Sulu Çözeltilerden Amoksisilin Gideriminde Ani (Flaş) Isıtma Yöntemiyle Elde Edilen Aktif Karbonların Kullanımı
Year 2024,
Volume: 27 Issue: 1, 387 - 396, 29.02.2024
Aygül Yurtay
,
Murat Kilic
Abstract
Bu çalışmada, farklı biyokütle atıkları kullanılarak aktif karbon ilk defa ani (flaş) ısıtma yöntemi ile üretilmiştir. Ani ısıtma yöntemiyle üretilen aktif karbonlar, sulu çözeltiden amoksisilin gideriminde adsorbent olarak kullanılmıştır. Adsorpsiyon deneyleri sonucunda elde edilen verilere farklı adsorpsiyon izoterm ve kinetik modelleri uygulanmış ve adsorpsiyon termodinamiği araştırılmıştır. Üretilen aktif karbonların amoksisilin (AMX) adsorpsiyon kapasitesi 300-500 mg/g arasında bulunmuştur. Sonuçlar değerlendirildiğinde, ani (flaş) ısıtma yöntemiyle yüzey alanı ve mikrogözenekliliği yüksek aktif karbonların amoksisilin gideriminde etkili bir adsorbent olarak kullanılabileceği belirlenmiştir.
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The Use of Activated Carbons Obtained by Flash Heating Method for the Removal of Amoxicillin From Aqueous Solutions
Year 2024,
Volume: 27 Issue: 1, 387 - 396, 29.02.2024
Aygül Yurtay
,
Murat Kilic
Abstract
In this study, activated carbon was produced for the first time by flash heating method using different biomass wastes. Activated carbons produced by the flash heating method were used as adsorbent in the removal of amoxicillin from the aqueous solution. Different adsorption isotherm and kinetic models were applied to the data obtained from the adsorption experiments and adsorption thermodynamics were investigated. The amoxicillin (AMX) adsorption capacity of the produced activated carbons was found between 300-500 mg/g. When the results were evaluated, it was determined that activated carbons with high surface area and microporosity can be used as an effective adsorbent in the removal of amoxicillin by flash heating.
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- [16] Dabrowski, A., “Adsorption-from theory to practice”, Advances in Colloid and Interface Science, 93:135-224, (2001).
- [17] Sarıkaya, Y., “Fizikokimya”, Ankara: Gazi Kitabevi, (2011).
- [18] Zeytinci B., “Elektrospining tekniği ve UV ışımasının eşzamanlı olarak uygulanması ile nanofiber membranların hazırlanması ve kıymetli metallerin adsorpsiyonunda uygulanması” (Doktora Tezi), İstanbul: İstanbul Teknik Üniversitesi, Fen Bilimleri Enstitüsü, (2014).
- [19] Qiu H., Lv L., Pan B., Zhang Q.J., Zhang W.M. and Zhang Q.X., “Critical review in adsorption kinetic models”, J. Zhejiang Univ Sci A, 10(5): 716-724, (2009).
- [20] Mutlu S., “Fındık kabuğu ve üzüm çekirdeğinden üretilen aktif karbonlar ile kurşun iyonlarının adsorpsiyonu”, (Yüksek Lisans Tezi), İstanbul: İstanbul Teknik Üniversitesi, Fen Bilimleri Enstitüsü, (2009).
- [21] Liu H., Xu G., Li G., “Preparation of porous biochar based on pharmaceutical sludge activated by NaOH and its application in the adsorption of tetracycline”, Journal of Colloid and Interface Science, 587: 271-278, (2021).
- [22] Kariim I., Abdulkareem A.S. and Abubakre O.K. “Development and characterization of MWCNTs from activated carbon as adsorbent for metronidazole and levofloxacin sorption from pharmaceutical wastewater: Kinetics, isotherms and thermodynamic studies”, Scientific African, e00242, (2020).
- [23] Putra E.K., Pranowo R., Sunarso J., Indraswati N. and Ismadji S., “Performance of activated carbon and bentonite for adsorption of amoxicillin from wastewater: mechanisms, isotherms and kinetics”, Water Research, 43: 2419-243, (2009).
- [24] Pezoti O., Cazetta A.L., Bedin K.C., Souza L.S., Martins A.C., Silva T.L., Junior O.O.S., Visentainer J.V. and Almeida V.C., “NaOH activated carbon of high surface area produces from guava seeds as a high efficiency adsorbent for amoxicillin removal: kinetic, isotherm and thermodynamic studies”, Chemical Engineering Journal, 288:778-788, (2016).
- [25] Belhachemi M. and Djelaila S., “Removal of Amoxicillin Antibiotic from Aqueous Solutions by Date Pits Activated Carbons”, Environmental Processes, 4: 549–561, (2017).
- [26] Chayid M.A. and Ahmed M.J., “Amoxicillin adsorption on microwave prepared from activated carbon from arundo donax linn: isotherms, kinetics ans thermodynamics studies”, Journal of Environmental Chemical Engineering, 3:1592-1601, (2015).
- [27] Mousssavi G., Alahabadi A., Yaghmaeian K. and Eskandari M., “Preparation characterization and adsorption potential of the NH4Cl induced activated carbon for the removal of amoxicillin antibiotic from water”, Chemical Engineering Journal, 217: 119-128, (2013).
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