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Asit turuncu II boyasının kitosan ve zirkonyum(IV)-kitosan üzerine adsorpsiyonunun karşılaştırılması

Yıl 2018, Cilt: 24 Sayı: 7, 1298 - 1303, 28.12.2018

Öz

Yaygın
olarak kullanılan bir biyopolimer olan kitosanın (Cht)   adsorpsiyon kapasitesini arttırmak amacıyla
zirkonyum (IV)-kitosan (Zr(IV)-Cht) kompoziti sentezlenmiş ve asit turuncu II
(T-II) sentetik boyası kullanılarak Cht ile adsorpsiyon kapasiteleri
karşılaştırılmıştır. Kesikli sistemde yapılan denemelerde Zr(IV) miktarı,
çözelti pH’ı, adsorban miktarı, temas süresi ve sıcaklıklığın T-II
adsorpsiyonuna olan etkileri incelenmiştir. Langmuir, Freundlich ve Temkin
izoterm modelleri denenerek elde edilen deneysel verilere en uygun cevap veren
izoterm modelinin Langmuir izoterm modeli olduğu bulunmuştur. Maksimum
adsorpsiyon kapasiteleri sırasıyla Cht için 256.41 mg/g ve Zr(IV)/Cht için
666.67 mg/g olarak bulunmuştur. Kinetik veriler yalancı-birinci dereceden ve
yalancı-ikinci dereceden kinetik modellerine uygulandığında yalancı-ikinci
dereceden kinetik modelinin en uygun olduğu sonucuna varılmıştır. Termodinamik
veriler ışığında, T-II adsorpsiyonunun hem Cht, hem de Zr(IV)/Cht için
endotermik olarak kendiliğinden gerçekleşen bir işlem olduğu belirlenmiştir.
Adsorpsiyon/desorpsiyon denemelerinde yedinci döngü sonunda  Cht’ın adsorpsiyon kapasitesi %65,
Zr(IV)-Cht’ın adsorpsiyon kapasitesinin %95 olduğu bulunmuştur. T-II
adsorpsiyonu için sentezlenen Zr(IV)-Cht kompoziti yüksek adsorpsiyon
kapasitesine sahip, ucuz ve toksik olmayan bir adsorban olarak boya gideriminde
kullanılabileceği sonucuna varılmıştır.

Kaynakça

  • Luo F, Chen Z, Megharaj M, Naidu R. “One-step green synthesis of bimetallic Fe/Pd nanoparticles used to degrade Orange II”. Journal of Hazardous Materials, 303, 145-153, 2016.
  • Kousha M, Daneshvar E, Sohrabi MS, Jokar M, Bhatnagar A. “Adsorption of acid orange II dye by raw and chemically modified Brown macroalga Stoechospermum marginatum”. Chemical Engineering Journal, 192, 67-76, 2012.
  • Nam S, Tratnyek PG. “Reduction of azo dyes with zero-valent iron”. Water Resources, 38(6), 565-571, 1999.
  • Mondal S. “Methods of dye removal from dye house effluent: An overview”. Environmental Engineering Science, 25(3), 383-396, 2008.
  • Gupta VK. “Application of low cost adsorbents for dye removal: A review”. Journal of Environmental Management, 90(8), 2313-2342, 2009.
  • Verma AK, Dash RR, Bhunia P. “A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters”. Journal of Environmental Management, 93(1), 154-168, 2012.
  • Sowmya A, Meenakshi S. “Zr(IV) loaded cross-linked chitosan beads with enhanced surface area for the removal of nitrate and phosphate”. International Journal of Biological Macromolecules, 69, 336-343, 2014.
  • Liu Q, Zhang L, Yang B, Huang R. “Removal of fluoride from aqueous solution using Zr(IV) immobilized cross-linked chitosan”. International Journal of Biological Macromolecules, 77, 15-23, 2015.
  • Viswanathan N, Meenakshi S. “Synthesis of Zr(IV) entrapped chitosan biopolymeric matrix for selective flüoride sorption”. Colloids and Surfaces B: Biointerfaces, 72(1), 88-93, 2009.
  • Zhang L, Xia W, Teng B, Liu X, Zhang W. “Zirconium-cross-linked chitosan composite: preparation, characterization and application in adsorption of Cr(VI)”. Chemical Engineering Journal, 229, 1-8, 2013.
  • Liu Q, Hu P, Wang J, Zhang L, Huang R. “Phosphate adsorption from aqueous solutions by Zirconium(IV) loaded cross-linked chitosan particles”. Journal of Taiwan Institue of Chemical Engineers, 59, 311-319, 2016.
  • Zhang L, Hu P, Wang J, Huang R. “Adsorption of amido black 10B from aqueous solutions onto Zr (IV) surface-immobilized cross-linked chitosan/bentonite composite”. 369, 558-566, 2016.
  • Jin X, Yu B, Chen Z, Arocena JM, Thring RW. “Adsorption of Orange II dye in aqueous solution onto surfactant-coated zeolite: Characterization, kinetic and thermodynamic studies”. Journal of Colloid and Interface Science, 435, 15-20, 2014.
  • Luo F, Yang D, Chen Z, Megharaj M,.Naidu R. “One-step gren synthesis of bimetallic Fe/Pd nanoparticles used to degrade Orange II”. Journal of Hazardous Materials, 303, 145-153, 2016.
  • Inchaurrondo N, Font J, Ramos CP, Haure P. “Natural diotomites: Efficient gren catalyst for Fenton-like oxidation of Orange II”. Aplied Catalysis B: Environmental, 181, 481-494, 2016.
  • Zhang L, Cheng Z, Guo X, Jiang X, Liu R. “Process optimization, kinetics and equilibrium of Orange G and acid Orange 7 adsorpstions onto chitosan/surfactant”. Journal of Molecular Liquids, 197, 353-367, 2014.

Comparison of adsorption of acid orange II dye on chitosan and zirconium(IV)-chitosan

Yıl 2018, Cilt: 24 Sayı: 7, 1298 - 1303, 28.12.2018

Öz

To
increase the adsorption capacity of chitosan (Cht), which is an abundant
biopolymer, zirconium (IV)-chitosan (Zr(IV)-Cht) composite was synthesized and
adsorption capacity was compared with Cht using acid orange II (T-II).
Batch studies were conducted to analyze the effect of
Zr (IV) loading amount, solution pH, adsorbent dosage, contact time and
temperature on T-II adsorption.
The best responding isotherm model to the
experimental data was found
Langmuir
adsorption isotherm model by analyzing
Langmuir, Freundlich and
Temkin isotherm models.
The
maximum adsorption capacities were found as
256.41 mg/g and 666.67 mg/g for Cht and Zr(IV)-Cht, respectively. Application of kinetic data
to the pseudo-first order and pseudo-second order kinetic models, pseudo-second
order model was the best-fitted model for the kinetic data. The adsorption
process was found endothermic and spontaneously occurred for both Cht and
Zr(IV)-Cht. According to adsorption/desorption experiments, after seventh cycle
adsorption capacities were found 65% for Cht and 95% for Zr(IV)-Cht. The
synthesized Zr(IV)-Cht composite was found as the high adsorption capacity,
low-cost and non-toxic material for T-II adsorption and can be used for dye
adsorption.

Kaynakça

  • Luo F, Chen Z, Megharaj M, Naidu R. “One-step green synthesis of bimetallic Fe/Pd nanoparticles used to degrade Orange II”. Journal of Hazardous Materials, 303, 145-153, 2016.
  • Kousha M, Daneshvar E, Sohrabi MS, Jokar M, Bhatnagar A. “Adsorption of acid orange II dye by raw and chemically modified Brown macroalga Stoechospermum marginatum”. Chemical Engineering Journal, 192, 67-76, 2012.
  • Nam S, Tratnyek PG. “Reduction of azo dyes with zero-valent iron”. Water Resources, 38(6), 565-571, 1999.
  • Mondal S. “Methods of dye removal from dye house effluent: An overview”. Environmental Engineering Science, 25(3), 383-396, 2008.
  • Gupta VK. “Application of low cost adsorbents for dye removal: A review”. Journal of Environmental Management, 90(8), 2313-2342, 2009.
  • Verma AK, Dash RR, Bhunia P. “A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters”. Journal of Environmental Management, 93(1), 154-168, 2012.
  • Sowmya A, Meenakshi S. “Zr(IV) loaded cross-linked chitosan beads with enhanced surface area for the removal of nitrate and phosphate”. International Journal of Biological Macromolecules, 69, 336-343, 2014.
  • Liu Q, Zhang L, Yang B, Huang R. “Removal of fluoride from aqueous solution using Zr(IV) immobilized cross-linked chitosan”. International Journal of Biological Macromolecules, 77, 15-23, 2015.
  • Viswanathan N, Meenakshi S. “Synthesis of Zr(IV) entrapped chitosan biopolymeric matrix for selective flüoride sorption”. Colloids and Surfaces B: Biointerfaces, 72(1), 88-93, 2009.
  • Zhang L, Xia W, Teng B, Liu X, Zhang W. “Zirconium-cross-linked chitosan composite: preparation, characterization and application in adsorption of Cr(VI)”. Chemical Engineering Journal, 229, 1-8, 2013.
  • Liu Q, Hu P, Wang J, Zhang L, Huang R. “Phosphate adsorption from aqueous solutions by Zirconium(IV) loaded cross-linked chitosan particles”. Journal of Taiwan Institue of Chemical Engineers, 59, 311-319, 2016.
  • Zhang L, Hu P, Wang J, Huang R. “Adsorption of amido black 10B from aqueous solutions onto Zr (IV) surface-immobilized cross-linked chitosan/bentonite composite”. 369, 558-566, 2016.
  • Jin X, Yu B, Chen Z, Arocena JM, Thring RW. “Adsorption of Orange II dye in aqueous solution onto surfactant-coated zeolite: Characterization, kinetic and thermodynamic studies”. Journal of Colloid and Interface Science, 435, 15-20, 2014.
  • Luo F, Yang D, Chen Z, Megharaj M,.Naidu R. “One-step gren synthesis of bimetallic Fe/Pd nanoparticles used to degrade Orange II”. Journal of Hazardous Materials, 303, 145-153, 2016.
  • Inchaurrondo N, Font J, Ramos CP, Haure P. “Natural diotomites: Efficient gren catalyst for Fenton-like oxidation of Orange II”. Aplied Catalysis B: Environmental, 181, 481-494, 2016.
  • Zhang L, Cheng Z, Guo X, Jiang X, Liu R. “Process optimization, kinetics and equilibrium of Orange G and acid Orange 7 adsorpstions onto chitosan/surfactant”. Journal of Molecular Liquids, 197, 353-367, 2014.
Toplam 16 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Makale
Yazarlar

Pelin Demirçivi Bu kişi benim 0000-0002-1068-9310

Yayımlanma Tarihi 28 Aralık 2018
Yayımlandığı Sayı Yıl 2018 Cilt: 24 Sayı: 7

Kaynak Göster

APA Demirçivi, P. (2018). Asit turuncu II boyasının kitosan ve zirkonyum(IV)-kitosan üzerine adsorpsiyonunun karşılaştırılması. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 24(7), 1298-1303.
AMA Demirçivi P. Asit turuncu II boyasının kitosan ve zirkonyum(IV)-kitosan üzerine adsorpsiyonunun karşılaştırılması. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. Aralık 2018;24(7):1298-1303.
Chicago Demirçivi, Pelin. “Asit Turuncu II boyasının Kitosan Ve zirkonyum(IV)-Kitosan üzerine Adsorpsiyonunun karşılaştırılması”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 24, sy. 7 (Aralık 2018): 1298-1303.
EndNote Demirçivi P (01 Aralık 2018) Asit turuncu II boyasının kitosan ve zirkonyum(IV)-kitosan üzerine adsorpsiyonunun karşılaştırılması. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 24 7 1298–1303.
IEEE P. Demirçivi, “Asit turuncu II boyasının kitosan ve zirkonyum(IV)-kitosan üzerine adsorpsiyonunun karşılaştırılması”, Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, c. 24, sy. 7, ss. 1298–1303, 2018.
ISNAD Demirçivi, Pelin. “Asit Turuncu II boyasının Kitosan Ve zirkonyum(IV)-Kitosan üzerine Adsorpsiyonunun karşılaştırılması”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 24/7 (Aralık 2018), 1298-1303.
JAMA Demirçivi P. Asit turuncu II boyasının kitosan ve zirkonyum(IV)-kitosan üzerine adsorpsiyonunun karşılaştırılması. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. 2018;24:1298–1303.
MLA Demirçivi, Pelin. “Asit Turuncu II boyasının Kitosan Ve zirkonyum(IV)-Kitosan üzerine Adsorpsiyonunun karşılaştırılması”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, c. 24, sy. 7, 2018, ss. 1298-03.
Vancouver Demirçivi P. Asit turuncu II boyasının kitosan ve zirkonyum(IV)-kitosan üzerine adsorpsiyonunun karşılaştırılması. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. 2018;24(7):1298-303.





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