Investigation of Corrosion Behavior of Powder Metallurgy Materials Produced From DistaloyAB Powders and Electrochemically Coated Chromium With Diamond Nanopartical Additive
Year 2017,
Volume: 20 Issue: 1, 223 - 230, 01.03.2017
E. Zeynep Bilgili
Elmas Salamcı
,
Abdurrahman Asan
Abstract
In this study, 0,2% and %0,5 carbon added DistaloyAB metal powders were pressed under 420 MPa compression and sintered. The specimens produced were coated with diamond nanoparticle added chromium using electrochemical method. The coated and uncoated specimens were compared and the effect of coating on the microstructure, and corrosion behavior of the powder metal specimens was studied. The specimens were examined with scanning electron microscope (SEM) and atomic force microscopy (AFM). Their corrosion rates were measured in 0,1 M H2SO4 and 0,1M NaOH solutions by applying Tafel extrapolation method. The experimental results showed that coating of powder specimens with diamond nanoparticles added chromium decreases corrosion rate the samples.
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DistaloyAB Tozundan Üretilmiş ve Elmas Nanoparçacık Katkılı Krom Kaplanmış Toz Metal Malzemelerin Korozyon Davranışlarının Araştırılması
Year 2017,
Volume: 20 Issue: 1, 223 - 230, 01.03.2017
E. Zeynep Bilgili
Elmas Salamcı
,
Abdurrahman Asan
Abstract
Bu çalışmada; iki farklı kimyasal bileşimdeki DistaloyAB tozlarından üretilen numunelere uygulanan nanoelmas ilaveli krom elektrokaplama işleminin numunelerin mikroyapı ve korozyon davranışına etkisi incelenmiştir. % 0,2 ve % 0,5 karbon ilaveli DistaloyAB tozları 420 MPa basınçta sıkıştırılmış ve sinterlenmiştir. Üretilen numunelerin SEM ve AFM incelemesi ve korozyon testleri yapılmıştır. Numunelerin korozyon hızları 0,1M H2SO4 ve 0,1M NaOH çözeltilerinde, Tafel ekstrapolasyonu yöntemi ile ölçülmüştür. Deneysel sonuçlar, toz metal numunelerin nanoelmas ilaveli krom ile kaplanması ile korozyon hızlarında önemli azalmalar olduğunu göstermiştir.
References
- 1. Etaat, M., Emamy, M., Ghambari, M. and Fadaei, E., “Surface treatment and nickel plating of iron powder metallurgy parts for corrosion protection”, Materials and Design, 30: 3560–3565, (2009).
- 2. Etaat, M., Emamy, M., Ghambari, M., and Fadaei, E. (2009). Surface treatment and nickel plating of iron powder metallurgy parts for corrosion protection. Materials & Design, 30(9): 3560-3565.
- 3. Vinokurov, E. G., Arsenkin, A. M., Grigorovich, K. V. and Bondar, V. V., “Electrodeposition and Physico-Mechanical Properties of Chromium Coatings Modified with Disperse Particles”, Protection of Metals, 42: 290–294, (2006).
- 4. Gidikova, N., Cias, A., Petkov, V., Madej, M., Sułowski, M. and Valov, R., “Wear Resistant Chromium Coatings Modified with Diamond Nanoparticles”, Archives of Metallurgy and Materials, 59: 1513-1516, (2014).
- 5. Isakov, V. P., Lyamkin, A. I., Nikitin, D. N., Shalimova, A. S. and Solntsev, A.V., “Structure and Properties of Chromium-Nanodiamond Composite Electrochemical Coatings”, Protection of Metals and Physical Chemistry of Surfaces, 46: 578-581, (2010).
- 6. Tikhonov, K. I., Burkat, G. K., Dolmatov, V. Y. and Orlova, E. A., “Use of Diamond Stock in Chromium Plating”, Russian Journal of Applied Chemistry, 80: 1082-1086, (2007).
- 7. Nguyen, V., Hoang, T., Nguyen, N., Kwon, S., Kım, M. and Lee, J., “Cr/nanodiamond composite plating with cobalt cation additive”, Transaction of Nonferrous Metals Socity of China, 19: 975-978, (2009).
- 8. Bekoz, N. and Oktay, E., “The role of pore wall microstructure and micropores on the mechanical properties of Cu–Ni–Mo based steel foams”, Materials Science and Engineering: A, 612: 387–397 (2014).
- 9. Beyragh, S., Asl, K. and Norouzi, S., “A comparative research on corrosion behavior of a standard, crack-free and duplex hard chromium coatings” Surface & Coatings Technology, 205: 2605–2610, (2010).
- 10. Kanani, N., Raj, L., Sathishkumar, J., Kumaragurubaran, B. and Gopal, P., Electroplating: Basic Principles Processes and Practice (1). The Netherlands: Elsevier, 1-213. (2004).
- 11. Sarıtaş, S., Türker, M. and Durlu, N. (Editörler), “Toz Metalurjisi ve Parçacıklı Malzeme İşlemleri”, Türk Toz Metalurjisi Derneği Yayınları, 1-504, (2007).
- 12. Mandich, N. V. and Dennis, J. K., “Codeposition of Nanodiamond with Chromium”, Metal Finishing, 99: 117-119, (2001).
- 13. Doruk, M., “Metalik Malzemeler ve Korozyon”, Korozyon Derneği, 1-500, (2014).
- 14. Nguyen, V., Hoang, T., Nguyen, N., Kwon, S., Kim, M. and Lee, J., “Cr/nanodiamond composite plating with cobalt cation additive”, Transactions of Nonferrous Metals society of China, 19: 975-978, (2009).