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Hegzagonal Bor Nitrürün Floresans Özelliği

Year 2024, EARLY VIEW, 1 - 1

Abstract

Bu çalışma, ileri bor uç ürünlerinden hekzagonal bor nitrürün (h-BN) ultraviyole-görünür (UV-visible), XRD, FTIR spektrumları ve SEM görüntüleri kullanılarak floresans özelliğini içermektedir. Karakterizasyon sonuçlarına göre h-BN’nin, yaprak deseni andıran bal peteği görünümündeki h-BN’nin tabakalı yapısı elde edildi. Deneysel çalışmada pelet haline getirilen bor nitrür, nem ve organik safsızlıkları uzaklaştırmak için 800 K’de 12h vakumlandıktan sonra optik absorbsiyon ve floresans ölçümleri gerçekleştirilmiştir. Karakterizasyon sonuçlarının literatür ile uyumlu olduğu ve h-BN’nin yarı-iletken özellik gösterdiği sonucuna varılmış ve elektrik-elektronik uygulamalarında kullanımına uygun bulunmuştur.

References

  • [1] Yacobi, B.G., “Semiconductor Materials: An Introduction to Basic Principles”, Springer Verlag, 1-3, (2003).
  • [2] Nic, M., Jirat, J., Kosata, B., “Chemical terminology at your fingertips”, Chemistry international, 28(6), 28, (2006).
  • [3] Vettoor, S.,“Electrical Conduction and Superconductivity”, Resonance, Cilt 08, No. 09, 41-48, 2003.
  • [4] Kittel, C.,“Introduction to Solid State Physics”, Wiley, 08, Kasım 2004.
  • [5] Beiranvand, R., and Valedbagi, S., “Electronic and optical properties of h-BN nanosheet: A first principles calculation”, Diamond and Related Materials, 58, 190-195, (2015).
  • [6] Eichler, J., and Lesniak, C., “Boron nitride (BN) and BN composites for high-temperature applications”, Journal of the European Ceramic Society, 28(5), 1105-1109, (2008).
  • [7] Jalilian, J., and Safari, M., “Tuning of the electronic and optical properties of single-layer boron nitride by strain and stres”, Diamond and Related Materials, 66, 163-170, (2016).
  • [8] Lipp, A., Schwetz, K. A., and Hunold, K., “Hexagonal boron nitride: fabrication, properties and applications”, Journal of the European Ceramic Society, 5(1), 3-9, (1989).
  • [9] Dana, S. S., “The properties of low pressure chemical vapor deposited boron nitride thin films”, In Materials Science Forum (Vol. 54, pp. 229-260). Trans Tech Publications Ltd., (1990).
  • [10] Chkhartishvili, L., Tabatadze, G., Nackebia, D., Bzhalava, T., and Kalandadze, I., “Hexagonal boron nitride as a solid lubricant additive (an overview)”, Nano Stud, 14, 91-98, (2016).
  • [11] Canöz, B., Metin, A. Ü., ve Gürü, M,. “Mekanokimyasal Yöntemle Elementlerinden Magnezyum Diborür (MgB2) Sentezi ve Enerjetik Madde Olarak Kullanımı”, Journal of Polytechnic, 24(3), 933-941, (2021).
  • [12] Çelik Ü. A., Sunar T., Özyürek D. ve Gürü M., “Production and Characterization of FeB and Fe2B Compounds by Mechanochemical Method”, Journal of Polytechnic, 1-1, (2023).
  • [13] Murathan, Ö. F., Kocatepe, K., and Erdoğan, M. “The effect of high boron additions on the microstructure of cast steel”, Journal of Boron, 5(2), 108-114, (2020).
  • [14] Pul M. ve Baydaroğlu V., “B4C/SiC katkılı alüminyum esaslı kompozitlerin mekanik özelliklerin incelenmesi ve balistik performanslarının modellenmesi”, Journal of Polytechnic, 23(2): 383-392, (2020).
  • [15] Aydın, Y. D., Gürü, M., and Akkurt, M., “Investigation Of Synthesis Parameters Of Antimony Fluoroborate And Its Usability As A Flame Retardant For Cellulosic Fabrics”, Cellulose Chem. Technol, 55(7-8), 893-900, (2021).
  • [16] Olgun Ş., Gürü M., Aydın D. Y. ve Ertürk A. A., “Fenol ve bor esaslı çevre dostu pigmentin deniz araçlarında boya olarak kullanılabilirliği”, Journal of Polytechnic, 26(1): 215-221, (2023).
  • [17] Arslan, K., Murathan, A. M., ve Murathan, H. B., Bor Nitrür Mikrotüp (BNMT) Sentezinde Reaksiyon Süresinin Etkisi, Journal of the Faculty of Engineering and Architecture of Gazi University, 32:3 977-986, (2017).
  • [18] Arslan, K., Seval, H. K., Murathan, Ö. F., and Soysal, K., “Multiwalled boron nitride microtubes (BNMTs) shielding in thermal neutron absorbing”. Radiation Effects and Defects in Solids, 173(7-8), 555-566, (2018).
  • [19] Kubota Y.,Watanabe K., Tsuda O. And Taniguchi T., “Deep Ultraviolet Light-Emitting Hexagonal Boron Nitride Synthesized at Atmospheric Pressure”, Science Magazine, 317 (5840): 932- 934 , (2007).
  • [20] Song, L., Ci, L., Lu, H., Sorokin, P. B., Jin, C., Ni, J., Kvashnin, A. G., Kvashnin, D. G., Lou, J., Yakobson B. I., and Ajayan, P. M., “Large scale growth and characterization of atomic hexagonal boron nitride layers”, Nano letters, 10(8), 3209-3215, (2010).
  • [21] Solozhenko, V. L.,Lazarenko, A. G.,Petitet, J. P. and Kanaev, A. V.,“Photoluminescence properties of pyrolytic boron nitride”, Journal of Phys. Chem. Solids, 62: 1331, (2001).
  • [22] Chen, T. M., Xiao, J., and Yang, G. W. Cubic boron nitride with an intrinsic peroxidase-like activity. RSC advances, 6(74), 70124-70132, (2016).
  • [23] Muthu, R. N., Rajashabala, S., and Kannan, R., “Hydrogen storage performance of lithium borohydride decorated activated hexagonal boron nitride nanocomposite for fuel cell applications”, International Journal of Hydrogen Energy, 42(23), 15586-15596, (2017).
  • [24] Kanaev A. V., Petitet, J. P. , Museur, L., Marine, V.. Solozhenko, V. L. and Zafiropulos, V. ,“Formation of c- BN nano crystals by He+ implantations of h- BN”, Journal of Appl. Phys., 96: 4483- 4489, (2004).
  • [25] Mohsin, M. H., Khashan, K. S., and Sulaiman, G. M., “Optical and structural properties of H-BN@ Gd2O3 nanoflake prepared by laser–induced ablation in liquid”, Physica Scripta, 98(5), 055903, (2023).
  • [26] Li, J.,Bernard, S.,Salles, V.,Gervaisand, C., Miele, P., “Preparation of Polyborazylene-Derived Bulk Boron Nitride with Tunable Properties by Warm-Pressing and Pressureless Pyrolysis”, Chem. Mater, 22, (2010).
  • [27] Guerra, V., Wan, C., Degirmenci, V., Sloan, J., Presvytis, D., and McNally, T., “2D boron nitride nanosheets (BNNS) prepared by high-pressure homogenisation: structure and morphology”, Nanoscale, 10(41), 19469-19477, (2018).
  • [28] Wang, Z., Zhu, Y., Ji, D., Li, Z., and Yu, H., “Scalable Exfoliation and High‐Efficiency Separation Membrane of Boron Nitride Nanosheets”, ChemistrySelect, 5(12), 3567-3573, (2020).
  • [29] Chakrabarty, K., Arnold, I., and Catledge, S. A., “Hexagonal boron nitride grown using high atomic boron emission during microwave plasma chemical vapor deposition”, Journal of Vacuum Science and Technology A: Vacuum, Surfaces, and Films, 37(6), 061507, (2019).
  • [30] Hu, S. Q., Wang, Y., and Liu, L. L., “Synthesis of h-BN by the Combustion of B/KNO3/Octogen Mixture under Nitrogen Atmosphere”, Journal of Chemistry, 2019, (2019).
  • [31] Huang J. ve Zhu Y. T., “Advances in the Synthesis and Characterisation of Boron Nitride”, Defect and Diffusion Forum, 186-187, 1-32, (2000).
  • [32] Gao L. ve Li J., “Preparation of Nanostructured Hexagonal Boron Nitride Powder”, Journal of American Ceramic Society, 111: 1982- 1984, (2003).
  • [33] Meng, Y., Mao, H. K., Eng, P. J., Trainor, T. P., Newville, M., Hu, M. Y., Kao, C., Shu, J., Hausermann, D., and Hemley, R. J., “The formation of sp3 bonding in compressed BN”, Nature materials, 3(2), 111-114, (2004).
  • [34] Thangasamy, P., and Sathish, M., “Supercritical fluid processing: a rapid, one-pot exfoliation process for the production of surfactant-free hexagonal boron nitride nanosheets”, Cryst Eng Comm, 17(31), 5895-5899, (2015).
  • [35] Ulus, H., Üstün, T., Eskizeybek, V., Şahin, Ö. S., Avcı, A., and Ekrem, M., “Boron nitride-MWCNT/epoxy hybrid nanocomposites: Preparation and mechanical properties”, Applied Surface Science, 318, 37-42, (2014).
  • [36] Naclerio, A. E., and Kidambi, P. R., “A review of scalable hexagonal boron nitride (h‐BN) synthesis for present and future applications”. Advanced Materials, 35(6), 2207374, (2023).

Florecence Properties of Hexagonal Boron Nitride

Year 2024, EARLY VIEW, 1 - 1

Abstract

This study contained florescence properties of hexagonal boron nitride (h-BN) which is an advanced boron product by using ultra violet-visible (UV-visible), XRD, FTIR, SEM. According to characterization results, it was obtained sheet-like honeycomb layered structure of boron nitride. In the experimental study, optical absorption and fluorescence measurements were performed after the pelleted boron nitride was vacuumed at 800 K for 12 hours to remove moisture and organic impurities. It was concluded that the characterization results were concordant with the literature and h-BN showed semi-conductive properties and was found suitable for use in electrical-electronic applications.

References

  • [1] Yacobi, B.G., “Semiconductor Materials: An Introduction to Basic Principles”, Springer Verlag, 1-3, (2003).
  • [2] Nic, M., Jirat, J., Kosata, B., “Chemical terminology at your fingertips”, Chemistry international, 28(6), 28, (2006).
  • [3] Vettoor, S.,“Electrical Conduction and Superconductivity”, Resonance, Cilt 08, No. 09, 41-48, 2003.
  • [4] Kittel, C.,“Introduction to Solid State Physics”, Wiley, 08, Kasım 2004.
  • [5] Beiranvand, R., and Valedbagi, S., “Electronic and optical properties of h-BN nanosheet: A first principles calculation”, Diamond and Related Materials, 58, 190-195, (2015).
  • [6] Eichler, J., and Lesniak, C., “Boron nitride (BN) and BN composites for high-temperature applications”, Journal of the European Ceramic Society, 28(5), 1105-1109, (2008).
  • [7] Jalilian, J., and Safari, M., “Tuning of the electronic and optical properties of single-layer boron nitride by strain and stres”, Diamond and Related Materials, 66, 163-170, (2016).
  • [8] Lipp, A., Schwetz, K. A., and Hunold, K., “Hexagonal boron nitride: fabrication, properties and applications”, Journal of the European Ceramic Society, 5(1), 3-9, (1989).
  • [9] Dana, S. S., “The properties of low pressure chemical vapor deposited boron nitride thin films”, In Materials Science Forum (Vol. 54, pp. 229-260). Trans Tech Publications Ltd., (1990).
  • [10] Chkhartishvili, L., Tabatadze, G., Nackebia, D., Bzhalava, T., and Kalandadze, I., “Hexagonal boron nitride as a solid lubricant additive (an overview)”, Nano Stud, 14, 91-98, (2016).
  • [11] Canöz, B., Metin, A. Ü., ve Gürü, M,. “Mekanokimyasal Yöntemle Elementlerinden Magnezyum Diborür (MgB2) Sentezi ve Enerjetik Madde Olarak Kullanımı”, Journal of Polytechnic, 24(3), 933-941, (2021).
  • [12] Çelik Ü. A., Sunar T., Özyürek D. ve Gürü M., “Production and Characterization of FeB and Fe2B Compounds by Mechanochemical Method”, Journal of Polytechnic, 1-1, (2023).
  • [13] Murathan, Ö. F., Kocatepe, K., and Erdoğan, M. “The effect of high boron additions on the microstructure of cast steel”, Journal of Boron, 5(2), 108-114, (2020).
  • [14] Pul M. ve Baydaroğlu V., “B4C/SiC katkılı alüminyum esaslı kompozitlerin mekanik özelliklerin incelenmesi ve balistik performanslarının modellenmesi”, Journal of Polytechnic, 23(2): 383-392, (2020).
  • [15] Aydın, Y. D., Gürü, M., and Akkurt, M., “Investigation Of Synthesis Parameters Of Antimony Fluoroborate And Its Usability As A Flame Retardant For Cellulosic Fabrics”, Cellulose Chem. Technol, 55(7-8), 893-900, (2021).
  • [16] Olgun Ş., Gürü M., Aydın D. Y. ve Ertürk A. A., “Fenol ve bor esaslı çevre dostu pigmentin deniz araçlarında boya olarak kullanılabilirliği”, Journal of Polytechnic, 26(1): 215-221, (2023).
  • [17] Arslan, K., Murathan, A. M., ve Murathan, H. B., Bor Nitrür Mikrotüp (BNMT) Sentezinde Reaksiyon Süresinin Etkisi, Journal of the Faculty of Engineering and Architecture of Gazi University, 32:3 977-986, (2017).
  • [18] Arslan, K., Seval, H. K., Murathan, Ö. F., and Soysal, K., “Multiwalled boron nitride microtubes (BNMTs) shielding in thermal neutron absorbing”. Radiation Effects and Defects in Solids, 173(7-8), 555-566, (2018).
  • [19] Kubota Y.,Watanabe K., Tsuda O. And Taniguchi T., “Deep Ultraviolet Light-Emitting Hexagonal Boron Nitride Synthesized at Atmospheric Pressure”, Science Magazine, 317 (5840): 932- 934 , (2007).
  • [20] Song, L., Ci, L., Lu, H., Sorokin, P. B., Jin, C., Ni, J., Kvashnin, A. G., Kvashnin, D. G., Lou, J., Yakobson B. I., and Ajayan, P. M., “Large scale growth and characterization of atomic hexagonal boron nitride layers”, Nano letters, 10(8), 3209-3215, (2010).
  • [21] Solozhenko, V. L.,Lazarenko, A. G.,Petitet, J. P. and Kanaev, A. V.,“Photoluminescence properties of pyrolytic boron nitride”, Journal of Phys. Chem. Solids, 62: 1331, (2001).
  • [22] Chen, T. M., Xiao, J., and Yang, G. W. Cubic boron nitride with an intrinsic peroxidase-like activity. RSC advances, 6(74), 70124-70132, (2016).
  • [23] Muthu, R. N., Rajashabala, S., and Kannan, R., “Hydrogen storage performance of lithium borohydride decorated activated hexagonal boron nitride nanocomposite for fuel cell applications”, International Journal of Hydrogen Energy, 42(23), 15586-15596, (2017).
  • [24] Kanaev A. V., Petitet, J. P. , Museur, L., Marine, V.. Solozhenko, V. L. and Zafiropulos, V. ,“Formation of c- BN nano crystals by He+ implantations of h- BN”, Journal of Appl. Phys., 96: 4483- 4489, (2004).
  • [25] Mohsin, M. H., Khashan, K. S., and Sulaiman, G. M., “Optical and structural properties of H-BN@ Gd2O3 nanoflake prepared by laser–induced ablation in liquid”, Physica Scripta, 98(5), 055903, (2023).
  • [26] Li, J.,Bernard, S.,Salles, V.,Gervaisand, C., Miele, P., “Preparation of Polyborazylene-Derived Bulk Boron Nitride with Tunable Properties by Warm-Pressing and Pressureless Pyrolysis”, Chem. Mater, 22, (2010).
  • [27] Guerra, V., Wan, C., Degirmenci, V., Sloan, J., Presvytis, D., and McNally, T., “2D boron nitride nanosheets (BNNS) prepared by high-pressure homogenisation: structure and morphology”, Nanoscale, 10(41), 19469-19477, (2018).
  • [28] Wang, Z., Zhu, Y., Ji, D., Li, Z., and Yu, H., “Scalable Exfoliation and High‐Efficiency Separation Membrane of Boron Nitride Nanosheets”, ChemistrySelect, 5(12), 3567-3573, (2020).
  • [29] Chakrabarty, K., Arnold, I., and Catledge, S. A., “Hexagonal boron nitride grown using high atomic boron emission during microwave plasma chemical vapor deposition”, Journal of Vacuum Science and Technology A: Vacuum, Surfaces, and Films, 37(6), 061507, (2019).
  • [30] Hu, S. Q., Wang, Y., and Liu, L. L., “Synthesis of h-BN by the Combustion of B/KNO3/Octogen Mixture under Nitrogen Atmosphere”, Journal of Chemistry, 2019, (2019).
  • [31] Huang J. ve Zhu Y. T., “Advances in the Synthesis and Characterisation of Boron Nitride”, Defect and Diffusion Forum, 186-187, 1-32, (2000).
  • [32] Gao L. ve Li J., “Preparation of Nanostructured Hexagonal Boron Nitride Powder”, Journal of American Ceramic Society, 111: 1982- 1984, (2003).
  • [33] Meng, Y., Mao, H. K., Eng, P. J., Trainor, T. P., Newville, M., Hu, M. Y., Kao, C., Shu, J., Hausermann, D., and Hemley, R. J., “The formation of sp3 bonding in compressed BN”, Nature materials, 3(2), 111-114, (2004).
  • [34] Thangasamy, P., and Sathish, M., “Supercritical fluid processing: a rapid, one-pot exfoliation process for the production of surfactant-free hexagonal boron nitride nanosheets”, Cryst Eng Comm, 17(31), 5895-5899, (2015).
  • [35] Ulus, H., Üstün, T., Eskizeybek, V., Şahin, Ö. S., Avcı, A., and Ekrem, M., “Boron nitride-MWCNT/epoxy hybrid nanocomposites: Preparation and mechanical properties”, Applied Surface Science, 318, 37-42, (2014).
  • [36] Naclerio, A. E., and Kidambi, P. R., “A review of scalable hexagonal boron nitride (h‐BN) synthesis for present and future applications”. Advanced Materials, 35(6), 2207374, (2023).
There are 36 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Research Article
Authors

Hatice Begüm Murathan 0000-0002-0491-098X

Early Pub Date July 2, 2024
Publication Date
Submission Date May 17, 2023
Published in Issue Year 2024 EARLY VIEW

Cite

APA Murathan, H. B. (2024). Hegzagonal Bor Nitrürün Floresans Özelliği. Politeknik Dergisi1-1.
AMA Murathan HB. Hegzagonal Bor Nitrürün Floresans Özelliği. Politeknik Dergisi. Published online July 1, 2024:1-1.
Chicago Murathan, Hatice Begüm. “Hegzagonal Bor Nitrürün Floresans Özelliği”. Politeknik Dergisi, July (July 2024), 1-1.
EndNote Murathan HB (July 1, 2024) Hegzagonal Bor Nitrürün Floresans Özelliği. Politeknik Dergisi 1–1.
IEEE H. B. Murathan, “Hegzagonal Bor Nitrürün Floresans Özelliği”, Politeknik Dergisi, pp. 1–1, July 2024.
ISNAD Murathan, Hatice Begüm. “Hegzagonal Bor Nitrürün Floresans Özelliği”. Politeknik Dergisi. July 2024. 1-1.
JAMA Murathan HB. Hegzagonal Bor Nitrürün Floresans Özelliği. Politeknik Dergisi. 2024;:1–1.
MLA Murathan, Hatice Begüm. “Hegzagonal Bor Nitrürün Floresans Özelliği”. Politeknik Dergisi, 2024, pp. 1-1.
Vancouver Murathan HB. Hegzagonal Bor Nitrürün Floresans Özelliği. Politeknik Dergisi. 2024:1-.