslerle arıtılmış afyon alkaloidleri endüstrisi atıksularının fenton oksidasyonu ile ileri arıtımı, İTÜ Dergisi. 1 (1).
  • Azbar, N., Yonar, T. and Kestioğlu, K. 2004. Comparison of various advanced oxidation processes and chemical treatment methods for COD and color removal from a polyester and acetate fiber dyeing effluent. Chemosphere. 55, 35-43.
  • Badawy, M.I., Ghaly, M.Y. and Gad-Allah, T.A. 2006. Advanced oxidation processes for the removal of organo-phosphorus pesticides from wastewater. Desalination. 194, 166-175.
  • Barbeni, M., Minero, C., Pelizzetti, E., Borgarello, E. and Serpone, N. 1987. Chemical degradation of chlorophenols with Fenton's reagent (Fe2+ + H2O2). Chemosphere. 16, 2225–2237.
  • Benitez, F.J., Acero, J.L., Real, F.J., Rubio, F.J. and Leal, A.I. 2001. The role of hydroxyl radicals for the decomposition of p-hydroxy phenylacetic acid in aqueous solutions. Water Research 35, 1338-1343.
  • Bidga, R.J. 1995. Consider Fenton’s chemistry for wastewater treatment. Chemical Engineering Progress. 91 (12), 62-66.
  • Brillas, E., Mur, E., Sauleda, R., Sanchez, L., Peral, J., Domenech, X. and Casadi, J. 1998. Aniline mineralization by AOP's: anodic oxidation, photocatalysis, electro-Fenton and photoelectronFenton processes. Applied Catalysis B: Environmental. 16 (1), 31–42.
  • Burbano, A.A., Dionysiou, D.D., Suidan, M.T. and Richardson, T.L. 2005. Oxidation kinetics and effect of pH on the degradation of MTBE with Fenton reagent. Water Research. 39, 107-118.
  • Chiron, S., Fernandez-Alba, A., Rodriguez, A. and Garcia-Calvo, E. 2000. Pesticide chemical oxidation: State-of-the art. Water Research. (2), 366-377.
  • Çatalkaya, E.Ç., Bali, U. ve Şengül, F. 2004. Fenol’ün fotokimyasal yöntemlerle parçalanması ve mineralizasyonu. Su Kirlenmesi ve Kontrolü Dergisi. (3), 31-41.
  • Çokay, E. ve Şengül, F. 2006. Toksik kirleticilerin ileri oksidasyon prosesleri ile arıtımı. DEÜ., Fen ve Mühendislik Dergisi. (2), 1-9.
  • Diao, H.F., Li, X.Y., Gu, J.D., Shi, H.C. and Xie, Z.M. 2004. Electron microscopic investigation of the bactericidal action of electrochemical disinfection in comparision with chlorination, ozonation and Fenton reaction, Process Biochemistry. 39, 1421-1426.
  • Johnson, R., Pankow, J.F., Bender, D.A., Price, C.V. and Zogorski, J.S. 2000. MTBE-To what extent will past releases contaminate community water supply wells? Environmental Science and Technology. (9), 210-217.
  • Kang, N., Lee, D.S. and Yoon, J. 2002. Kinetic modeling of Fenton oxidation of phenol and monochlorophenols. Chemosphere. 47, 915–924.
  • Kang, S.F., Wang, T.H. and Lin, Y.H. 1999. Decolourization and degradation of 2,4dinitrophenol by Fenton's reagent. Journal of Environmental Science and Health A. 34, 935–950.
  • Kang, Y.W. and Hwang, K. 2000. Effect of reaction conditions on the oxidation efficiency in the fenton process. Water Research. (10), 2786-2790.
  • Khoufi, S., Aloui, F. and Sayadi, S. 2006. Treatment of olive oil mill wastewater by combined process electro-Fenton reaction and anaerobic digestion Water Research. (10) 2007-2016.
  • Kwon, B.G., Lee, D.S., Kang, N. and Yoon, J. 2004. Characteristics of p-chlorophenol oxidation by Fenton’s reagent. Water Research. (9), 2110-2118.
  • Lin, S.H. and Chang, C.C. 2000. Treatment of landfill leachate by combined electro-fenton oxidation and sequencing batch reactor method. Water Research. (17), 4243-4249.
  • Lin, S.H. and Lo, C.C. 1997. Fenton process for treatment of desizing wastewater. Water Research. 2050-2056.
  • Lin, S.H. and Peng, C.F. 1995. Treatment of textile wastewater by fenton’s reagent. Journal of Environmental Science and Health A. 30. 89-101.
  • Liou, M.J., Lu, M.C. and Chen, J.N. 2003. Oxidation of explosives by Fenton and photo-Fenton processes. Water Research. (13), 3172-3179.
  • Lipczynska-Kochany, E. 1991. Degradation of aqueous nitrophenols and nitrobenzene by means of the Fenton reaction. Chemosphere. 22, 529–536.
  • Lopez, A., Pagano, M., Volpe, A. and Pinto, A.C. 2004. Fenton’s pre-treatment of mature landfill leachate. Chemosphere. 54, 1005-1010.
  • Lucas, M.S. and Peres, J.A. 2006. Decolorization of the azo dye Reactive Black 5 by Fenton and photoFenton oxidation. Dyes and Pigments. 71, 236-244.
  • Lunar, L., Sicilia, D., Rubio, S., Perez-Bendito, D. and Nickel, U. 2000. Degradation of photographic developers by Fenton's reagent: condition optimization and kinetics for metol oxidation. Water Research. (6), 1791-1802.
  • Martinez, N.S.S, Fernandez, J.F., Segura, X.F. and Ferrer, A.S. 2003. Pre-oxidation of an extremely polluted industrial wastewater by the Fenton’s reagent, Journal of Hazardous Materials B101. 315-322.
  • Neyens, E. and Baeyens, J. 2003. A rewiev of classic Fenton’s peroxidation as an advanced oxidation technique. Journal of Hazardous Materials. B98 33-50.
  • Öztürk, İ. 1999. Anaerobik biyoteknoloji ve atık arıtımındaki uygulamaları. 320 s. Su Vakfı Yayınları.
  • Perez, M., Torrades, F., Hortal, J.A., Domenech, X. and Peral, J. 2002. Removal of organic contaminants in paper pulp treatment effluents under fenton and foto-fenton conditions. Applied Catalysis B: Environmental. (1), 63-74.
  • Potter, F.J. and Roth, J.A. 1993. Oxidation of chlorinated phenols using fenton reagent. Hazardous Waste and Hazardous Materials. (2), 151–170.
  • Rivas, F.J., Beltran, F.J., Carvalho, F., Acedo, B. and Gimeno, O. 2004. Stabilized leachates: sequential coagulation-flocculation + chemical oxidation process. Journal of Hazardous Materials. (1-2), 95-102.
  • Rivas, F.J., Beltran, F.J., Gimeno, O. and Alvarez, P. 2003. Optimisation of Fenton's reagent usage as a pre-treatment for fermentation brines. Journal of Hazardous Materials. (2-3), 277-290.
  • Rivas, F.J., Beltran, F.J., Gimeno, O. and Frades, J. 2001. Treatment of olive oil mill wastewater by Fenton's reagent. Journal of Agricultural and Food Chemistry. (4), 1873-1880.
  • Sevimli, M.F. 2005. Post-treatment of pulp and paper industry wastewater by advanced oxidation processes. Ozone: Science & Engineering. (1), 37-43.
  • Tambosi, J.L., Di Domenico, M. and Schirmer, W.N. 2006. Treatment of paper and pulp wastewater and removal of odorous compounds by a Fenton-like process at the pilot scale. Journal of Chemical Technology and Biotechnology. (8), 1426-1432.
  • Teel, A.M. and Watts, R. 2002. Degradation of carbon tetrachloride by modified Fenton’s reagent. Journal of Hazardous Materials B94. 179-189.
  • Xu, X.R., Zhao, Z.Y. and Li, X.Y. 2004. Chemical oxidative degradation of methyl tert-butyl ether in aqueous solution by Fenton's reagent. Chemosphere. (1), 73-79.
  • Yoon, J., Kim, S., Lee, D.S. and Huh, J. 2000. Characteristics of p-chlorophenol degradation by photo Fenton oxidation. Water Science and Technology. (3/4), 219–224.
  • Zoh, K.D. and Stenstrom, M.K. 2002. Fenton oxidation of hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) and octahydro-1,3,5,7-tetranitro-1,3,5,7tetrazocine (HMX). Water Research. (5), 1331-1341.

BİR İLERİ OKSİDASYON PROSESİ : FENTON PROSES

Year 2008, Volume: 14 Issue: 3, 229 - 236, 01.03.2008

Abstract

Atıksularda toksik ve kalıcı organiklerin bulunması durumunda biyolojik arıtımla yeterli verim elde edilememektedir. Bu tip atıksulardan toksisite ve organik yük giderimi için biyolojik arıtım öncesi ileri oksidasyon proseslerine dayanan kimyasal prosesler kullanılmaktadır. İleri oksidasyon prosesleri, hidroksil radikallerinin olusumuna dayanmaktadır. İleri oksidasyon proseslerinden biri olan Fenton proses, diger ileri oksidasyon prosesleriyle karsılastırıldıgında basit ve ekonomik olusu, kısa reaksiyon zamanı gerektirmesi gibi birçok avantaja sahiptir. Fenton proses, birçok farklı alanda uygulanmaktadır. Bu makalede, bir ileri oksidasyon prosesi olan Fenton proses incelenmistir.

References

  • Alaton, İ. A. ve Gürses, F. 2004. Penisilin prokain G antibiyotik formülasyon atıksuyunun Fenton-benzeri ve Foto-fenton-benzeri ileri oksidasyon prosesleri ile arıtılabilirliğinin incelenmesi. Su Kirlenmesi ve Kontrolü Dergisi. (1), 11-16.
  • Anotai, J., Lu, M.C. and Chewpreecha, P. 2006. Kinetics of aniline degradation by Fenton and electro-fenton processes. Water Research. (9), 1841-1847.
  • Aydın, A.F. ve Sarıkaya, H.Z. 2002. Biyolojik proseslerle arıtılmış afyon alkaloidleri endüstrisi atıksularının fenton oksidasyonu ile ileri arıtımı, İTÜ Dergisi. 1 (1).
  • Azbar, N., Yonar, T. and Kestioğlu, K. 2004. Comparison of various advanced oxidation processes and chemical treatment methods for COD and color removal from a polyester and acetate fiber dyeing effluent. Chemosphere. 55, 35-43.
  • Badawy, M.I., Ghaly, M.Y. and Gad-Allah, T.A. 2006. Advanced oxidation processes for the removal of organo-phosphorus pesticides from wastewater. Desalination. 194, 166-175.
  • Barbeni, M., Minero, C., Pelizzetti, E., Borgarello, E. and Serpone, N. 1987. Chemical degradation of chlorophenols with Fenton's reagent (Fe2+ + H2O2). Chemosphere. 16, 2225–2237.
  • Benitez, F.J., Acero, J.L., Real, F.J., Rubio, F.J. and Leal, A.I. 2001. The role of hydroxyl radicals for the decomposition of p-hydroxy phenylacetic acid in aqueous solutions. Water Research 35, 1338-1343.
  • Bidga, R.J. 1995. Consider Fenton’s chemistry for wastewater treatment. Chemical Engineering Progress. 91 (12), 62-66.
  • Brillas, E., Mur, E., Sauleda, R., Sanchez, L., Peral, J., Domenech, X. and Casadi, J. 1998. Aniline mineralization by AOP's: anodic oxidation, photocatalysis, electro-Fenton and photoelectronFenton processes. Applied Catalysis B: Environmental. 16 (1), 31–42.
  • Burbano, A.A., Dionysiou, D.D., Suidan, M.T. and Richardson, T.L. 2005. Oxidation kinetics and effect of pH on the degradation of MTBE with Fenton reagent. Water Research. 39, 107-118.
  • Chiron, S., Fernandez-Alba, A., Rodriguez, A. and Garcia-Calvo, E. 2000. Pesticide chemical oxidation: State-of-the art. Water Research. (2), 366-377.
  • Çatalkaya, E.Ç., Bali, U. ve Şengül, F. 2004. Fenol’ün fotokimyasal yöntemlerle parçalanması ve mineralizasyonu. Su Kirlenmesi ve Kontrolü Dergisi. (3), 31-41.
  • Çokay, E. ve Şengül, F. 2006. Toksik kirleticilerin ileri oksidasyon prosesleri ile arıtımı. DEÜ., Fen ve Mühendislik Dergisi. (2), 1-9.
  • Diao, H.F., Li, X.Y., Gu, J.D., Shi, H.C. and Xie, Z.M. 2004. Electron microscopic investigation of the bactericidal action of electrochemical disinfection in comparision with chlorination, ozonation and Fenton reaction, Process Biochemistry. 39, 1421-1426.
  • Johnson, R., Pankow, J.F., Bender, D.A., Price, C.V. and Zogorski, J.S. 2000. MTBE-To what extent will past releases contaminate community water supply wells? Environmental Science and Technology. (9), 210-217.
  • Kang, N., Lee, D.S. and Yoon, J. 2002. Kinetic modeling of Fenton oxidation of phenol and monochlorophenols. Chemosphere. 47, 915–924.
  • Kang, S.F., Wang, T.H. and Lin, Y.H. 1999. Decolourization and degradation of 2,4dinitrophenol by Fenton's reagent. Journal of Environmental Science and Health A. 34, 935–950.
  • Kang, Y.W. and Hwang, K. 2000. Effect of reaction conditions on the oxidation efficiency in the fenton process. Water Research. (10), 2786-2790.
  • Khoufi, S., Aloui, F. and Sayadi, S. 2006. Treatment of olive oil mill wastewater by combined process electro-Fenton reaction and anaerobic digestion Water Research. (10) 2007-2016.
  • Kwon, B.G., Lee, D.S., Kang, N. and Yoon, J. 2004. Characteristics of p-chlorophenol oxidation by Fenton’s reagent. Water Research. (9), 2110-2118.
  • Lin, S.H. and Chang, C.C. 2000. Treatment of landfill leachate by combined electro-fenton oxidation and sequencing batch reactor method. Water Research. (17), 4243-4249.
  • Lin, S.H. and Lo, C.C. 1997. Fenton process for treatment of desizing wastewater. Water Research. 2050-2056.
  • Lin, S.H. and Peng, C.F. 1995. Treatment of textile wastewater by fenton’s reagent. Journal of Environmental Science and Health A. 30. 89-101.
  • Liou, M.J., Lu, M.C. and Chen, J.N. 2003. Oxidation of explosives by Fenton and photo-Fenton processes. Water Research. (13), 3172-3179.
  • Lipczynska-Kochany, E. 1991. Degradation of aqueous nitrophenols and nitrobenzene by means of the Fenton reaction. Chemosphere. 22, 529–536.
  • Lopez, A., Pagano, M., Volpe, A. and Pinto, A.C. 2004. Fenton’s pre-treatment of mature landfill leachate. Chemosphere. 54, 1005-1010.
  • Lucas, M.S. and Peres, J.A. 2006. Decolorization of the azo dye Reactive Black 5 by Fenton and photoFenton oxidation. Dyes and Pigments. 71, 236-244.
  • Lunar, L., Sicilia, D., Rubio, S., Perez-Bendito, D. and Nickel, U. 2000. Degradation of photographic developers by Fenton's reagent: condition optimization and kinetics for metol oxidation. Water Research. (6), 1791-1802.
  • Martinez, N.S.S, Fernandez, J.F., Segura, X.F. and Ferrer, A.S. 2003. Pre-oxidation of an extremely polluted industrial wastewater by the Fenton’s reagent, Journal of Hazardous Materials B101. 315-322.
  • Neyens, E. and Baeyens, J. 2003. A rewiev of classic Fenton’s peroxidation as an advanced oxidation technique. Journal of Hazardous Materials. B98 33-50.
  • Öztürk, İ. 1999. Anaerobik biyoteknoloji ve atık arıtımındaki uygulamaları. 320 s. Su Vakfı Yayınları.
  • Perez, M., Torrades, F., Hortal, J.A., Domenech, X. and Peral, J. 2002. Removal of organic contaminants in paper pulp treatment effluents under fenton and foto-fenton conditions. Applied Catalysis B: Environmental. (1), 63-74.
  • Potter, F.J. and Roth, J.A. 1993. Oxidation of chlorinated phenols using fenton reagent. Hazardous Waste and Hazardous Materials. (2), 151–170.
  • Rivas, F.J., Beltran, F.J., Carvalho, F., Acedo, B. and Gimeno, O. 2004. Stabilized leachates: sequential coagulation-flocculation + chemical oxidation process. Journal of Hazardous Materials. (1-2), 95-102.
  • Rivas, F.J., Beltran, F.J., Gimeno, O. and Alvarez, P. 2003. Optimisation of Fenton's reagent usage as a pre-treatment for fermentation brines. Journal of Hazardous Materials. (2-3), 277-290.
  • Rivas, F.J., Beltran, F.J., Gimeno, O. and Frades, J. 2001. Treatment of olive oil mill wastewater by Fenton's reagent. Journal of Agricultural and Food Chemistry. (4), 1873-1880.
  • Sevimli, M.F. 2005. Post-treatment of pulp and paper industry wastewater by advanced oxidation processes. Ozone: Science & Engineering. (1), 37-43.
  • Tambosi, J.L., Di Domenico, M. and Schirmer, W.N. 2006. Treatment of paper and pulp wastewater and removal of odorous compounds by a Fenton-like process at the pilot scale. Journal of Chemical Technology and Biotechnology. (8), 1426-1432.
  • Teel, A.M. and Watts, R. 2002. Degradation of carbon tetrachloride by modified Fenton’s reagent. Journal of Hazardous Materials B94. 179-189.
  • Xu, X.R., Zhao, Z.Y. and Li, X.Y. 2004. Chemical oxidative degradation of methyl tert-butyl ether in aqueous solution by Fenton's reagent. Chemosphere. (1), 73-79.
  • Yoon, J., Kim, S., Lee, D.S. and Huh, J. 2000. Characteristics of p-chlorophenol degradation by photo Fenton oxidation. Water Science and Technology. (3/4), 219–224.
  • Zoh, K.D. and Stenstrom, M.K. 2002. Fenton oxidation of hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) and octahydro-1,3,5,7-tetranitro-1,3,5,7tetrazocine (HMX). Water Research. (5), 1331-1341.
There are 42 citations in total.

Details

Primary Language Turkish
Journal Section Research Article
Authors

Engin Gürtekin This is me

Nusret Şekerdağ This is me

Publication Date March 1, 2008
Published in Issue Year 2008 Volume: 14 Issue: 3

Cite

APA Gürtekin, E. ., & Şekerdağ, N. . (2008). BİR İLERİ OKSİDASYON PROSESİ : FENTON PROSES. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 14(3), 229-236.
AMA Gürtekin E, Şekerdağ N. BİR İLERİ OKSİDASYON PROSESİ : FENTON PROSES. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. March 2008;14(3):229-236.
Chicago Gürtekin, Engin, and Nusret Şekerdağ. “BİR İLERİ OKSİDASYON PROSESİ : FENTON PROSES”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 14, no. 3 (March 2008): 229-36.
EndNote Gürtekin E, Şekerdağ N (March 1, 2008) BİR İLERİ OKSİDASYON PROSESİ : FENTON PROSES. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 14 3 229–236.
IEEE E. . Gürtekin and N. . Şekerdağ, “BİR İLERİ OKSİDASYON PROSESİ : FENTON PROSES”, Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, vol. 14, no. 3, pp. 229–236, 2008.
ISNAD Gürtekin, Engin - Şekerdağ, Nusret. “BİR İLERİ OKSİDASYON PROSESİ : FENTON PROSES”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 14/3 (March 2008), 229-236.
JAMA Gürtekin E, Şekerdağ N. BİR İLERİ OKSİDASYON PROSESİ : FENTON PROSES. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. 2008;14:229–236.
MLA Gürtekin, Engin and Nusret Şekerdağ. “BİR İLERİ OKSİDASYON PROSESİ : FENTON PROSES”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, vol. 14, no. 3, 2008, pp. 229-36.
Vancouver Gürtekin E, Şekerdağ N. BİR İLERİ OKSİDASYON PROSESİ : FENTON PROSES. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. 2008;14(3):229-36.





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