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Kalsine Edilmiş Doğal Zeolit İkameli Harçların Mühendislik Özelliklerinin İncelenmesi

Year 2024, EARLY VIEW, 1 - 1
https://doi.org/10.2339/politeknik.1481264

Abstract

Bu çalışmada, ülkemizde bol miktarda bulunan zeolit rezervlerinin, doğal ve kalsine edilmiş hallerinin çimento yerine ikame edilerek hazırlanan harç numunelerinin fiziksel ve mekanik özellikleri araştırılmıştır. Çalışmada, %15 oranında doğal ve kalsine edilmiş zeolit, çimento yerine ikame edilerek 50x50x50 mm boyutlarında numuneler üretilmiştir. Hazırlanan numuneler üzerinde 3, 7, 28 ve 90 günlük basınç dayanımı deneyleri; ayrıca kapiler su emme, ultrasonik geçiş hızı, ıslanma kuruma deneyleri ve mikroyapı özelliklerini incelemek amacıyla SEM analizleri yapılmıştır. Çalışmadan elde edilen sonuçlara göre, çimento yerine ikame edilen kalsine zeolit, harcın özelliklerini iyileştirdiği ve kontrol harcına göre daha olumlu sonuçlar verdiği gözlemlenmiştir. Kalsine edilmiş zeolit ikameli harçların kontrol harçlarına kıyasla daha geçirimsiz olduğu ve dayanıklılık açısından daha olumlu sonuçlar verdiği tespit edilmiştir.

References

  • [1] Iijima, A., “Geology of natural zeolites and zeolitic rocks”, Pure and Applied Chemistry Fifth, 52(9), 2115-2130, (1980).
  • [2] Ahmadi, B., Shekarchi, M., “Use of natural zeolite as a supplementary cementitious material”, Cement and Concrete Composites, 32(2), 134-141, (2010).
  • [3] Islam, M. S., Mohr, B. J., VandenBerge, D., “Performance of natural clinoptilolite zeolite in the cementitious materials: A comparative study with metakaolin, fly ash, and blast furnace slag”, Journal of Building Engineering, 53, 104535, (2022).
  • [4] Toma, I. O., Stoian, G., Rusu, M. M., Ardelean, I., Cimpoeşu, N., Alexa-Stratulat, S., M., “Analysis of Pore Structure in Cement Pastes with Micronized Natural Zeolite”, Materials, 16(13), 4500, (2023).
  • [5] Kazemian, M., Shafei, B., “Internal curing capabilities of natural zeolite to improve the hydration of ultra-high performance concrete”, Construction and Building Materials, 340, 127452, (2022).
  • [6] Gottardi, G.; Galli, E., “Natural Zeolites”, Springer, Berlin/Heidelberg, Germany, Volume 18, ISBN 978-3-642-46520-8, (1985).
  • [7] Ceylan, S., Yazıcıoğlu, S., Turanlı, L., “Usage of micronized zeolite in high performanced concrete”, Journal of the Faculty of Engineering and Architecture of Gazi University, 36(1), 163-176, (2021).
  • [8] Kitsopoulos, K. P., Dunham, A. C., “Heulandite and mordenite-rich tuffs from Greece: a potential source for pozzolanic materials”, Mineralium Deposita, 31, 576-583, (1996).
  • [9] Janotka, I., Krajči, L. U., Dzivák., M. “Properties and utilization of zeolite-blended Portland cements”, Clays and Clay Minerals, 51(6), 616-624, (2003).
  • [10] Perraki, T., Kakali, G., Kontoleon, F. “The effect of natural zeolites on the early hydration of Portland cement”, Microporous and mesoporous materials, 61(1-3), 205-212, (2003).
  • [11] Canpolat, F., Yılmaz, K., Köse, M. M., Sümer, M., Yurdusev, M. A., “Use of zeolite, coal bottom ash and fly ash as replacement materials in cement production”, Cement and concrete research, 34(5), 731-735, (2004).
  • [12] Martínez-Ramírez, S., Blanco-Varela, M. T., Ereña, I., Gener, M., “Pozzolanic reactivity of zeolitic rocks from two different Cuban deposits: Characterization of reaction products”, Applied Clay Science, 32(1-2), 40-52, (2006).
  • [13] Kontori, E., Perraki, T., Tsivilis, S., & Kakali, G., “Zeolite blended cements: evaluation of their hydration rate by means of thermal analysis”, Journal of Thermal Analysis and Calorimetry, 96, 993-998, (2009).
  • [14] Snellings, R., Mertens, G., Hertsens, S., Elsen, J., “The zeolite–lime pozzolanic reaction: Reaction kinetics and products by in situ synchrotron X-ray powder diffraction”, Microporous and mesoporous Materials, 126(1-2), 40-49, (2009).
  • [15] Perraki, T., Kontori, E., Tsivilis, S., Kakali, G.. “The effect of zeolite on the properties and hydration of blended cements”, Cement and Concrete Composites, 32(2), 128-133, (2010).
  • [16] Ramezanianpour, A. A., Kazemian, A., Sarvari, M., Ahmadi, B., “Use of natural zeolite to produce self-consolidating concrete with low Portland cement content and high durability”, Journal of Materials in Civil Engineering, 25(5), 589-596, (2013).
  • [17] Beers, A. E., van Bokhoven, J. A., De Lathouder, K. M., Kapteijn, F., Moulijn, J. A., “Optimization of zeolite Beta by steaming and acid leaching for the acylation of anisole with octanoic acid: a structure–activity relation”, Journal of Catalysis, 218(2), 239-248, (2003).
  • [18] Pérez-Ramırez, J., Kapteijn, F., Groen, J. C., Doménech, A., Mul, G., Moulijn, J. A., “Steam-activated FeMFI zeolites. Evolution of iron species and activity in direct N2O decomposition”, Journal of Catalysis, 214(1), 33-45, (2003).
  • [19] Tao, Y., Kanoh, H., Abrams, L., Kaneko, K., “Mesopore-modified zeolites: preparation, characterization, and applications”, Chemical reviews, 106(3), 896-910. (2006).
  • [20] Duvarcı, Ö. Ç., Akdeniz, Y., Özmıhçı, F., Ülkü, S., Balköse, D., Çiftçioğlu, M., “Thermal behaviour of a zeolitic tuff”, Ceramics International, 33(5), 795-801, (2007).
  • [21] Ates, A., Hardacre, C., “The effect of various treatment conditions on natural zeolites: Ion exchange, acidic, thermal and steam treatments”, Journal of colloid and interface science, 372(1), 130-140, (2012).
  • [22] Habert, G., Choupay, N., Montel, J. M., Guillaume, D., Escadeillas, G., “Effects of the secondary minerals of the natural pozzolans on their pozzolanic activity”, Cement and Concrete Research, 38(7), 963-975, (2008).
  • [23] Perraki, T., Kakali, G., Kontori, E., “Characterization and pozzolanic activity of thermally treated zeolite”, Journal of thermal analysis and calorimetry, 82(1), 109-113, (2005).
  • [24] Liebig, E., Althaus, E., “Pozzolanic activity of volcanic tuff and suevite: effects of calcination”, Cement and concrete research, 28(4), 567-575. (1998).
  • [25] Johnson, M., O'Connor, D., Barnes, P., Catlow, C. R. A., Owens, S. L., Sankar, G., Stephenson, R., “Cation exchange, dehydration, and calcination in clinoptilolite: In situ X-ray diffraction and computer modeling”, The Journal of Physical Chemistry B, 107(4), 942-951, (2003).
  • [26] Snellings, R., Mertens, G., Elsen, J., “Supplementary cementitious materials”, Reviews in mineralogy and geochemistry, 74(1), 211-278, (2012).
  • [27] Seraj, S., Ferron, R. D., Juenger, M. C., “Calcining natural zeolites to improve their effect on cementitious mixture workability”, Cement and Concrete Research, 85, 102-110, (2016).
  • [28] Burris, L. E., Juenger, M. C., “Milling as a pretreatment method for increasing the reactivity of natural zeolites for use as supplementary cementitious materials”, Cement and Concrete Composites, 65, 163-170, (2016).
  • [29] Küçükyıldırım, E., Uzal, B., “Characteristics of calcined natural zeolites for use in 4 high-performance pozzolan blended cements”, Construction and Building Materials, 73(5), 229-234, (2014).
  • [30] Dayi, M., Aruntaş, H. Y., Çavuş, M., Şimşek, O., “Zeolit, uçucu kül ve atik cam malzemelerin portland kompoze çimento üretiminde kullanılabilirliğinin araştırılması”, Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 28(3), (2013).
  • [31] TS EN 197-1, “Çimento-Bölüm 1: Genel çimentolar - Bileşim, özellikler ve uygunluk kriterleri”, (2012).
  • [32] TS EN 196-1, “Çimento deney metotları-Bölüm 1: Dayanım tayini”, (2016).
  • [33] ASTM C597-02, “Standard Test Method for Pulse Velocity Through Concrete”, American Society for Testing And Materials, Philadelphia, (2009).
  • [34] TS 4045, Yapı Malzemelerinde Kapiler Su Emme Tayini”, Türk Standartları Enstitüsü, Ankara, (1985).
  • [35] Florez, C., Restrepo-Baena, O., Tobon, J. I., “Effects of calcination and milling pre-treatments on natural zeolites as a supplementary cementitious material”, Construction and Building Materials, 310, 125220, (2021).
  • [36] Öner, A., Direr, S., Sevgül, T., “Islanma Kuruma Çevrimi-Dinamik Elastisite Modülü İlişkisi”, İzmit, Kocaeli Üniversitesi, (2014).
  • [37] Sefıdehkhan, H. P., Şimşek, O., “Farklı oranlarda geri dönüşüm agregası kullanılarak üretilen betonun bazı mühendislik özelliklerinin araştırılması”, Politeknik Dergisi, 21(1), 83-91, (2018).

Investigation of the Engineering Properties of Mortars with Calcined Natural Zeolite Replacement

Year 2024, EARLY VIEW, 1 - 1
https://doi.org/10.2339/politeknik.1481264

Abstract

In this study, the physical and mechanical properties of mortar specimens prepared by substituting natural and calcined forms of zeolite, abundant in reserves in our country, for cement have been investigated. In this study, specimens measuring 50x50x50 mm were produced by substituting 15% natural and calcined zeolite for cement. On the prepared specimens, compressive strength tests at 3, 7, 28, and 90 days were conducted; additionally, capillary water absorption, ultrasonic pulse velocity, wetting-drying tests, and microstructure properties were examined using SEM analyses. According to the results obtained from the study, it was observed that calcined zeolite, when substituted for cement, improved the properties of the mortar and yielded more favorable results compared to the control mortar. It has been observed that mortars containing calcined zeolite are more impermeable compared to the control mortars and provide more favorable results in terms of durability.

References

  • [1] Iijima, A., “Geology of natural zeolites and zeolitic rocks”, Pure and Applied Chemistry Fifth, 52(9), 2115-2130, (1980).
  • [2] Ahmadi, B., Shekarchi, M., “Use of natural zeolite as a supplementary cementitious material”, Cement and Concrete Composites, 32(2), 134-141, (2010).
  • [3] Islam, M. S., Mohr, B. J., VandenBerge, D., “Performance of natural clinoptilolite zeolite in the cementitious materials: A comparative study with metakaolin, fly ash, and blast furnace slag”, Journal of Building Engineering, 53, 104535, (2022).
  • [4] Toma, I. O., Stoian, G., Rusu, M. M., Ardelean, I., Cimpoeşu, N., Alexa-Stratulat, S., M., “Analysis of Pore Structure in Cement Pastes with Micronized Natural Zeolite”, Materials, 16(13), 4500, (2023).
  • [5] Kazemian, M., Shafei, B., “Internal curing capabilities of natural zeolite to improve the hydration of ultra-high performance concrete”, Construction and Building Materials, 340, 127452, (2022).
  • [6] Gottardi, G.; Galli, E., “Natural Zeolites”, Springer, Berlin/Heidelberg, Germany, Volume 18, ISBN 978-3-642-46520-8, (1985).
  • [7] Ceylan, S., Yazıcıoğlu, S., Turanlı, L., “Usage of micronized zeolite in high performanced concrete”, Journal of the Faculty of Engineering and Architecture of Gazi University, 36(1), 163-176, (2021).
  • [8] Kitsopoulos, K. P., Dunham, A. C., “Heulandite and mordenite-rich tuffs from Greece: a potential source for pozzolanic materials”, Mineralium Deposita, 31, 576-583, (1996).
  • [9] Janotka, I., Krajči, L. U., Dzivák., M. “Properties and utilization of zeolite-blended Portland cements”, Clays and Clay Minerals, 51(6), 616-624, (2003).
  • [10] Perraki, T., Kakali, G., Kontoleon, F. “The effect of natural zeolites on the early hydration of Portland cement”, Microporous and mesoporous materials, 61(1-3), 205-212, (2003).
  • [11] Canpolat, F., Yılmaz, K., Köse, M. M., Sümer, M., Yurdusev, M. A., “Use of zeolite, coal bottom ash and fly ash as replacement materials in cement production”, Cement and concrete research, 34(5), 731-735, (2004).
  • [12] Martínez-Ramírez, S., Blanco-Varela, M. T., Ereña, I., Gener, M., “Pozzolanic reactivity of zeolitic rocks from two different Cuban deposits: Characterization of reaction products”, Applied Clay Science, 32(1-2), 40-52, (2006).
  • [13] Kontori, E., Perraki, T., Tsivilis, S., & Kakali, G., “Zeolite blended cements: evaluation of their hydration rate by means of thermal analysis”, Journal of Thermal Analysis and Calorimetry, 96, 993-998, (2009).
  • [14] Snellings, R., Mertens, G., Hertsens, S., Elsen, J., “The zeolite–lime pozzolanic reaction: Reaction kinetics and products by in situ synchrotron X-ray powder diffraction”, Microporous and mesoporous Materials, 126(1-2), 40-49, (2009).
  • [15] Perraki, T., Kontori, E., Tsivilis, S., Kakali, G.. “The effect of zeolite on the properties and hydration of blended cements”, Cement and Concrete Composites, 32(2), 128-133, (2010).
  • [16] Ramezanianpour, A. A., Kazemian, A., Sarvari, M., Ahmadi, B., “Use of natural zeolite to produce self-consolidating concrete with low Portland cement content and high durability”, Journal of Materials in Civil Engineering, 25(5), 589-596, (2013).
  • [17] Beers, A. E., van Bokhoven, J. A., De Lathouder, K. M., Kapteijn, F., Moulijn, J. A., “Optimization of zeolite Beta by steaming and acid leaching for the acylation of anisole with octanoic acid: a structure–activity relation”, Journal of Catalysis, 218(2), 239-248, (2003).
  • [18] Pérez-Ramırez, J., Kapteijn, F., Groen, J. C., Doménech, A., Mul, G., Moulijn, J. A., “Steam-activated FeMFI zeolites. Evolution of iron species and activity in direct N2O decomposition”, Journal of Catalysis, 214(1), 33-45, (2003).
  • [19] Tao, Y., Kanoh, H., Abrams, L., Kaneko, K., “Mesopore-modified zeolites: preparation, characterization, and applications”, Chemical reviews, 106(3), 896-910. (2006).
  • [20] Duvarcı, Ö. Ç., Akdeniz, Y., Özmıhçı, F., Ülkü, S., Balköse, D., Çiftçioğlu, M., “Thermal behaviour of a zeolitic tuff”, Ceramics International, 33(5), 795-801, (2007).
  • [21] Ates, A., Hardacre, C., “The effect of various treatment conditions on natural zeolites: Ion exchange, acidic, thermal and steam treatments”, Journal of colloid and interface science, 372(1), 130-140, (2012).
  • [22] Habert, G., Choupay, N., Montel, J. M., Guillaume, D., Escadeillas, G., “Effects of the secondary minerals of the natural pozzolans on their pozzolanic activity”, Cement and Concrete Research, 38(7), 963-975, (2008).
  • [23] Perraki, T., Kakali, G., Kontori, E., “Characterization and pozzolanic activity of thermally treated zeolite”, Journal of thermal analysis and calorimetry, 82(1), 109-113, (2005).
  • [24] Liebig, E., Althaus, E., “Pozzolanic activity of volcanic tuff and suevite: effects of calcination”, Cement and concrete research, 28(4), 567-575. (1998).
  • [25] Johnson, M., O'Connor, D., Barnes, P., Catlow, C. R. A., Owens, S. L., Sankar, G., Stephenson, R., “Cation exchange, dehydration, and calcination in clinoptilolite: In situ X-ray diffraction and computer modeling”, The Journal of Physical Chemistry B, 107(4), 942-951, (2003).
  • [26] Snellings, R., Mertens, G., Elsen, J., “Supplementary cementitious materials”, Reviews in mineralogy and geochemistry, 74(1), 211-278, (2012).
  • [27] Seraj, S., Ferron, R. D., Juenger, M. C., “Calcining natural zeolites to improve their effect on cementitious mixture workability”, Cement and Concrete Research, 85, 102-110, (2016).
  • [28] Burris, L. E., Juenger, M. C., “Milling as a pretreatment method for increasing the reactivity of natural zeolites for use as supplementary cementitious materials”, Cement and Concrete Composites, 65, 163-170, (2016).
  • [29] Küçükyıldırım, E., Uzal, B., “Characteristics of calcined natural zeolites for use in 4 high-performance pozzolan blended cements”, Construction and Building Materials, 73(5), 229-234, (2014).
  • [30] Dayi, M., Aruntaş, H. Y., Çavuş, M., Şimşek, O., “Zeolit, uçucu kül ve atik cam malzemelerin portland kompoze çimento üretiminde kullanılabilirliğinin araştırılması”, Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 28(3), (2013).
  • [31] TS EN 197-1, “Çimento-Bölüm 1: Genel çimentolar - Bileşim, özellikler ve uygunluk kriterleri”, (2012).
  • [32] TS EN 196-1, “Çimento deney metotları-Bölüm 1: Dayanım tayini”, (2016).
  • [33] ASTM C597-02, “Standard Test Method for Pulse Velocity Through Concrete”, American Society for Testing And Materials, Philadelphia, (2009).
  • [34] TS 4045, Yapı Malzemelerinde Kapiler Su Emme Tayini”, Türk Standartları Enstitüsü, Ankara, (1985).
  • [35] Florez, C., Restrepo-Baena, O., Tobon, J. I., “Effects of calcination and milling pre-treatments on natural zeolites as a supplementary cementitious material”, Construction and Building Materials, 310, 125220, (2021).
  • [36] Öner, A., Direr, S., Sevgül, T., “Islanma Kuruma Çevrimi-Dinamik Elastisite Modülü İlişkisi”, İzmit, Kocaeli Üniversitesi, (2014).
  • [37] Sefıdehkhan, H. P., Şimşek, O., “Farklı oranlarda geri dönüşüm agregası kullanılarak üretilen betonun bazı mühendislik özelliklerinin araştırılması”, Politeknik Dergisi, 21(1), 83-91, (2018).
There are 37 citations in total.

Details

Primary Language Turkish
Subjects Construction Materials
Journal Section Research Article
Authors

Mustafa Kop 0000-0002-9834-4690

Salih Yazıcıoğlu 0000-0002-6767-2026

Early Pub Date August 6, 2024
Publication Date
Submission Date May 10, 2024
Acceptance Date August 1, 2024
Published in Issue Year 2024 EARLY VIEW

Cite

APA Kop, M., & Yazıcıoğlu, S. (2024). Kalsine Edilmiş Doğal Zeolit İkameli Harçların Mühendislik Özelliklerinin İncelenmesi. Politeknik Dergisi1-1. https://doi.org/10.2339/politeknik.1481264
AMA Kop M, Yazıcıoğlu S. Kalsine Edilmiş Doğal Zeolit İkameli Harçların Mühendislik Özelliklerinin İncelenmesi. Politeknik Dergisi. Published online August 1, 2024:1-1. doi:10.2339/politeknik.1481264
Chicago Kop, Mustafa, and Salih Yazıcıoğlu. “Kalsine Edilmiş Doğal Zeolit İkameli Harçların Mühendislik Özelliklerinin İncelenmesi”. Politeknik Dergisi, August (August 2024), 1-1. https://doi.org/10.2339/politeknik.1481264.
EndNote Kop M, Yazıcıoğlu S (August 1, 2024) Kalsine Edilmiş Doğal Zeolit İkameli Harçların Mühendislik Özelliklerinin İncelenmesi. Politeknik Dergisi 1–1.
IEEE M. Kop and S. Yazıcıoğlu, “Kalsine Edilmiş Doğal Zeolit İkameli Harçların Mühendislik Özelliklerinin İncelenmesi”, Politeknik Dergisi, pp. 1–1, August 2024, doi: 10.2339/politeknik.1481264.
ISNAD Kop, Mustafa - Yazıcıoğlu, Salih. “Kalsine Edilmiş Doğal Zeolit İkameli Harçların Mühendislik Özelliklerinin İncelenmesi”. Politeknik Dergisi. August 2024. 1-1. https://doi.org/10.2339/politeknik.1481264.
JAMA Kop M, Yazıcıoğlu S. Kalsine Edilmiş Doğal Zeolit İkameli Harçların Mühendislik Özelliklerinin İncelenmesi. Politeknik Dergisi. 2024;:1–1.
MLA Kop, Mustafa and Salih Yazıcıoğlu. “Kalsine Edilmiş Doğal Zeolit İkameli Harçların Mühendislik Özelliklerinin İncelenmesi”. Politeknik Dergisi, 2024, pp. 1-1, doi:10.2339/politeknik.1481264.
Vancouver Kop M, Yazıcıoğlu S. Kalsine Edilmiş Doğal Zeolit İkameli Harçların Mühendislik Özelliklerinin İncelenmesi. Politeknik Dergisi. 2024:1-.